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Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes

Boris Mironovich Mykhalichko 1
Boris Mironovich Mykhalichko
, 
Oleg Naumovich Temkin 2
Oleg Naumovich Temkin
, 
Mar'yan Grigor'evich Mys'kiv 1
Mar'yan Grigor'evich Mys'kiv
1 Ivan Franko National University of L'viv
2 M. V. Lomonosov Moscow State Academy of Fine Chemical Technology
10.1070/RC2000v069n11ABEH000609
Published 30 November 1999
Communication , Volume 69, Issue 11, 957-984
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Mykhalichko B. M., Temkin O. N., Mys'kiv M. G. Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes // Russian Chemical Reviews. 2000. Vol. 69. No. 11. pp. 957-984.
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Mykhalichko B. M., Temkin O. N., Mys'kiv M. G. Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes // Russian Chemical Reviews. 2000. Vol. 69. No. 11. pp. 957-984.
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TY - JOUR
DO - 10.1070/RC2000v069n11ABEH000609
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000609
TI - Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes
T2 - Russian Chemical Reviews
AU - Mykhalichko, Boris Mironovich
AU - Temkin, Oleg Naumovich
AU - Mys'kiv, Mar'yan Grigor'evich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 957-984
IS - 11
VL - 69
ER -
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@article{2000_Mykhalichko,
author = {Boris Mironovich Mykhalichko and Oleg Naumovich Temkin and Mar'yan Grigor'evich Mys'kiv},
title = {Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000609},
number = {11},
pages = {957--984},
doi = {10.1070/RC2000v069n11ABEH000609}
}
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Mykhalichko, Boris Mironovich, et al. “Polynuclear complexes of copper(I) halides: coordination chemistry and catalytic transformations of alkynes.” Russian Chemical Reviews, vol. 69, no. 11, Nov. 2000, pp. 957-984. https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000609.
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Abstract

Characteristic features of the coordination chemistry of Cu(I) and mechanisms of catalytic conversions of alkynes in the CuCl–MCl–H2O–HC≡CR system (MCl is alkali metal or ammonium chloride or amine hydrochloride; R=H, CH2OH, CH=CH2, etc.) are analysed based on studies of the compositions and structures of copper(I) chloride (bromide) complexes, alkyne π-complexes and ethynyl organometallic polynuclear compounds formed in this system in solutions and in the crystalline state. The role of polynuclear complexes in various reactions of alkynes is discussed. The bibliography includes 149 references.

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