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Non-isothermal regimes and chemical control of branching-chain processes

Vilen Vagarshovich Azatyan 1
Vilen Vagarshovich Azatyan
1 Institute of Structural Macrokinetics and Materials Science, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC1999v068n12ABEH000520
Published 30 November 1998
Communication , Volume 68, Issue 12, 1021-1039
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Azatyan V. V. Non-isothermal regimes and chemical control of branching-chain processes // Russian Chemical Reviews. 1999. Vol. 68. No. 12. pp. 1021-1039.
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Azatyan V. V. Non-isothermal regimes and chemical control of branching-chain processes // Russian Chemical Reviews. 1999. Vol. 68. No. 12. pp. 1021-1039.
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TY - JOUR
DO - 10.1070/RC1999v068n12ABEH000520
UR - https://rcr.colab.ws/publications/10.1070/RC1999v068n12ABEH000520
TI - Non-isothermal regimes and chemical control of branching-chain processes
T2 - Russian Chemical Reviews
AU - Azatyan, Vilen Vagarshovich
PY - 1999
DA - 1998/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1021-1039
IS - 12
VL - 68
ER -
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@article{1999_Azatyan,
author = {Vilen Vagarshovich Azatyan},
title = {Non-isothermal regimes and chemical control of branching-chain processes},
journal = {Russian Chemical Reviews},
year = {1999},
volume = {68},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC1999v068n12ABEH000520},
number = {12},
pages = {1021--1039},
doi = {10.1070/RC1999v068n12ABEH000520}
}
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Azatyan, Vilen Vagarshovich. “Non-isothermal regimes and chemical control of branching-chain processes.” Russian Chemical Reviews, vol. 68, no. 12, Nov. 1999, pp. 1021-1039. https://rcr.colab.ws/publications/10.1070/RC1999v068n12ABEH000520.
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Abstract

Non-isothermal modes of branching-chain reactions are analysed. Characteristic features of these reactions caused by the simultaneous action of the reaction chain avalanche and self-heating are considered in terms of concepts of the modern theory. New data are presented indicating that chain branching is the predominant factor in gas combustion processes not only at very low pressures, as it was assumed earlier, but also at atmospheric and higher pressures. The specific character of the temperature dependence of the rate of chain reactions and data dealing with the discovery of a special chain combustion mode, chain thermal explosion, are considered. The efficiency of chemical control of chain combustion in any mode including explosion, flame propagation and its transition to detonation by virtue of highly efficient non-corrosive inhibitors is demonstrated. The bibliography includes 135 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
5
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1953
6.
6
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
7.
7
E. Rabinowitch
"Photosynthesis" , 1956
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
9.
9
V. H. Lynch
Carnegie Inst. Year Book , 1954
10.
10
T. A. Kryukova
"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959
11.
Slow oxidation of hydrocarbons and cool flames
Yang C., Gray B.F.
The Journal of Physical Chemistry , 1969
12.
Explosive systems with reactant consumption. II. Stability
Gray B.F., Sherrington M.E.
Combustion and Flame , 1972
14.
14
V. B. Evstigneev
Zhur. Fiz. Khim. , 1958
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
17.
17
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
18.
18
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
19.
19
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1959
20.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
21.
21
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
22.
22
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
23.
23
N. V. Vostrilova
Dokl. Akad. Nauk Uzbek. SSR , 1958
24.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
25.
25
G. W. Robinson
J. Chem. Phys. , 1955
26.
26
B. Ya. Dain
1957
27.
27
A. A. Krasnovskii
Biofizika , 1956
28.
348. The reaction of hydrogen atoms with oxygen and with ethane
Baldwin R.R., Melvin A.
Journal of the Chemical Society (Resumed) , 1964
29.
29
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
30.
30
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
31.
31
A. A. Krasnovskii
Biokhimiya , 1960
32.
32
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
34.
35
Z. K. Maizus
Dokl. Akad. Nauk SSSR , 1960
35.
36
J. Billon
Bull. Soc. chim. France , 1960
36.
37
L. M. Kosobutskaya
Dokl. Akad. Nauk SSSR , 1950
37.
38
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
38.
39
V. F. Gachkovskii
Biofizika , 1959
39.
Chemical Kinetic Data Base for Combustion Chemistry. Part I. Methane and Related Compounds
Tsang W., Hampson R.F.
Journal of Physical and Chemical Reference Data , 1986
40.
Summary table of evaluated kinetic data for combustion modeling: Supplement 1
Baulch D.L., Cobos C.J., Cox R.A., Frank P., Hayman G., Just T., Kerr J.A., Murrells T., Pilling M.J., Troe J., Walker R.W., Warnatz J.
Combustion and Flame , 1994
41.
42
L. K. Obukhova
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
42.
43
N. Bunge
Ber. Deutsch. Chem. Ges. , 1870
43.
44
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
44.
45
W. Hendrich
Roczniki Chemii , 1958
45.
46
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1955
46.
47
G. Oster
"Research in Photosynthesis" , 1957
48.
49
A. A. Krasnovskii
Biofizika , 1958
49.
50
G. Glacomello
Gazzetta. , 1935
50.
Fluorine and Chlorine Flames
Slootmaekers P.J., van Tiggelen A.
Bulletin des Sociétés Chimiques Belges , 2010
51.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
52.
53
D. Porretand E. Rabinowitch
Nature , 1937
53.
54
R. Livingston
J. Phys. Chem. , 1941
54.
55
G. A. Bogdanovskii
1958
55.
56
T. Iasui
Bull. Chem. Soc. Japan. , 1935
56.
57
R. Livingston
"Research in Photosynthesis" , 1957
57.
58
N. E. Khomutov
1953
58.
NCl(a1Δ) and I(52P12) production in a D/NCl3/HI transverse flow reactor
Schwenz R.W., Gilbert J.V., Coombe R.D.
Chemical Physics Letters , 1993
59.
60
A. N. Terenin
Optika i Spektrosk. , 1956
60.
61
A. N. Terenin
1959
61.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
62.
The Thermal Reaction Between Hydrogen and Oxygen II. The Third Explosion Limit
Oldenberg O., Sommers H.S.
Journal of Chemical Physics , 1941
63.
The mechanism of the hydrogen-oxygen reaction II. The reaction occurring between the second and third explosion limits
WILLBOURN A H, HINSHELWOOD C N
Proceedings of the Royal Society A: Mathematical, Physical and Engineering Sciences , 1946
64.
Mechanism of the Thermal Reaction Between Hydrogen and Oxygen
von Elbe G., Lewis B.
Journal of Chemical Physics , 1942
65.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
66.
The kinetics of the combination of hydrogen and oxygen
Proceedings of the Royal Society of London Series A Containing Papers of a Mathematical and Physical Character , 2006
67.
68
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1946
68.
69
B. Commoner
1958
69.
70
N. Bubnov
Biofizika , 1960
70.
71
Yu. A. Shlyapnikov
Vysokomol. Soed. , 1962
71.
72
A. F. Lukovnikov
"Starenie i Stabilizatsiya Polimerov" (Aging arid Stabilisation of Polymers) , 1963
73.
Analytical and numerical modeling of flame-balls in hydrogen-air mixtures☆
BUCKMASTER J., SMOOKE M., GIOVANGIGLI V.
Combustion and Flame , 1993
75.
Flamelet structure of radiating CH4-air flames
Chan S.H., Pan X.C., Abou-Ellail M.M.
Combustion and Flame , 1995
77.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
78.
79
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
79.
80
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1937
80.
81
J. C. Ghosh
J. Indian Chem. Soc. , 1934
81.
82
G. P. Brin
Biokhimiya , 1957
82.
83
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
84.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
85.
86
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
86.
87
J. F. Arens
"Advances in Organic Chemistry" , 1960
87.
88
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1946
88.
89
A. A. Krasnovskii
Izd. Akad. Nauk SSSR, Moscow , 1955
89.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
90.
91
L. M. Vorob'eva
Biokhimiya , 1956
91.
92
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
92.
93
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
94.
95
A. A. Krasnovskii
Fiziologiya Rastenii , 1957
95.
96
L. M. Vorob'eva
Biokhimiya , 1958
96.
On Deflagration-to-Detonation Transition
BRAILOVSKY I., SIVASHlNSKY G.I.
Combustion Science and Technology , 1997
97.
98
W. Franke
Chem. Zentr. , 1954
98.
Two-dimensional reactive flow dynamics in cellular detonation waves
Gamezo V.N., Desbordes D., Oran E.S.
Shock Waves , 1999
99.
100
V. V. Zolotarev
Chem. Abs. , 1941
100.
101
M. F. Shostakovskii
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
101.
Ignition processes in hydrogenoxygen mixtures
Maas U., Warnatz J.
Combustion and Flame , 1988
103.
104
O. P. Osipova
Dokl. Akad. Nauk SSSR , 1950
104.
105
F. F. Litvin
Dokl. Akad. Nauk SSSR , 1958
105.
106
F. Fichter
Helv. Chim. Acta , 1927
106.
107
M. F. Shostakovskii
Zhur. Obshch. Khim. , 1961
107.
108
F. Fichter
Helv. Chim. Acta , 1924
108.
109
F. Ficher
Bull. Soc. chim. France (4) , 1916
109.
110
M. F. Shostakovskii
Dokl. Akad. Nauk SSSR , 1960
110.
111
M. Calvin
1956
114.
115
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1957
115.
116
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
116.
117
V. V. Levchenko
Zhur. Obshch. Khim. , 1948
117.
118
V. M. Rodionov
Zhur. Obshch. Khim. , 1935
118.
119
V. V. Levchenko
Zhur. Obshch. Khim. , 1947
119.
120
V. V. Levchenko
Zhur. Obshch. Khim. , 1948
120.
121
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953
121.
122
S. R. Rafikov
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1953
122.
123
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
123.
124
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
124.
Heterogeneous free-radical reactions in oxidation processes
Sinev M.Y., Margolis L.Y., Korchak V.N.
Russian Chemical Reviews , 1995
125.
126
J. Wiemannand Ch. Clachet
Compt. rend. , 1948
126.
127
R. Pasternak
Helv. Chim. Acta , 1948
127.
Determination of absolute H atom concentrations in low-pressure flames by two-photon laser-excited fluorescence
Bittner J., Kohse-Höinghaus K., Meier U., Kelm S., Just T.
Combustion and Flame , 1988
128.
129
J. Wiemann
Bull. Soc. chim. France , 1955
129.
130
J. Wiemann
Bull. Soc. chim. France , 1958
131.
132
G. Shima
Kyoto Univ. , 1929
132.
133
C. Wilson
Trans. Electrochem. Soc. , 1941
133.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
134.
135
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1945
135.
136
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1954
136.
137
S. R. Rafikov
Zh. Obshch. Khim. , 1944