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Dehydrocondensation of organylsilanes giving Si–Si bonds

Vera Borisovna Pukhnarevich 1
Vera Borisovna Pukhnarevich
, 
Mikhail Grigor'evich Voronkov 2
Mikhail Grigor'evich Voronkov
, 
Larisa Ivanovna Kopylova 1
Larisa Ivanovna Kopylova
1 Irkutsk State Pedagogical University
2 Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
10.1070/RC2000v069n02ABEH000498
Published 30 November 1999
Communication , Volume 69, Issue 2, 137-151
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Pukhnarevich V. B., Voronkov M. G., Kopylova L. I. Dehydrocondensation of organylsilanes giving Si–Si bonds // Russian Chemical Reviews. 2000. Vol. 69. No. 2. pp. 137-151.
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Pukhnarevich V. B., Voronkov M. G., Kopylova L. I. Dehydrocondensation of organylsilanes giving Si–Si bonds // Russian Chemical Reviews. 2000. Vol. 69. No. 2. pp. 137-151.
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TY - JOUR
DO - 10.1070/RC2000v069n02ABEH000498
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n02ABEH000498
TI - Dehydrocondensation of organylsilanes giving Si–Si bonds
T2 - Russian Chemical Reviews
AU - Pukhnarevich, Vera Borisovna
AU - Voronkov, Mikhail Grigor'evich
AU - Kopylova, Larisa Ivanovna
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 137-151
IS - 2
VL - 69
ER -
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@article{2000_Pukhnarevich,
author = {Vera Borisovna Pukhnarevich and Mikhail Grigor'evich Voronkov and Larisa Ivanovna Kopylova},
title = {Dehydrocondensation of organylsilanes giving Si–Si bonds},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n02ABEH000498},
number = {2},
pages = {137--151},
doi = {10.1070/RC2000v069n02ABEH000498}
}
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Pukhnarevich, Vera Borisovna, et al. “Dehydrocondensation of organylsilanes giving Si–Si bonds.” Russian Chemical Reviews, vol. 69, no. 2, Nov. 2000, pp. 137-151. https://rcr.colab.ws/publications/10.1070/RC2000v069n02ABEH000498.
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Abstract

The data on catalytic dehydrocondensation of organylsilanes with the formation of Si–Si bonds are systematised and generalised. The mechanism and general features (the effects of the nature of the reactants and the catalyst, the solvent and the reaction conditions) of these reactions catalysed by cyclopentadienyl complexes of transition metals are considered. Electrochemical and other procedures for the dehydrocondensation of organylsilanes are discussed. The bibliography includes 220 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
6.
6
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
7.
7
E. Rabinowitch
"Photosynthesis" , 1956
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
9.
9
V. H. Lynch
Carnegie Inst. Year Book , 1954
10.
The alcoholysis of hydrosilanes
Lukevics E., Dzintara M.
Journal of Organometallic Chemistry , 1985
11.
11
T. T. Bannister
Diss. Abstr. , 1959
12.
Conversion of hydrosilanes to alkoxysilanes catalyzed by Cp2TiCl2/nBuLi
Bedard T.C., Corey J.Y.
Journal of Organometallic Chemistry , 1992
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
14
V. B. Evstigneev
Zhur. Fiz. Khim. , 1958
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
20.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
21.
21
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
22.
22
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
24.
24
M. S. Ashkinazi
Dokl. Akad. Nauk SSSR , 1951
25.
25
G. W. Robinson
J. Chem. Phys. , 1955
26.
26
B. Ya. Dain
1957
27.
27
A. A. Krasnovskii
Biofizika , 1956
28.
28
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
30.
30
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
31.
31
A. A. Krasnovskii
Biokhimiya , 1960
32.
Dehydrocoupling reactions of organosilanes with hydrazines
He J., Liu H.Q., Harrod J.F., Hynes R.
Organometallics , 1994
35.
RhCl(PPh3)3 catalyzed hydrosilylation of styrene and phenylacetylene with phenylsilanes
Baruah J.B., Osakada K., Yamamoto T.
Journal of Molecular Catalysis A Chemical , 1995
36.
Reactions of coordinated organosilanes: cobalt carbonyl complexes of ethynylhydrogenosilanes
Corriu R.J., Moreau J.J., Praet H.
Journal of Organometallic Chemistry , 1989
38.
Dehydrocondensation of trialkylsilanes with acetylene and monosubstituted acetylenes
Voronkov M.G., Ushakova N.I., Tsykhanskaya I.I., Pukhnarevich V.B.
Journal of Organometallic Chemistry , 1984
39.
39
V. F. Gachkovskii
Biofizika , 1959
44.
Mechanistic Studies of Palladium(II)-Catalyzed Hydrosilation and Dehydrogenative Silation Reactions
LaPointe A.M., Rix F.C., Brookhart M.
Journal of the American Chemical Society , 1997
46.
Recent Advances in the Chemistry of Cyclopolysilanes
Hengge E., Stüger H.
Chemistry of Functional Groups , 1998
48.
Synthesis of new poly(2,4-disilapentane) oligomers via dehydrocondensation reaction using Group IV metallocene catalysts
Roux P., Pillot J., Birot M., Dunoguès J., Lapouyade P.
Journal of Organometallic Chemistry , 1995
50.
50
G. Glacomello
Gazzetta. , 1935
51.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
52.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
55.
Cp2TiPh2-Catalyzed Dehydrogenative Coupling of Polyhydromonosilanes
Nakano T., Nakamura H., Nagai Y.
Chemistry Letters , 1989
56.
56
T. Iasui
Bull. Chem. Soc. Japan. , 1935
57.
57
R. Livingston
"Research in Photosynthesis" , 1957
58.
58
N. E. Khomutov
1953
59.
Organosilane polymers. III. Block copolymers
Wesson J.P., Williams T.C.
Journal of Polymer Science Polymer Chemistry Edition , 1981
60.
60
A. N. Terenin
Optika i Spektrosk. , 1956
61.
61
A. N. Terenin
1959
62.
62
A. A. Krasnovskii
"Sbornik, Voprosy Khimicheskoi Kinetiki" (Symposium, Problems of Chemical Kinetics) , 1955
63.
Ceramics Via Polymer Pyrolysisdagger
Wynne K.J., Rice R.W.
Annual Review of Materials Science , 1984
64.
Development of a silicon carbide fibre with high tensile strength
YAJIMA S., HAYASHI J., OMORI M., OKAMURA K.
Nature , 1976
65.
Characterization of Organosilicon‐Infiltrated Porous Reaction‐Sintered Si3N4
MAZDIYASNI K.S., WEST R., DAVID L.D.
Journal of the American Ceramic Society , 1978
66.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
67.
67
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1940
68.
CONTINUOUS SILICON CARBIDE FIBER OF HIGH TENSILE STRENGTH
Yajima S., Hayashi J., Omori M.
Chemistry Letters , 1975
69.
69
B. Commoner
1958
71.
Some further observations on polymethylsilane as a precursor for silicon carbide
Mu Y., Harrod J.F., Laine R.M.
Applied Organometallic Chemistry , 1994
72.
72
A. F. Lukovnikov
"Starenie i Stabilizatsiya Polimerov" (Aging arid Stabilisation of Polymers) , 1963
74.
74
F. F. Litvin
Uspekhi Fiz. Nauk , 1960
75.
Phenylmethylpolysilanes: formable silane copolymers with potential semiconducting properties
West R., David L.D., Djurovich P.I., Stearley K.L., Srinivasan K.S., Yu H.
Journal of the American Chemical Society , 1981
77.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
78.
Self-Developing Polysilane Deep-UV Resists - Photochemistry, Photophysics, And Submicron Lithography
Zeigler J.M., Harrah L.A., Johnson A.W.
Proceedings of SPIE - The International Society for Optical Engineering , 1985
79.
Contrast Enhanced UV Lithography With Polysilanes
Hofer D.C., Miller R.D., Willson C.G., Neureuther A.R.
Proceedings of SPIE - The International Society for Optical Engineering , 1984
80.
Polysilane high polymers: mechanism of photodegradation
Trefonas P., West R., Miller R.D.
Journal of the American Chemical Society , 1985
81.
The polysilane high polymers
West R.
Journal of Organometallic Chemistry , 1986
82.
Electronic spectra of polysilanes
Harrah L.A., Zeigler J.M.
Macromolecules , 1987
83.
83
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
84.
Organosilane high polymers: Electronic spectra and photodegradation
Trefonas P., West R., Miller R.D., Hofer D.
Journal of Polymer Science Part C Polymer Letters , 1983
85.
Evaluation of halomethylated poly(methylphenylsilane)s as electron-beam resists
Holder S.J., Jones R.G., Murphy J.J.
Journal of Materials Chemistry A , 1997
87.
87
J. F. Arens
"Advances in Organic Chemistry" , 1960
88.
Dehydrogenative Condensation of Hydrosilanes Catalyzed by an Organoneodymium Complex
Sakakura T., Lautenschlager H., Nakajima M., Tanaka M.
Chemistry Letters , 1991
91.
91
L. M. Vorob'eva
Biokhimiya , 1956
94.
Synthesis and characterization of a novel bis(cyclopentadienyl)titanium hydride complex
Samuel E., Harrod J.F.
Journal of the American Chemical Society , 1984
95.
Identification of some intermediates in the titanocene-catalyzed dehydrogenative coupling of primary organosilanes
Aitken C.T., Harrod J.F., Samuel E.
Journal of the American Chemical Society , 1986
96.
Polymerization of primary silanes to linear polysilanes catalyzed by titanocene derivatives
Aitken C., Harrod J.F., Samuel E.
Journal of Organometallic Chemistry , 1985
97.
Synthesis and structural characterization of an unusual silylzirconium hydride complex
Aitken C., Harrod J.F., Samuel E.
Canadian Journal of Chemistry , 1986
99.
Reactions of silanes with bis(cyclopentadienyl)dialkylzirconium complexes
Mu Y., Aitken C., Cote B., Harrod J.F., Samuel E.
Canadian Journal of Chemistry , 1991
100.
100
V. V. Zolotarev
Chem. Abs. , 1941
101.
101
M. F. Shostakovskii
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
106.
Synthesis and properties of some novel bis(cyclopentadienyl)silyltitanium(III) complexes
Samuel E., Mu Y., Harrod J.F., Dromzee Y., Jeannin Y.
Journal of the American Chemical Society , 1990
108.
Synthesis and Crystal Structure of Some Novel Titanocene Phosphido Compounds by P−H Activation in the Presence of Hydrosilanes
Xin S., Woo H.G., Harrod J.F., Samuel E., Lebuis A.
Journal of the American Chemical Society , 1997
110.
110
M. F. Shostakovskii
Dokl. Akad. Nauk SSSR , 1960
112.
Low Temperature Wurtz-Type Polymerization of Substituted Dichlorosilanes
Miller R.D., Ginsburg E.J., Thompson D.
Polymer Journal , 1993
113.
113
H. Blum
"Photodynamic Action and Diseases caused Light" , 1940
115.
Sacrificial Additives in the Wurtz Synthesis of Polysilanes
Miller R.D., Jenkner P.K.
Macromolecules , 1994
116.
116
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
118.
118
V. M. Rodionov
Zhur. Obshch. Khim. , 1935
119.
119
V. V. Levchenko
Zhur. Obshch. Khim. , 1947
120.
The action of tris(triphenylphosphine)chlororhodium on polyhydromonosilanes
Ojima I., Inaba S., Kogure T., Nagai Y.
Journal of Organometallic Chemistry , 1973
123.
123
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
124.
Dehydrogenative coupling of diarylsilanes
Chang L.S., Corey J.Y.
Organometallics , 1989
125.
Catalytic dehydrogenative coupling of secondary silanes with Cp2MCl2-BuLi
Corey J.Y., Zhu X.H., Bedard T.C., Lange L.D.
Organometallics , 1991
127.
127
R. Pasternak
Helv. Chim. Acta , 1948
129.
Dehydrogenative Coupling of Alkyl or Arylsilanes Catalyzed by Ti(O-i-Pr)4.
SAKAKURA T., LAGADEC R.L., TANAKA M.
NIPPON KAGAKU KAISHI , 1996
130.
130
J. Wiemann
Bull. Soc. chim. France , 1958
131.
131
N. Thooi
Compt. rend. , 1958
134.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
135.
One-step route to silicon carbide precursors by a tunable catalytic polycondensation
Corriu R.J., Enders M., Huille S., Moreau J.J.
Chemistry of Materials , 1994
137.
Selective free-radical halogenation of poly(phenylsilane)
Banovetz J.P., Hsiao Y.L., Waymouth R.M.
Journal of the American Chemical Society , 1993
138.
Stereoselectivity in the catalytic oligomerization of phenylsilane
Banovetz J.P., Stein K.M., Waymouth R.M.
Organometallics , 1991
139.
139
I. L. Knunyants
1959
140.
Condensation of primary silanes in the presence of Cp2MCl2/nBuLi (M Ti, Zr, Hf)
Corey J.Y., Xiao-Hong Z.
Journal of Organometallic Chemistry , 1992
141.
141
Friedl.
142.
142
1913
145.
145
Friedl.
146.
146
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1952
147.
147
Y. Sasada
Acta Cryst. , 1898
148.
148
P. Kresse
Chem. Abs. , 1960
150.
Ethylene polymerization by a cationic dicyclopentadienyl zirconium(IV) alkyl complex
Jordan R.F., Bajgur C.S., Willett R., Scott B.
Journal of the American Chemical Society , 1986
151.
151
V. M. Rodionov
Zhur. Obshch. Khim. , 1936
152.
152
W. Albert
Trans. Electrochem. Soc. , 1943
153.
.sigma.-Bond metathesis mechanism for dehydropolymerization of silanes to polysilanes by d0 metal catalysts
Woo H.G., Walzer J.F., Tilley T.D.
Journal of the American Chemical Society , 1992
156.
Synthetic, structural and reactivity studies with new group 4 transition-metal silyl complexes
Imori T., Heyn R.H., Don Tilley T., Rheingold A.L.
Journal of Organometallic Chemistry , 1995
158.
The X-ray crystal structures of the ansa-metallocenes, Me2C(C5H4)2MCl2 (M = Ti, Zr and Hf)
Shaltout R.M., Corey J.Y., Rath N.P.
Journal of Organometallic Chemistry , 1995
159.
159
J. Tafel
Z. Elektrochem. , 1911
160.
SiH-containing cyclosilanes and their behaviour in the dehydrogenative polymerization reaction
Hengge E., Gspaltl P., Pinter E.
Journal of Organometallic Chemistry , 1996
161.
161
Friedl.
162.
Dehydrocoupling of Silanes Catalyzed by Zirconocene- and Titanocene Alkyne Complexes
Peulecke N., Thomas D., Baumann W., Fischer C., Rosenthal U.
Tetrahedron Letters , 1997
165.
165
Friedl.
166.
166
1917
167.
167
Friedl.
168.
Syndiospecific propylene polymerizations with Group IVB metallocenes
Ewen J.A., Jones R.L., Razavi A., Ferrara J.D.
Journal of the American Chemical Society , 1988
169.
169
Friedl.
170.
Disproportionation of pentamethyldisilane and sym-tetramethyldisilane catalysed by platinum complexes
Yamamoto K., Okinoshima H., Kumada M.
Journal of Organometallic Chemistry , 1970
171.
Some aspects of organosilicon and ferrocene chemistry
Kumada M.
Journal of Organometallic Chemistry , 1995
174.
Dehydrogenative condensation of monohydrosilanes yielding disilanes in the presence of platinum complex catalysts
Tanaka M., Kobayashi T., Hayashi T., Sakakura T.
Applied Organometallic Chemistry , 1988
175.
Dehydrogenative coupling of heterocyclic dihydrosilanes
Corey J.Y., Chang L.S., Corey E.R.
Organometallics , 1987
177.
177
J. Henry
Proc. R. Irish Acad. , 1945
178.
Ruthenium complex-catalysed selective redistribution reaction of aryltrihydrosilanes and desilanative polymerization of bis(trihydrosilyl)benzenes
Sakakura T., Kumberger O., Tan R.P., Arthur M., Tanaka M.
Journal of the Chemical Society Chemical Communications , 1995
179.
179
Chem. Abs. , 1947
182.
Dimesitylsilyl derivatives of zirconium
Roddick D.M., Heyn R.H., Tilley T.D.
Organometallics , 1989
188.
An electrochemical method for the synthesis of silicon—silicon bonds
Hengge E., Firgoi H.
Journal of Organometallic Chemistry , 1981
189.
Electroreductive formation of polysilanes
Shono T., Kashimura S., Ishifune M., Nishida R.
Journal of the Chemical Society Chemical Communications , 1990
192.
Electrochemical Access to Di-, Tri-, and Polysilanes
Bordeau M., Biran C., Léger-Lambert M.-., Spirau F., Deffieux D.
ACS Symposium Series , 1994
193.
194
A. A. Vertman
"Svoistva Rasplavov Zheleza" (Properties of Iron Melts) , 1969
194.
195
M. Allen
J. Chem. Soc. , 1961
196.
197
J. Sicher
Chem. Listy , 1955
197.
Electroreductive synthesis of some functionalized polysilanes and related polymers
Kashimura S., Ishifune M., Bu H., Takebayashi M., Kitajima S., Yoshihara D., Nishida R., Kawasaki S., Murase H., Shono T.
Tetrahedron Letters , 1997
199.
201
A. Aladjem
1969
200.
202
G. Shiroa
Mem. Coll. Sci., Kyoto Univ. , 1930
201.
203
L. Andrieux
Compt. rend. , 1929
202.
Electrochemical Reactions of Organosilicon Compounds
Yoshida J.
Topics in Current Chemistry , 1994
203.
205
N. Bunge
Zhur. Russ. Fiz.-Khim. Obshch. , 1889
204.
206
J. Petersen
Z. Phys. Chem. , 1900
205.
207
F. Fichter
"Organische Elektrochemie" , 1942
206.
208
O. A. Reutov
"Teoreticheskie Problemy Organicheskoi Khimii" (Theoretical Problems in Organic Chemistry) , 1956
207.
Electrochemical Polymerization of Hydrosilane Compounds
Kimata Y., Suzuki H., Satoh S., Kuriyama A.
Organometallics , 1995
208.
Electrochemical Oxidation of Hydrosilanes. A Synthetic Approach to Halosilanes and Disilanes
Kunai A., Kawakami T., Toyoda E., Sakurai T., Ishikawa M.
Chemistry Letters , 1993
209.
211
C. Schall
Z. Elektrochem. , 1923
212.
214
L. V. Pavlova
1965
213.
Synthesis of Oligosilanes by Electrolysis of Hydrosilanes
Kimata Y., Suzuki H., Satoh S., Kuriyama A.
Chemistry Letters , 1994
214.
216
A. P. Tomilov
Zhur. Prikl. Khim. , 1959
215.
217
1925
216.
Mechanism of hydrogen transfer from metal hydrides
Klingler R.J., Mochida K., Kochi J.K.
Journal of the American Chemical Society , 1979
217.
219
G. I. Pustoshkin
Collected Papers "Biologicheskie Aktivnie Soedinenii" (Biologically Active Compounds) , 1955
218.
Configurations of silicon-centred radicals: the bis(trimethylsilyl)silyl radical
Jackson R.A., Rhodes C.J.
Journal of Organometallic Chemistry , 1987
219.
Silyl Radicals. Formation and Reactions of Cyclopropyldimethylsilyl Radicals
Sakurai H., Hosomi A., Kumada M.
Bulletin of the Chemical Society of Japan , 1967
220.
222
Chem. Abs. , 1961
221.
223
1959
222.
224
Chem. Abs. , 1959
223.
225
1960
224.
COVALENT ORGANODIELEMENTARY COMPOUNDS
Vyazankin N.S., Kruglaya O.A.
Russian Chemical Reviews , 1966
225.
228
B. Roetheke
Chem. Abs. , 1959
226.
Mixed Organic Derivatives of Mercury and Silicon
Voronkov M.G., Chernov N.F.
Russian Chemical Reviews , 1979
227.
Neues aus der Chemie der Metallsilyle M(SiR3)n
Wiberg E., Stecher O., Andrascheck H.-., Kreuzbichler L., Staude E.
Angewandte Chemie , 1963
228.
Synthesis and properties of ethyl(trichlorosilyl) mercury and trichlorosilylmercury halides
Marano G.A., MacDiarmid A.G.
Inorganic and Nuclear Chemistry Letters , 1969
230.
234
Ebach E A
Chem. Abs. , 1966
231.
Reactions of bis(trimethylsilyl)mercury with organic compounds containing oxygen, nitrogen, or halogen
Beaumont A.G., Eaborn C., Jackson R.A., Walsingham R.W.
Journal of Organometallic Chemistry , 1966
232.
Organosilicon compounds. Part XLIX. Some reactions of bis(triphenylsilyl)mercury
Eaborn C., Jackson R.A., Rahman M.T.
Journal of the Chemical Society Perkin Transactions 2 , 1972
233.
Organosilicon compounds. Part L. Kinetics of the thermal decomposition of bis(trimethylsilyl)mercury in solution
Eaborn C., Jackson R.A., Walsingham R.W.
Journal of the Chemical Society Perkin Transactions 2 , 1973
234.
The preparation and reactions of an optically-active silyl-mercurial
Eaborn C., Jackson R.A., Tune D.J., Walton D.R.
Journal of Organometallic Chemistry , 1973
237.
Synthesen mit verbindungen R3MHgMR3
Lehnig M., Werner F., Neumann W.P.
Journal of Organometallic Chemistry , 1975