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Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives

Elena Antonovna Gastilovich 1
Elena Antonovna Gastilovich
, 
Vasilii Grigor'evich Klimenko 1
Vasilii Grigor'evich Klimenko
, 
Nina Vladimirovna Korol'kova 1
Nina Vladimirovna Korol'kova
, 
Ravil' Nurlanovich Nurmukhametov 1
Ravil' Nurlanovich Nurmukhametov
1 State Scientific Centre of Russian Federation "L. Ya. Karpov Institute of Physical Chemistry", Moscow
10.1070/RC2000v069n12ABEH000602
Published 30 November 1999
Communication , Volume 69, Issue 12, 1037-1056
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Gastilovich E. A. et al. Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives // Russian Chemical Reviews. 2000. Vol. 69. No. 12. pp. 1037-1056.
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Gastilovich E. A., Klimenko V. G., Korol'kova N. V., Nurmukhametov R. N. Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives // Russian Chemical Reviews. 2000. Vol. 69. No. 12. pp. 1037-1056.
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TY - JOUR
DO - 10.1070/RC2000v069n12ABEH000602
UR - https://rcr.colab.ws/publications/10.1070/RC2000v069n12ABEH000602
TI - Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives
T2 - Russian Chemical Reviews
AU - Gastilovich, Elena Antonovna
AU - Klimenko, Vasilii Grigor'evich
AU - Korol'kova, Nina Vladimirovna
AU - Nurmukhametov, Ravil' Nurlanovich
PY - 2000
DA - 1999/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1037-1056
IS - 12
VL - 69
ER -
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@article{2000_Gastilovich,
author = {Elena Antonovna Gastilovich and Vasilii Grigor'evich Klimenko and Nina Vladimirovna Korol'kova and Ravil' Nurlanovich Nurmukhametov},
title = {Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives},
journal = {Russian Chemical Reviews},
year = {2000},
volume = {69},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2000v069n12ABEH000602},
number = {12},
pages = {1037--1056},
doi = {10.1070/RC2000v069n12ABEH000602}
}
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Gastilovich, Elena Antonovna, et al. “Optical spectra and photophysical properties of polychlorinated dibenzo-p-dioxin derivatives.” Russian Chemical Reviews, vol. 69, no. 12, Nov. 2000, pp. 1037-1056. https://rcr.colab.ws/publications/10.1070/RC2000v069n12ABEH000602.
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Abstract

Published data on the optical spectra and theoretical investigations of dioxins, polychlorinated derivatives of dibenzo-p-dioxin, which are well-known environmental toxins, are generalised. The geometrical and electronic structures of the molecules and their vibrational and electronically excited states are considered. The influence of the number and positions of chlorine atoms in dioxin molecules on the optical spectra (IR and UV absorption, fluorescence and phosphorescence spectra), in particular, on the low-temperature fine-structure phosphorescence spectra of solid solutions and on the photophysical deactivation of triplet electronic states are discussed. The results of the use of optical spectroscopy for identification and quantification of dioxins are presented. The bibliography includes 108 references.

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