Abstract
Phase relations in the subsolidus region are considered for 54 ternary systems including M2O3–V2O5–R2O5, Y2O3 (La2O3, Sc2O3)–Nb2O5–Ta2O5, M2O3–B2O3–R2O5, M2O3–Ga2O3–R2O5, Al2O3–V2O5–R2O5 (where M is a rare-earth element and R = Ta, Nb). The criteria determining the formation of ternary oxide compounds were found to include the cation sizes and the ratios between the radii of the ions constituting the anionic part of the compounds. The crystal-chemical characteristics are presented for MR2VO9, LaRB2O7, La4VBO10, Ln7VBO17 (Ln = La, Pr, Nd), La3Ga5.5R0.5O14. The vibrational spectra of polycrystals of ternary compounds and solid solutions based on them are described in detail. The bibliography includes 154 references.
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