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Reactions of nitrogen oxides with polymers

Georgii Borisovich Pariiskii 1
Georgii Borisovich Pariiskii
, 
Irina Stepanovna Gaponova 1
Irina Stepanovna Gaponova
, 
Evgenii Yakovlevich Davydov 1
Evgenii Yakovlevich Davydov
1 Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC2000v069n11ABEH000611
Published 30 November 1999
Communication , Volume 69, Issue 11, 985-999
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Pariiskii G. B., Gaponova I. S., Davydov E. Y. Reactions of nitrogen oxides with polymers // Russian Chemical Reviews. 2000. Vol. 69. No. 11. pp. 985-999.
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Pariiskii G. B., Gaponova I. S., Davydov E. Y. Reactions of nitrogen oxides with polymers // Russian Chemical Reviews. 2000. Vol. 69. No. 11. pp. 985-999.
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TY - JOUR
DO - 10.1070/RC2000v069n11ABEH000611
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000611
TI - Reactions of nitrogen oxides with polymers
T2 - Russian Chemical Reviews
AU - Pariiskii, Georgii Borisovich
AU - Gaponova, Irina Stepanovna
AU - Davydov, Evgenii Yakovlevich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 985-999
IS - 11
VL - 69
ER -
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@article{2000_Pariiskii,
author = {Georgii Borisovich Pariiskii and Irina Stepanovna Gaponova and Evgenii Yakovlevich Davydov},
title = {Reactions of nitrogen oxides with polymers},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000611},
number = {11},
pages = {985--999},
doi = {10.1070/RC2000v069n11ABEH000611}
}
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Pariiskii, Georgii Borisovich, et al. “Reactions of nitrogen oxides with polymers.” Russian Chemical Reviews, vol. 69, no. 11, Nov. 2000, pp. 985-999. https://rcr.colab.ws/publications/10.1070/RC2000v069n11ABEH000611.
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Abstract

The mechanisms of the reactions of nitrogen oxides and different classes of solid polymers are considered. Particular emphasis is given to the analysis of the mechanisms of the formation of stable nitroxyl radicals. Double bonds and amide groups of macromolecules, as well as hydroperoxides and peroxide macroradicals are shown to be involved in the reactions with nitrogen oxides. The application of nitrogen oxides for the preparation of spin-labelled polymers and the use of the ESR imaging technique (ESR tomography) for the investigation of the structure of the reaction front during nitration of solid polymers are considered. The bibliography includes 111 references.

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