Home / Articles / Relaxation properties of polymers and the physical network model

Relaxation properties of polymers and the physical network model

Vadim Isaakovich Irzhak 1
Vadim Isaakovich Irzhak
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
Published 30 November 1999
Communication , Volume 69, Issue 3, 261-278
12
Share
Cite this
GOST
 | 
Cite this
GOST
Irzhak V. I. Relaxation properties of polymers and the physical network model // Russian Chemical Reviews. 2000. Vol. 69. No. 3. pp. 261-278.
GOST all authors (up to 50)
Irzhak V. I. Relaxation properties of polymers and the physical network model // Russian Chemical Reviews. 2000. Vol. 69. No. 3. pp. 261-278.
RIS
 | 
Cite this
RIS
TY - JOUR
DO - 10.1070/RC2000v069n03ABEH000554
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n03ABEH000554
TI - Relaxation properties of polymers and the physical network model
T2 - Russian Chemical Reviews
AU - Irzhak, Vadim Isaakovich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 261-278
IS - 3
VL - 69
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
@article{2000_Irzhak,
author = {Vadim Isaakovich Irzhak},
title = {Relaxation properties of polymers and the physical network model},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n03ABEH000554},
number = {3},
pages = {261--278},
doi = {10.1070/RC2000v069n03ABEH000554}
}
MLA
Cite this
MLA
Irzhak, Vadim Isaakovich. “Relaxation properties of polymers and the physical network model.” Russian Chemical Reviews, vol. 69, no. 3, Nov. 2000, pp. 261-278. https://rcr.colab.ws/publications/10.1070/RC2000v069n03ABEH000554.
Views / Visits / Downloads
19 / 19 / 8

Abstract

The role of the physical network in the dynamics of macromolecules is considered. It is shown that experimental data are often inconsistent not only quantitatively but also qualitatively with the results obtained in terms of the widespread reptation model based on the concept of network entanglement. Evidence is given indicating that the network of physical bonds is the governing factor in the dynamics of macromolecules. The bibliography includes 218 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
Intermolecular interaction in polymers and the physical network model
Irzhak V.I., Korolev G.V., Solov'ev M.E.
Russian Chemical Reviews , 1997
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
5
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1953
6.
6
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1953
7.
Introduction
Advances in Polymer Science , 1997
9.
Introductory lecture
Flory P.J.
Faraday Discussions of the Chemical Society , 1974
10.
10
T. A. Kryukova
"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959
11.
11
T. T. Bannister
Diss. Abstr. , 1959
12.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
14.
14
V. B. Evstigneev
Zhur. Fiz. Khim. , 1958
15.
The Entanglement Concept in Polymer Systems
Porter R.S., Johnson J.F.
Chemical Reviews , 1966
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
17.
17
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
20.
Dynamics of Entangled Polymer Liquids: Do Linear Chains Reptate?
Lodge T.P., Rotstein N.A., Prager S.
Advances in Chemical Physics , 1990
21.
21
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
25.
Polymer Motion at the Crossover from Rouse to Reptation Dynamics
Richter D., Willner L., Zirkel A., Farago B., Fetters L.J., Huang J.S.
Macromolecules , 1994
26.
Conformation and dynamics of polymer chains in condensed systems
27.
DYNAMIC STRUCTURE FACTOR IN A BIDISPERSE POLYMER MELT
Wilson J.D., Loring R.F.
Journal of Chemical Physics , 1995
29.
Experimental studies of an entangled polystyrene solution in steady state mixed type flows
Yavich D., Mead D.W., Oberhauser J.P., Leal L.G.
Journal of Rheology , 1998
30.
NMR field gradient diffusometry of segment displacements in melts of entangled polymers
Fischer E., Kimmich R., Fatkullin N.
Journal of Chemical Physics , 1996
31.
MOLECULAR DYNAMICS SIMULATIONS OF POLYMER SYSTEMS
Dünweg B., Grest G.S., Kremer K.
Chaotic Processes in the Geological Sciences , 1998
32.
32
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
33.
Self Diffusion Coefficients and Atomic Mean-Squared Displacements in Entangled Hard Chain Fluids
Smith S.W., Hall C.K., Freeman B.D., McCormick J.A.
Chaotic Processes in the Geological Sciences , 1998
35.
35
Z. K. Maizus
Dokl. Akad. Nauk SSSR , 1960
42.
Relaxation of randomly cross-linked polymer melts
Duering E.R., Kremer K., Grest G.S.
Physical Review Letters , 1991
43.
Kinetics of End Crosslinking in Dense Polymer Melts
Grest G.S., Kremer K., Duering E.R.
Europhysics Letters , 1992
44.
Dynamics of model networks: the role of the melt entanglement length
Duering E.R., Kremer K., Grest G.S.
Macromolecules , 1993
45.
Structure and relaxation of end‐linked polymer networks
Duering E.R., Kremer K., Grest G.S.
Journal of Chemical Physics , 1994
48.
48
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1955
49.
49
A. A. Krasnovskii
Biofizika , 1958
52.
52
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1957
55.
55
G. A. Bogdanovskii
1958
57.
57
R. Livingston
"Research in Photosynthesis" , 1957
58.
Connection between Polymer Molecular Weight, Density, Chain Dimensions, and Melt Viscoelastic Properties
Fetters L.J., Lohse D.J., Richter D., Witten T.A., Zirkel A.
Macromolecules , 1994
59.
59
H. Linshitz
"Research in Photosynthesis" , 1957
61.
Viscoelastic detergent solutions
Rehage H., Hoffmann H.
Faraday Discussions of the Chemical Society , 1983
62.
Rheology, Phase Equilibria and Processing of Lyotropic Liquid Crystalline Polymers
Kulichikhin V.G.
Molecular Crystals and Liquid Crystals Incorporating Nonlinear Optics , 1989
63.
Rheology of a Comblike Liquid Crystalline Polymer as a Function of Its Molecular Weight
Fourmaux-Demange V., Brûlet A., Cotton J.P., Hilliou L., Martinoty P., Keller P., Boué F.
Macromolecules , 1998
64.
Viscosity of linear and branched polymers in concentrated solutions and melt
Utracki L.A.
Journal of Polymer Science Part C Polymer Letters , 1973
65.
Effect of long-chain branching on the rheology of 1,4-polyisoprene
Santangelo P.G., Roland C.M.
Journal of Non-Crystalline Solids , 1998
66.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
68.
Entanglement scaling in polymer melts and solutions
Kavassalis T.A., Noolandi J.
Macromolecules , 1989
69.
69
B. Commoner
1958
70.
Steady shear viscosity of weakly aggregating polystyrene latex dispersions
de Rooij R., Potanin A.A., van den Ende D., Mellema J.
Journal of Chemical Physics , 1993
71.
71
Yu. A. Shlyapnikov
Vysokomol. Soed. , 1962
72.
72
A. F. Lukovnikov
"Starenie i Stabilizatsiya Polimerov" (Aging arid Stabilisation of Polymers) , 1963
73.
73
T. Skwarski
Chem. Abs. , 1957
74.
Extrapolation formulas for polymer solution properties
Muthukumar M., Edwards S.F.
Journal of Chemical Physics , 1982
75.
Solutions of Flexible Polymers. Neutron Experiments and Interpretation
Daoud M., Cotton J.P., Farnoux B., Jannink G., Sarma G., Benoit H., Duplessix C., Picot C., de Gennes P.G.
Macromolecules , 1975
76.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
77.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
78.
78
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
79.
Temperature coefficients for the chain dimensions of polystyrene and polymethylmethacrylate
Boothroyd A.T., Rennie A.R., Wignall G.D.
Journal of Chemical Physics , 1993
82.
Crossover scaling in semidilute polymer solutions: a Monte Carlo test
Paul W., Binder K., Heermann D.W., Kremer K.
Journal de Physique II , 2003
83.
83
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
85.
85
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1947
86.
86
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1958
87.
87
J. F. Arens
"Advances in Organic Chemistry" , 1960
88.
88
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1946
89.
89
A. A. Krasnovskii
Izd. Akad. Nauk SSSR, Moscow , 1955
90.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
91.
91
L. M. Vorob'eva
Biokhimiya , 1956
93.
93
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1956
94.
94
A. A. Krasnovskii
Fiziologiya Rastenii , 1957
95.
95
A. A. Krasnovskii
Fiziologiya Rastenii , 1957
96.
On Concentration Dependence of Polymer Solution Viscosity
Irzhak V.I.
International Journal of Polymeric Materials and Polymeric Biomaterials , 1980
97.
97
A. N. Terenin
Dokl. Akad. Nauk SSSR , 1952
98.
Viscosities of concentrated polymer solutions. II. Polyisobutylene
Johnson M.F., Evans W.W., Jordan I., Ferry J.D.
Journal of Colloid Science , 1952
99.
99
V. V. Zolotarev
1938
100.
Rheologische untersuchungen an polyvinylacetat-Lösungen
Schurz V.J., Müller K.
Die Makromolekulare Chemie , 1969
103.
The melt viscosity-molecular weight relationship for linear polymers
Colby R.H., Fetters L.J., Graessley W.W.
Macromolecules , 1987
104.
Self-diffusion and spin-spin relaxation in cyclic and linear polydimethylsiloxane melts
Cosgrove T., Griffiths P.C., Hollingshurst J., Richards R.D., Semlyen J.A.
Macromolecules , 1992
106.
Viscosity and self-diffusion coefficient of hydrogenated polybutadiene
Pearson D.S., Fetters L.J., Graessley W.W., Ver Strate G., von Meerwall E.
Macromolecules , 1994
107.
Range of validity of the hydrodynamic scaling model
Phillies G.D.
The Journal of Physical Chemistry , 1992
111.
Anomalous Segment Diffusion in Polydimethylsiloxane Melts
Pahl S., Fleischer G., Fujara F., Geil B.
Macromolecules , 1997
112.
Self-diffusion of polystyrene in solution 1. Experimental results of the NMR pulsed field gradient technique
Fleischer G., Zgadzai O.E., Skirda V.D., Maklakov A.I.
Colloid and Polymer Science , 1988
118.
118
V. M. Rodionov
Zhur. Obshch. Khim. , 1935
119.
10.1002/(SICI)1099-0488(19970115)35:1<1::AID-POLB1>3.0.CO;2-#
120.
Dynamics of polymer solutions and melts. Reptation predictions and scaling of relaxation times
Paul W., Binder K., Heermann D.W., Kremer K.
Journal of Chemical Physics , 1991
121.
Does reptation describe the dynamics of entangled, finite length polymer systems? A model simulation
124.
124
V. V. Levchenko
Zhur. Obshch. Khim. , 1952
126.
126
J. Wiemannand Ch. Clachet
Compt. rend. , 1948
127.
Stress Relaxation and Creep Master Curves for Several Monodisperse Polystyrenes
Aklonis J.J., Tobolsky A.V.
Journal of Applied Physics , 1965
128.
128
J. Wiemann
Bull. Soc. chim. France , 1952
131.
131
N. Thooi
Compt. rend. , 1958
132.
Linear elastico-viscous properties of molten standard polystyrenes
Schausberger A., Schindlauer G., Janeschitz-Kriegl H.
Rheologica Acta , 1985
133.
Molecular motion in glass-forming systems
Williams G.
Journal of Non-Crystalline Solids , 1991
134.
The relaxation of polymers with linear flexible chains of uniform length
Baumgaertel M., Schausberger A., Winter H.H.
Rheologica Acta , 1990
135.
135
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1945
137.
An explanation of anomalous dielectric relaxation properties of polypropylene glycol
141.
Infrared dichroism measurements of molecular relaxation in binary blend melt rheology
143.
Oligomers as molecular probes of orientational coupling interactions in polymer melts and networks
148.
Contribution to a Liquid‐Like Theory of Rubber Elasticity
DiMarzio E.A.
Journal of Chemical Physics , 1962
149.
Short-Range Order in Deformed Polymer Networks
Tanaka T., Allen G.
Macromolecules , 1977
151.
Molecular weight dependence of component dynamics in bidisperse melt rheology
Ylitalo C.M., Kornfield J.A., Fuller G.G., Pearson D.S.
Macromolecules , 1991
152.
Relaxation dynamics of selected polymer chain segments and comparison with theoretical models
Ylitalo C.M., Fuller G.G., Abetz V., Stadler R., Pearson D.S.
Rheologica Acta , 1990
153.
Solvent vs. segment orientation in strained swollen elastomeric networks
Toriumi H., Deloche B., Herz J., Samulski E.T.
Macromolecules , 1985
155.
Orientation of rigid rods dissolved in deformed networks
159.
Orientation and linear dichroism of symmetrical aromatic molecules imbedded in stretched polyethylene
162.
Diffusion and relaxation in oriented polymer media
Merrill W.W., Tirrell M., Tassin J.F., Monnerie L.
Macromolecules , 1989
163.
Dynamics of reversible networks
Leibler L., Rubinstein M., Colby R.H.
Macromolecules , 1991
165.
Dynamics of hydrogen bond complexes in polymer melts
Stadler R., de Lucca Freitas L.
Colloid and Polymer Science , 1988
167.
Hydrogen bonds in unpolar matrix — Comparison of complexation in polymeric and low molecular-weight systems
de Lucca Freitas L., Auschra C., Abetz V., Stadler R.
Colloid and Polymer Science , 1991
169.
On the Motional Coupling between Chain and Junction Dynamics in Thermoreversible Networks
Mueller M., Stadler R., Kremer F., Williams G.
Macromolecules , 1995
170.
Junction Dynamics in Telechelic Hydrogen Bonded Polyisobutylene Networks
Müller M., Dardin A., Seidel U., Balsamo V., Iván B., Spiess H.W., Stadler R.
Macromolecules , 1996
171.
171
Friedl.
172.
172
1918
173.
173
Friedl.
174.
LIGHT-SCATTERING-STUDIES ON LONG-RANGE DENSITY-FLUCTUATIONS IN A GLASS-FORMING POLYMER
Kanaya T., Patkowski A., Fischer E.W., Seils J., Gläser H., Kaji K.
Acta Polymerica , 1994
175.
Conformational Order in Molten Amorphous Poly(ethyl methacrylate)
Kulik A.S., Radloff D., Spiess H.W.
Macromolecules , 1994
176.
176
G. V. Samsonov
"Metody Ispytaniya na Mikrotverdost' i Pribory" (Methods of Microhardness Testing and Apparatus) , 1965
178.
Long-lived interchain contacts in polymer melts
Szamel G., Wang T.
Journal of Chemical Physics , 1997
182.
182
1947
183.
183
Chem. Abs. , 1947
184.
Nanoscale heterogeneity if glass-forming liquids: experimental advances
Böhmer R.
Current Opinion in Solid State and Materials Science , 1998
188.
188
Chem. Abs. , 1955
189.
189
M. Godchot
Bull. Soc. chim. France (5) , 1913
190.
190
H. Law
J. Chem. Soc. , 1912
191.
Individual entanglements in a simulated polymer melt
Ben-Naim E., Grest G.S., Witten T.A., Baljon A.R.
Physical Review E , 1996
195.
A model for the plateau in the relaxation modulus for linear chain polymer melts
Herman M.F., Panajotova B.V.
Computational and Theoretical Polymer Science , 1997
198.
Dynamics of weakly-coupled linear macromolecules
201.
Crossover to entangled dynamics in polymer solutions and melts
Schweizer K.S., Szamel G.
Journal of Chemical Physics , 1995
202.
Mode‐coupling theory for self‐diffusion in polymer blends and blend solutions
203.
Polymer-mode-coupling theory of the slow dynamics of entangled macromolecular fluids
Schweizer K.S., Fuchs M., Szamel G., Guenza M., Tang H.
Macromolecular Theory and Simulations , 1997
205.
The Hartree approximation in dynamics of polymeric manifolds in the melt
Rostiashvili V.G., Rehkopf M., Vilgis T.A.
Journal of Chemical Physics , 1999
206.
Rouse's dynamics of networks with pendant chains
Vega D.A., Villar M.A., Alessandrini J.L., Vall�s E.M.
Journal of Polymer Science, Part B: Polymer Physics , 1999
207.
Comparison of Polymer Dynamics between Entanglements and Covalent Cross-Links
Nicolai T., Prochazka F., Durand D.
Physical Review Letters , 1999
208.
208
O. A. Reutov
"Teoreticheskie Problemy Organicheskoi Khimii" (Theoretical Problems in Organic Chemistry) , 1956
209.
Long-ranged Relaxations in Poly(ethylene oxide) Melts
Walkenhorst R., Selser J.C., Piet G.
Journal of Chemical Physics , 1998
210.
210
H. L. Wheeler
Chem. Zentr. , 1908
211.
211
C. Schall
Z. Elektrochem. , 1923
212.
212
L. V. Pavlova
Zh. Obshch. Khim. , 1965
213.
A new transient network model for associative polymer networks
Wientjes R.H., Jongschaap R.J., Duits M.H., Mellema J.
Journal of Rheology , 1999
214.
Onset of polymer entanglement
Chitanvis S.M.
Physical Review E , 1998
215.
Determination of Plateau Moduli and Entanglement Molecular Weights of Isotactic, Syndiotactic, and Atactic Polypropylenes Synthesized with Metallocene Catalysts
Eckstein A., Suhm J., Friedrich C., Maier R.-., Sassmannshausen J., Bochmann M., Mülhaupt R.
Macromolecules , 1998
216.
216
A. P. Tomilov
Zhur. Prikl. Khim. , 1959
217.
217
1925
218.
218
Chem. Zentr. II , 1925
219.
219
G. I. Pustoshkin
Collected Papers "Biologicheskie Aktivnie Soedinenii" (Biologically Active Compounds) , 1955