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Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium

Konstantin Nikolaevich Gavrilov 1
Konstantin Nikolaevich Gavrilov
, 
Aleksei Ivanovich Polosukhin 2
Aleksei Ivanovich Polosukhin
1 Ryazan State Pedagogical University
2 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
10.1070/RC2000v069n08ABEH000559
Published 30 November 1999
Communication , Volume 69, Issue 8, 661-682
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Gavrilov K. N., Polosukhin A. I. Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium // Russian Chemical Reviews. 2000. Vol. 69. No. 8. pp. 661-682.
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Gavrilov K. N., Polosukhin A. I. Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium // Russian Chemical Reviews. 2000. Vol. 69. No. 8. pp. 661-682.
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TY - JOUR
DO - 10.1070/RC2000v069n08ABEH000559
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n08ABEH000559
TI - Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium
T2 - Russian Chemical Reviews
AU - Gavrilov, Konstantin Nikolaevich
AU - Polosukhin, Aleksei Ivanovich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 661-682
IS - 8
VL - 69
ER -
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@article{2000_Gavrilov,
author = {Konstantin Nikolaevich Gavrilov and Aleksei Ivanovich Polosukhin},
title = {Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n08ABEH000559},
number = {8},
pages = {661--682},
doi = {10.1070/RC2000v069n08ABEH000559}
}
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Gavrilov, Konstantin Nikolaevich, and Aleksei Ivanovich Polosukhin. “Chiral P,N-bidentate ligands in coordination chemistry and organic catalysis involving rhodium and palladium.” Russian Chemical Reviews, vol. 69, no. 8, Nov. 2000, pp. 661-682. https://rcr.colab.ws/publications/10.1070/RC2000v069n08ABEH000559.
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Abstract

Published data on the synthesis of rhodium and palladium complexes with optically active P,N-bidentate ligands and their applications in homogeneous asymmetric catalysis are summarised and discussed. The effect of the nature of the P,N-bidentate compounds on the structure of the metal complexes and on enantioselectivity in catalysis is examined. Allylic substitution, cross-coupling, hydroboration and hydrosilylation catalysed by Rh or Pd complexes with optically active P,N-bidentate ligands are considered. The prospects for the development of this field of chemistry are demonstrated. The bibliography includes 186 references.

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