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Chemical modification and blending of polymers in an extruder reactor

Eduard Veniaminovich Prut 1
Eduard Veniaminovich Prut
, 
Alexandr Nikolaevich Zelenetskii 2
Alexandr Nikolaevich Zelenetskii
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
2 N. S. Enikolopov Institute of Synthetic Polymer Materials RAS, Moscow
10.1070/RC2001v070n01ABEH000624
Published 30 November 2000
Communication , Volume 70, Issue 1, 65-79
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Prut E. V., Zelenetskii A. N. Chemical modification and blending of polymers in an extruder reactor // Russian Chemical Reviews. 2001. Vol. 70. No. 1. pp. 65-79.
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Prut E. V., Zelenetskii A. N. Chemical modification and blending of polymers in an extruder reactor // Russian Chemical Reviews. 2001. Vol. 70. No. 1. pp. 65-79.
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TY - JOUR
DO - 10.1070/RC2001v070n01ABEH000624
UR - https://rcr.colab.ws/publications/10.1070/RC2001v070n01ABEH000624
TI - Chemical modification and blending of polymers in an extruder reactor
T2 - Russian Chemical Reviews
AU - Prut, Eduard Veniaminovich
AU - Zelenetskii, Alexandr Nikolaevich
PY - 2001
DA - 2000/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 65-79
IS - 1
VL - 70
ER -
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@article{2001_Prut,
author = {Eduard Veniaminovich Prut and Alexandr Nikolaevich Zelenetskii},
title = {Chemical modification and blending of polymers in an extruder reactor},
journal = {Russian Chemical Reviews},
year = {2001},
volume = {70},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2001v070n01ABEH000624},
number = {1},
pages = {65--79},
doi = {10.1070/RC2001v070n01ABEH000624}
}
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Prut, Eduard Veniaminovich, and Alexandr Nikolaevich Zelenetskii. “Chemical modification and blending of polymers in an extruder reactor.” Russian Chemical Reviews, vol. 70, no. 1, Nov. 2001, pp. 65-79. https://rcr.colab.ws/publications/10.1070/RC2001v070n01ABEH000624.
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Abstract

Chemical modification and blending of polymers in an extruder reactor are discussed. Relationships between the parameters affecting the reaction kinetics, viz., mixing time, duration of a chemical reaction and the residence time of the system in the extruder reactor, and the structure of the materials produced are analysed. The mechanisms of (i) grafting of low-molecular-mass compounds onto polymers; (ii) reactions between terminal groups of different polymers and (iii) transesterification and interchange reactions are considered. The factors affecting the mechanism of dynamic vulcanisation and the properties of thermoplastic elastomers are identified. Solid-phase reactions of polysaccharides in an extruder are discussed. The priority aspects of studies on the chemical modification and blending of polymers are noted. The bibliography includes 90 references.

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