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Structural and dynamic properties of tetrahydroborate complexes

Viktor Dmitrievich Makhaev 1
Viktor Dmitrievich Makhaev
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2000v069n09ABEH000580
Published 30 November 1999
Communication , Volume 69, Issue 9, 727-746
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Makhaev V. D. Structural and dynamic properties of tetrahydroborate complexes // Russian Chemical Reviews. 2000. Vol. 69. No. 9. pp. 727-746.
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Makhaev V. D. Structural and dynamic properties of tetrahydroborate complexes // Russian Chemical Reviews. 2000. Vol. 69. No. 9. pp. 727-746.
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TY - JOUR
DO - 10.1070/RC2000v069n09ABEH000580
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n09ABEH000580
TI - Structural and dynamic properties of tetrahydroborate complexes
T2 - Russian Chemical Reviews
AU - Makhaev, Viktor Dmitrievich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 727-746
IS - 9
VL - 69
ER -
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@article{2000_Makhaev,
author = {Viktor Dmitrievich Makhaev},
title = {Structural and dynamic properties of tetrahydroborate complexes},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n09ABEH000580},
number = {9},
pages = {727--746},
doi = {10.1070/RC2000v069n09ABEH000580}
}
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Makhaev, Viktor Dmitrievich. “Structural and dynamic properties of tetrahydroborate complexes.” Russian Chemical Reviews, vol. 69, no. 9, Nov. 2000, pp. 727-746. https://rcr.colab.ws/publications/10.1070/RC2000v069n09ABEH000580.
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Abstract

Data on the structures of tetrahydroborate complexes from X-ray diffraction analysis, neutron and electron diffraction, and IR and NMR spectroscopy are considered. It is shown that, in addition to the diversity of stabilising ligands, complexes of Group III and IV transition metals are characterised by diverse types of coordination of terminal (η1, η2 and η3) and bridging (between neutral molecular units) tetrahydroborate groups. Compounds with BH4 groups with different denticities can be found among these complexes. Most tetrahydroborates of these metals in the oxidation states +3, +4 comply with the principle of maximum occupancy of the coordination sphere. Tetrahydroborates of Group III and IV metals exhibit clear-cut stereochemical non-rigidity (fluxionality): the protons of the BH4 ligand are equivalent on the NMR time scale. Group I and V–VIII transition metals mainly form η2-complexes, which are stereochemically much more rigid than complexes of Group III and IV metals. It is suggested that electronic configuration of the central atom is the crucial factor determining different structures and stereochemical behaviours of the tetrahydroborate complexes. Data on the structures and properties of post-transition and s-element tetrahydroborates are also consistent with this assumption. The bibliography includes 248 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
Metal Tetrahydroborates
James B.D., Wallbridge M.G.
Progress in Inorganic Chemistry , 1970
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
5
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1953
9.
Fluxionality in (BH4)Mn(CO)4 and (BH4)Cu(PH3)2
Oishi Y., albright T.A., Fujimoto H.
Polyhedron , 1995
10.
Hydride Exchange Processes in the Coordination Sphere of Transition Metal Complexes: The OsH3(BH4)(PR3)2 System
Demachy I., Esteruelas M.A., Jean Y., Lledós A., Maseras F., Oro L.A., Valero C., Volatron F.
Journal of the American Chemical Society , 1996
11.
11
T. T. Bannister
Diss. Abstr. , 1959
12.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
13.
Metallocene(III) tetrahydridoborates of the Group 3Aelements and the X-ray structure of [Sc{η-C5H3(SiMe3)2}2(µ-H)2BH2]
Lappert M.F., Singh A., Atwood J.L., Hunter W.E.
Journal of the Chemical Society Chemical Communications , 1983
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
18.
18
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1951
23.
Tertiary phosphine complexes of trivalent uranium: preparation and structure of U(BH4)3(dmpe)2(dmpe = Me2PCH2CH2PMe2)
Wasserman H.J., Moody D.C., Ryan R.R.
Journal of the Chemical Society Chemical Communications , 1984
24.
Tetrahydroborate complexes of uranium with 2-(diphenylphosphino)pyridine
Wasserman H.J., Moody D.C., Paine R.T., Ryan R.R., Salazar K.V.
Journal of the Chemical Society Chemical Communications , 1984
25.
Arene uranium borohydrides: synthesis and crystal structure of η-C6Me6)U(BH4)3
Baudry D., Bulot E., Charpin P., Ephritikhine M., Lance M., Nierlich M., Vigner J.
Journal of Organometallic Chemistry , 1989
26.
Synthesis of a uranium (IV) hydride from the corresponding borohydride: preparation of {(MeOCH2CH2OMe)U(BH4)3(µ-H)}2and the crystal structure of its toluene solvate
Baudry D., Charpin P., Ephritikhine M., Lance M., Nierlich M., Vigner J.
Journal of the Chemical Society Chemical Communications , 1987
28.
Inverse cycloheptatrienyl sandwich complexes. Crystal structure of [U(BH4)2(OC4H8)5][(BH4)3U(µ-η7,η7-C7H7)U(BH4)3]
Arliguie T., Lance M., Nierlich M., Vigner J., Ephritikhine M.
Journal of the Chemical Society Chemical Communications , 1994
29.
Insertion of trivalent uranium in macrocyclic crown-ethers: EXAFS and X-ray structural analyses
Dejean A., Charpin P., Folcher G., Rigny P., Navaza A., Tsoucaris G.
Polyhedron , 1987
30.
Structure of (tetrahydroborato)bis(tetrahydrofuran)uranium(IV): a model for hydrogen–uranium bonding
Charpin P., Nierlich M., Vigner D., Lance M., Baudry D.
Acta Crystallographica Section C Crystal Structure Communications , 1987
31.
Structure du complexe bis(oxyde de triphénylphosphine)tétrakis(tétrahydroborato)uranium(IV) solvaté avec le benzène
Charpin P., Lance M., Soulie E., Vigner D., Marquet-Ellis H.
Acta Crystallographica Section C Crystal Structure Communications , 1985
32.
Structure du complexe bis(oxyde de triphénylphosphine)tétrakis(tétrahydroborato)uranium(IV)
Charpin P., Nierlich M., Chevrier G., Vigner D., Lance M., Baudry D.
Acta Crystallographica Section C Crystal Structure Communications , 1987
33.
Synthesis and crystal structure of the volatile monocyclopentadienyl uranium complex (η-C5H5)U(BH4)3
Baudry D., Charpin P., Ephritikhine M., Folcher G., Lambard J., Lance M., Nierlich M., Vigner J.
Journal of the Chemical Society Chemical Communications , 1985
34.
Pentadienyluranium borohydride complexes and their cyclopentadienyl analogues; crystal structures of (η-2,4-Me2C5H5)U(BH4)3 and (η-C5H5)U(BH4)3
Baudry D., Bulot E., Charpin P., Ephritikhine M., Lance M., Nierlich M., Vigner J.
Journal of Organometallic Chemistry , 1989
36.
Synthesis, spectroscopic properties and crystal structures of [ML2Cl2][M = Th or U; L =η-C5H3(SiMe3)2-1,3] and [UL2X2](X = Br, I or BH4)
Blake P.C., Lappert M.F., Taylor R.G., Atwood J.L., Hunter W.E., Zhang H.
Journal of the Chemical Society Dalton Transactions , 1995
37.
Tetramethylphospholyluranium complexes and their pentamethylcyclopentadienyl analogues
Gradoz P., Baudry D., Ephritikhine M., Lance M., Nierlich M., Vigner J.
Journal of Organometallic Chemistry , 1994
38.
Chemical and structural aspects of cyclopentadienyl uranium(IV) tetrahydroborato complexes
Zanella P., Brianese N., Casellato U., Ossola F., Porchia M., Rossetto G., Graziani R.
Inorganica Chimica Acta , 1988
40.
Structure of bis[(1,2,3,3a,7a-η)-indenyl]bis(tetrahydroborato)uranium(IV)
Rebizant J., Spirlet M.R., Bettonville S., Goffart J.
Acta Crystallographica Section C Crystal Structure Communications , 1989
41.
41
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1950
42.
Influence of electronic factors on the structure and stability of uranium compounds. Tri-tert-butyl methoxide uranium(IV) complexes
Baudin C., Baudry D., Ephritikhine M., Lance M., Navaza A., Nierlich M., Vigner J.
Journal of Organometallic Chemistry , 1991
43.
Monocyclooctatetraenyluranium(IV) borohydrides. Crystal structure of (η-C8H8)U(BH4)2(OPPh3)
Baudry D., Bulot E., Ephritikhine M., Nierlich M., Lance M., Vigner J.
Journal of Organometallic Chemistry , 1990
45.
Exploring the auxiliary co-ordination sphere of tripodal amino(triamido) actinide complexes
Scott P., Hitchcock P.B.
Journal of the Chemical Society Dalton Transactions , 1995
47.
Volatility and molecular structure of neptunium(IV) borohydride
Banks R.H., Edelstein N.M., Spencer B., Templeton D.H., Zalkin A.
Journal of the American Chemical Society , 1980
48.
Preparation and properties of the actinide borohydrides: protactinium(IV), neptunium(IV), and plutonium(IV) borohydrides
Banks R.H., Edelstein N.M., Rietz R.R., Templeton D.H., Zalkin A.
Journal of the American Chemical Society , 1978
49.
Molecular structure of gaseous titanium tris(tetrahydroborate), Ti(BH4)3: experimental determination by electron diffraction and molecular orbital analysis of some Ti(BH4)3 derivatives
Dain C.J., Downs A.J., Goode M.J., Evans D.G., Nicholls K.T., Rankin D.W., Robertson H.E.
Journal of the Chemical Society Dalton Transactions , 1991
50.
50
G. Glacomello
Gazzetta. , 1935
51.
51
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
53.
Divalent titanium chemistry. Synthesis, reactivity, and x-ray and neutron diffraction studies of Ti(BH4)2(dmpe)2 and Ti(CH3)2(dmpe)2
Jensen J.A., Wilson S.R., Schultz A.J., Girolami G.S.
Journal of the American Chemical Society , 1987
59.
59
H. Linshitz
"Research in Photosynthesis" , 1957
63.
Cyclische metallamide: III. Flüchtige tetrahydroborat-komplexe von titan und zirkonium
Herrmann W.A., Denk M., Scherer W., Klingan F.
Journal of Organometallic Chemistry , 1993
64.
Titanium(IV) and zirconium(IV) tetrahydroborate moieties supported by a phenoxo ligand
Corazza F., Floriani C., Chiesi-Villa A., Guastini C.
Inorganic Chemistry , 1991
67.
The crystal structure of zirconium(IV) borohydride (at –160°)
Bird P.H., Churchill M.R.
Chemical Communications (London) , 1967
68.
68
N. N. Mel'nikov
Zhur. Obshch. Khim. , 1946
69.
Bis(tetrahydroborato)bis(cyclopentadienyl)zirconium(IV)
Smith B.E., James B.D., Dilts J.A.
Journal of Inorganic and Nuclear Chemistry , 1976
70.
Geometry and electronic structure of bis(tetrahydridoborato)bis(cyclopentadienyl)zirconium(IV)
Sztáray B., Rosta E., Böcskey Z., Szepes L.
Journal of Organometallic Chemistry , 1999
75.
A zirconium polyhydride dimer, [Zr2H4(BH4)4(PMe3)4]
Mayo S.C., Bown M., Lloyd V.K.
Acta Crystallographica Section C Crystal Structure Communications , 1994
76.
Zirconium and hafnium polyhydrides. 2. Preparation and characterization of M3H6(BH4)6(PMe3)4 and M2H4(BH4)4(dmpe)2
Gozum J.E., Wilson S.R., Girolami G.S.
Journal of the American Chemical Society , 1992
80.
Raman and infrared spectra of hafnium tetrakis(tetrahydroborate) and hafnium tetrakis(tetrahydroborate-d16). Evidence for hafnium-boron bonding
Keiderling T.A., Wozniak W.T., Gay R.S., Jurkowitz D., Bernstein E.R., Lippard S.J., Spiro T.G.
Inorganic Chemistry , 1975
81.
Vibrational spectra of zirconium tetrahydroborate and related molecules
Davies N., Wallbridge M.G., Smith B.E., James B.D.
Journal of the Chemical Society Dalton Transactions , 1973
86.
Monocyclopentadienylvanadium(III) and -vanadium(II) methyl, phenyl, and borohydride compounds
Hessen B., Teuben J.H., Lemmen T.H., Huffman J.C., Caulton K.G.
Organometallics , 1985
87.
Paramagnetic monocyclopentadienyl hydrocarbyl and borohydride compounds of vanadium(II) and vanadium(III). Synthesis, structure, and reactivity
Hessen B., Lemmen T.H., Luttikhedde H.J., Teuben J.H., Petersen J.L., Huffman J.C., Jagner S., Caulton K.G.
Organometallics , 1987
89.
Monomeric and dimeric V(III) complexes supported by organic amides
Berno P., Moore M., Minhas R., Gambarotta S.
Canadian Journal of Chemistry , 1996
90.
90
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1951
93.
Preparation and characterization of a new series of Cr(II) hydroborates
Dionne M., Hao S., Gambarotta S.
Canadian Journal of Chemistry , 1995
95.
Structural characterizations of salts of HCr(CO)5- and (μ-H)2BH2Cr(CO)4- and studies of their interconversions
Darensbourg M.Y., Bau R., Marks M.W., Burch R.R., Deaton J.C., Slater S.
Journal of the American Chemical Society , 1982
96.
Chemistry, structure, and molecular dynamics of the tetrahydroboratotetracarbonylmolybdate(1-) anion, Mo(CO)4BH4-
Kirtley S.W., Andrews M.A., Bau R., Grynkewich G.W., Marks T.J., Tipton D.L., Whittlesey B.R.
Journal of the American Chemical Society , 1977
97.
Synthesis and crystal structure of hydrido(tetrahydroborato)tetrakis(trimethylphosphine)molybdenum(II)
Atwood J.L., Hunter W.E., Carmona-Guzman E., Wilkinson G.
Journal of the Chemical Society Dalton Transactions , 1980
99.
99
V. V. Zolotarev
1938
100.
100
V. V. Zolotarev
Chem. Abs. , 1941
101.
101
M. F. Shostakovskii
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
102.
Synthesis and molecular structure of hydrido(tetrahydroborato)(1,1,1-tris(diphenylphosphinomethyl)ethane)-iron(II)
Ghilardi C.A., Innocenti P., Midollini S., Orlandini A.
Journal of Organometallic Chemistry , 1982
103.
Synthesis, characterization, and structure of the complex [FeH(H2BH2){CH3C(CH2PPh2)3}]
Ghilardi C.A., Innocenti P., Midollini S., Orlandini A.
Journal of the Chemical Society Dalton Transactions , 1985
105.
An osmium tetrahydroborate complex with unusual dynamic behaviour: X-ray crystal structure of [Os(BH4)H3{P(c-C5H9)3}2](c-C5H9= cyclo-C5H9)
Frost P.W., Howard J.A., Spencer J.L.
Journal of the Chemical Society Chemical Communications , 1984
106.
Preparation, unusual spectral properties, and structural characterization of (terpyridine)(tetrahydroborato-H,H')cobalt
Corey E.J., Cooper N.J., Canning W.M., Lipscomb W.N., Koetzle T.F.
Inorganic Chemistry , 1982
107.
Synthesis and molecular structure of a paramagnetic hydridotetrahydroborato complex of cobalt: hydridotetrahydroboratobis(tricyclohexylphosphine)cobalt
Nakajima M., Moriyama H., Kobayashi A., Saito T., Sasaki Y.
Journal of the Chemical Society Chemical Communications , 1975
108.
Crystal and molecular structure of a paramagnetic hydridotetrahydro-borato-complex of cobalt: hydridotetrahydroboratobis(tricyclohexylphosphine)cobalt
Nakajima M., Saito T., Kobayashi A., Sasaki Y.
Journal of the Chemical Society Dalton Transactions , 1977
111.
Crystal and molecular structure of hydrido(tetrahydroborato)bis(tricyclohexylphosphine)nickel(II)
Saito T., Nakajima M., Kobayashi A., Sasaki Y.
Journal of the Chemical Society Dalton Transactions , 1978
112.
Studies on tertiary phosphine–hydride and –hydridoborohydride compounds of nickel and palladium
Green M.L., Munakata H., Saito T.
Journal of the Chemical Society A Inorganic Physical Theoretical , 1971
113.
(2,9-Dimethyl-1,10-phenanthroline)tetrahydroboratocopper(I)
Green B.E., Kennard C.H., Hawkins C.J., Smith G., James B.D., White A.H.
Acta Crystallographica Section B , 1980
115.
115
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1957
117.
117
V. V. Levchenko
Zhur. Obshch. Khim. , 1948
118.
118
V. M. Rodionov
Zhur. Obshch. Khim. , 1935
119.
119
V. V. Levchenko
Zhur. Obshch. Khim. , 1947
125.
Neutron and x-ray diffraction studies of tris(methyldiphenylphosphine)[tetrahydroborato(1-)]copper, Cu[P(C6H5)2CH3]3(BH4). The first accurate characterization of an unsupported metal-hydrogen-boron bridge bond
Takusagawa F., Fumagalli A., Koetzle T.F., Shore S.G., Schmitkons T., Fratini A.V., Morse K.W., Wei C., Bau R.
Journal of the American Chemical Society , 1981
128.
128
J. Wiemann
Bull. Soc. chim. France , 1952
129.
129
J. Wiemann
Bull. Soc. chim. France , 1955
130.
130
J. Wiemann
Bull. Soc. chim. France , 1958
131.
131
N. Thooi
Compt. rend. , 1958
132.
132
G. Shima
Kyoto Univ. , 1929
133.
Hydride-bridged heterobimetallic complexes of gallium and zinc: the first X-ray structural determination of the gah4–moiety
Koutsantonis G.A., Iee F.C., Raston C.L.
Journal of the Chemical Society Chemical Communications , 1994
134.
134
V. V. Korshak
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1948
135.
135
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1945
136.
A bimetallic vanadium(I) polyhydride
Bansemer R.L., Huffman J.C., Caulton K.G.
Journal of the American Chemical Society , 1983
137.
Synthesis and molecular structure of the niobocenecarbonylhydride adduct to bis(tetrahydroborate)zinc
Porai-Koshits M.A., Antsyshkina A.S., Pasynskii A.A., Sadikov G.G., Skripkin Y.V., Ostrikova V.N.
Inorganica Chimica Acta , 1979
138.
Syntheses of the first molecular complexes containing a cadmium-cadmium bond and a cadmium-hydrogen bond
Reger D.L., Mason S.S., Rheingold A.L.
Journal of the American Chemical Society , 1993
139.
Gallaborane, H2Ga(µ-H)2BH2: synthesis, properties, and structure of the gaseous molecule as determined by electron diffraction
Pulham C.R., Brain P.T., Downs A.J., Rankin D.W., Robertson H.E.
Journal of the Chemical Society Chemical Communications , 1990
140.
Hydridogallium Bis(tetrahydroborate) in the Gas Phase: Vibrational Properties and Structure Determined by Electron Diffraction and ab Initio and Density Functional Theory Computations
Downs A.J., Greene T.M., Harman L.A., Souter P.F., Brain P.T., Pulham C.R., Rankin D.W., Robertson H.E., Hofmann M., Schleyer P.V.
Inorganic Chemistry , 1995
141.
Group 3 tetrahydroborates. Part 1. The synthesis and properties of dimethylgallium tetrahydroborate
Downs A.J., Thomas P.D.
Journal of the Chemical Society Dalton Transactions , 1978
146.
146
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1952
147.
Structural Chemistry of Lithium Tetrahydroborate Ether Solvates⋆
Giese H., Nöth H., Schwenk H., Thomas S.
European Journal of Inorganic Chemistry , 1998
148.
Metal Tetrahydridoborates and Tetrahydridoborato Metalates. 23.1 Amine Solvates of Lithium and Sodium Tetrahydridoborate
Giese H., Habereder T., Nöth H., Ponikwar W., Thomas S., Warchhold M.
Inorganic Chemistry , 1999
149.
Lithium‐7 and lithium‐6 NMR studies of solid complexes of lithium tetrahydroborate
Espidel J.E., Harris R.K., Wade K.
Magnetic Resonance in Chemistry , 1994
150.
150
Ya. E. Bernadskaya
"Iskusstvennoe Volokno" (Artificial Fibres) , 1952
151.
Drew D.A., Gundersen G., Haaland A., Enzell C.R., Svensson S.
Acta Chemica Scandinavica , 2008
152.
Vibrational spectra and torsional barrier of cyclopentadienyl beryllium borohydride, C5H5BeBH4
Coe D.A., Nibler J.W., Cook T.H., Drew D., Morgan G.L.
Journal of Chemical Physics , 1975
153.
Crystal and molecular structure of tetra-t-butoxytriberyllium bistetrahydroborate
Morosin B., Howatson J.
Journal of Inorganic and Nuclear Chemistry , 1979
154.
154
Friedl.
156.
156
J. S. Fruton
J. Biol. Med. , 1950
158.
Almenningen A., Gundersen G., Haaland A., Haug A., Enzell C., Francis G.
Acta Chemica Scandinavica , 2008
159.
Infrared and Raman spectra of aluminum borohydride, Al(BH4)3
Coe D.A., Nibler J.W.
Spectrochimica Acta Part A Molecular Spectroscopy , 1973
160.
Some tetrahydroborate derivatives of aluminium: crystal structures of dimethylaluminium tetrahydroborate and the α and β phases of aluminium tris(tetrahydroborate) at low temperature
Aldridge S., Blake A.J., Downs A.J., Gould R.O., Parsons S., Pulham C.R.
Journal of the Chemical Society Dalton Transactions , 1997
162.
Preparation and properties of methylaluminium tetrahydroborates and their reactions with some Lewis bases
Oddy P.R., Wallbridge M.G.
Journal of the Chemical Society Dalton Transactions , 1976
163.
Group 3 tetrahydroborates. Part 3. The molecular structure of methylaluminium bis(tetrahydroborate) in the gas phase as determined by electron diffraction
Barlow M.T., Dain C.J., Downs A.J., Thomas P.D., Rankin D.W.
Journal of the Chemical Society Dalton Transactions , 1980
164.
164
1917
165.
Crystal structure of aluminum tetrahydroborate-trimethylamine at 25 and -160.deg.
Bailey N.A., Bird P.H., Wallbridge M.G.
Inorganic Chemistry , 1968
166.
Spectroscopic studies on derivatives of aluminium borohydride
Davies N., Bird P.H., Wallbridge M.G.
Journal of the Chemical Society A Inorganic Physical Theoretical , 1968
167.
167
Friedl.
168.
Dimethylsiloxy-aluminiumdihalide dimers. Molecular structures of [Me2HSiOAlX2]2 (X Cl, I) and [Me3SiOAl(BH4)2]2
Bissinger P., Mikulcik P., Riede J., Schier A., Schmidbaur H.
Journal of Organometallic Chemistry , 1993
169.
Borohydride, hydride, halide, and carbonyl derivatives of bis(pentamethylcyclopentadienyl)niobium
Bell R.A., Cohen S.A., Doherty N.M., Threlkel R.S., Bercaw J.E.
Organometallics , 1986
170.
Studies on bis(η-indenyl)niobium complexes
Green M.L., Hughes A.K.
Journal of the Chemical Society Dalton Transactions , 1992
171.
Hydrogen scrambling processes in [Ta(η-C5Me5)(η-C5H5){(µ-H)2BH2}]: a surprising observation
Green M.L., Wong L.
Journal of the Chemical Society Chemical Communications , 1989
172.
Tetrahydroborate complexes of tantalum: synthesis, characterization, and reactivity of Ta(BH4)H2(PMe3)4
Luetkens M.L., Huffman J.C., Sattelberger A.P.
Journal of the American Chemical Society , 1985
176.
Classical and Nonclassical Nitrosyl Hydride Complexes of Rhenium in Various Oxidation States
Gusev D., Llamazares A., Artus G., Jacobsen H., Berke H.
Organometallics , 1998
177.
The structure and properties of HFe3(CO)9BH3R and the conjugate bases [HFe3(CO)9BH2R]- (R = H and CH3). Inorganometallic analogs of hydrocarbyltriiron clusters
Vites J., Housecroft C.E., Eigenbrot C., Buhl M.L., Long G.J., Fehlner T.P.
Journal of the American Chemical Society , 1986
178.
Dinuclear (Arene)ruthenium Hydrido Complexes:  Synthesis, Structure, and Fluxionality of (C6Me6)2Ru2H3(BH4)
Jahncke M., Meister G., Rheinwald G., Stoeckli-Evans H., Süss-Fink G.
Organometallics , 1997
179.
Some new π-cyclopentadienylruthenium complexes
Blackmore T., Bruce M.I., Stone F.G.
Journal of the Chemical Society A Inorganic Physical Theoretical , 1971
180.
Trihydridoruthenium(IV) complexes: preparation and photo-induced H/D exchange reaction
Suzuki H., Hwan Lee D., Oshima N., Moro-Oka Y.
Journal of Organometallic Chemistry , 1986
181.
Borohydride/ethanol reduction of RuCl3(PMe2Ph)3
Bruno J.W., Huffman J.C., Caulton K.G.
Inorganica Chimica Acta , 1984
185.
Use of the new ligand P(CH2CH2PCy2)3 in the synthesis of dihydrogen complexes of iron(II) and ruthenium(II)
Jia G., Drouin S.D., Jessop P.G., Lough A.J., Morris R.H.
Organometallics , 1993
186.
Classical and nonclassical polyhydride ruthenium(II) complexes stabilized by the tetraphosphine P(CH2CH2PPh2)3
Bianchini C., Perez P.J., Peruzzini M., Zanobini F., Vacca A.
Inorganic Chemistry , 1991
187.
187
1954
188.
η2‐Tetrahydroborato)ruthenium(II)‐ und ‐osmium(II)‐Komplexe mit fluktuierender Struktur
Werner H., Esteruelas M.A., Meyer U., Wrackmeyer B.
Chemische Berichte , 1987
190.
190
H. Law
J. Chem. Soc. , 1912
191.
191
M. Matsui
Mem. Coll. Sci., Kyoto Univ. , 1920
192.
Preparation and Spectroscopic and Theoretical Characterization of the Tetrahydroborate Complex OsH3(.eta.2-H2BH2)(P-i-Pr3)2
Esteruelas M.A., Jean Y., Lledos A., Oro L.A., Ruiz N., Volatron F.
Inorganic Chemistry , 1994
193.
Exchange of bridging and terminal hydrides in [Co(terpy)(H2BH2)]
Wink D.J., Cooper N.J.
Journal of the Chemical Society Dalton Transactions , 1984
194.
Iridium and rhodium dihydride–hydroborate complexes of the type [MH2(BH4)L2]
Empsall H.D., Mentzer E., Shaw B.L.
Journal of the Chemical Society Chemical Communications , 1975
195.
Some iridium hydride and tetrahydroborate complexes with bulky tertiary phosphine ligands
Empsall H.D., Hyde E.M., Mentzer E., Shaw B.L., Uttely M.F.
Journal of the Chemical Society Dalton Transactions , 1976
198.
Structure and bonding of the lithium tetrahydroborate–tetramethylethylenediamine adduct (TMEDA·LiBH4)2, a centrosymmetric dimer containing doubly and triply bridging hydrogen atoms
Armstrong D.R., Clegg W., Colquhoun H.M., Daniels J.A., Mulvey R.E., Stephenson I.R., Wade K.
Journal of the Chemical Society Chemical Communications , 1987
199.
199
Yu. K. Delimarskii
Byull. Izobr. , 1970
200.
Beryllium borohydride structure in the solid phase
Lipscomb W.N., Marynick D.
Journal of the American Chemical Society , 1971
201.
Infrared and Raman Spectra of Solid Beryllium Borohydride, BeB2H8
Nibler J.W., Shriver D.F., Cook T.H.
Journal of Chemical Physics , 1971
202.
202
G. Shiroa
Mem. Coll. Sci., Kyoto Univ. , 1930
204.
Unsolvated lanthanidocene hydrides and borohydrides. X-Ray crystal structure of [(η5-C5H3tBu2)2Ln(μ-H)]2 (Ln = Ce, Sm)
Gun'ko Y.K., Bulychev B.M., Soloveichik G.L., Belsky V.K.
Journal of Organometallic Chemistry , 1992
207.
14-Coordinate uranium(IV). Structure of uranium borohydride by single-crystal neutron diffraction
Bernstein E.R., Hamilton W.C., Keiderling T.A., La Placa S.J., Lippard S.J., Mayerle J.J.
Inorganic Chemistry , 1972
208.
Structure of uranium borohydride by single-crystal x-ray diffraction
Bernstein E.R., Keiderling T.A., Lippard S.J., Mayerle J.J.
Journal of the American Chemical Society , 1972
209.
209
C. J. Haggerty
Trans. Am. Electrochem. Soc. , 1929
210.
Structure of the second crystalline form of uranium(IV) tetrahydroborate
Charpin P., Nierlich M., Vigner D., Lance M., Baudry D.
Acta Crystallographica Section C Crystal Structure Communications , 1987
211.
Preparation and molecular and crystal structures of uranium(IV) borohydride-dimethyl ether and uranium(IV) borohydride-diethyl ether
Rietz R.R., Zalkin A., Templeton D.H., Edelstein N.M., Templeton L.K.
Inorganic Chemistry , 1978
212.
Preparation and crystal structure of uranium(IV) borohydride-n-propyl ether
Zalkin A., Rietz R.R., Templeton D.H., Edelstein N.M.
Inorganic Chemistry , 1978
215.
μ-tetrahydridoboratebis-bis(triphenylphosphine)copper (I) salts
Cariati F., Naldini L.
Journal of Inorganic and Nuclear Chemistry , 1966
216.
Crystal and molecular structure of μ-tetrahydroborato-bis[bis(triphenylphosphine)copper(I)] perchlorate
Green B.E., Kennard C.H., Smith G., James B.D., Healy P.C., White A.H.
Inorganica Chimica Acta , 1984
217.
Methylzinc tetrahydroborate: physical and chemical properties and crystal structure at low temperature
Aldridge S., Blake A.J., Downs A.J., Parsons S., Pulham C.R.
Journal of the Chemical Society Dalton Transactions , 1996
218.
Vibrational spectra of solid methylzinc borohydride, CH3Zn+··· BH4−
Nibler J.W., Cook T.H.
Journal of Chemical Physics , 1973
219.
219
G. I. Pustoshkin
Collected Papers "Biologicheskie Aktivnie Soedinenii" (Biologically Active Compounds) , 1955
220.
Crown compounds for anions. Spectroscopic and theoretical studies of complexation of borohydride anions with cyclic trimeric perfluoro-o-phenylenemercury
Saitkulova L.N., Bakhmutova E.V., Shubina E.S., Tikhonova I.A., Furin G.G., Bakhmutov V.I., Gambaryan N.P., Chistyakov A.L., Stankevich I.V., Shur V.B., Epstein L.M.
Journal of Organometallic Chemistry , 1999
221.
Downs A.J., Parsons S., Pulham C.R., Souter P.F.
1997
223.
Bonding in metal borohydride complexes
Edelstein N.
Inorganic Chemistry , 1981
224.
224
Chem. Abs. , 1959
225.
225
1960
227.
Covalent Tetrahydroborates
Semenenko K.N., Kravchenko O.V., Polyakova V.B.
Russian Chemical Reviews , 1973
228.
Structure and chemistry of bis(cyclopentadienyl)-MLn complexes
Lauher J.W., Hoffmann R.
Journal of the American Chemical Society , 1976
231.
232
Chem. Abs. , 1960
232.
Metallboranate und Boranatometallate. IV. Boranatokomplexe M(BH4)4+nn? des Zirkoniums, Hafniums und Thoriums
Ehemann M., N�th H.
Zeitschrift fur Anorganische und Allgemeine Chemie , 1971
233.
234
Ebach E A
Chem. Abs. , 1966
237.
238
Brown G P
Am. Chem. Soc., Polymer Preprints , 1964
238.
239
Mendelbaum H. G.
Bull. Soc. chim. France , 1973
239.
240
W. A. Waters
"The Chemistry of Free Radicals" , 1948
240.
241
M. S. Kharasch
"Grignard Reactions of Nonmetallic Substances" , 1954
241.
The tridentate bonding mode of tetrahydroborate towards germanium and tin
Siddiqi K.S., Aqra F.M., Shah S.A., Zaidi S.A.
Polyhedron , 1994
242.
Borohydride derivatives of tricyclopentadienyl cerium(IV) and bisindenyl cerium(IV)
Kapur S., Kalsotra B.L., Multani R.K., Jain B.D.
Journal of Inorganic and Nuclear Chemistry , 1973
243.
Studies on bis(borohydride) derivatives of di-π-cyclopentadienylmolybdenum(VI) and -tungsten(VI)
Anand S.P., Multani R.K., Jain B.D.
Journal of Organometallic Chemistry , 1971
247.
Highly active metallocene catalysts for olefin polymerization
Kaminsky W.
Journal of the Chemical Society Dalton Transactions , 1998
248.
249
A. I. Fedorova
Dokl. Akad. Nauk SSSR , 1961