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Electrochemically active species and multielectron processes in ionic melts

Viktor Ivanovich Shapoval 1
Viktor Ivanovich Shapoval
, 
Veniamin Vasil'evich Solov'ev 2
Veniamin Vasil'evich Solov'ev
, 
Viktor Vladimirovich Malyshev 1
Viktor Vladimirovich Malyshev
1 V. I. Vernadsky Institute of General and Inorganic Chemistry, National Academy of Sciences of Ukraine, Kiev
2 Poltava State Technical University named after Yuri Kondratyuk
10.1070/RC2001v070n02ABEH000619
Published 30 November 2000
Communication , Volume 70, Issue 2, 161-176
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Shapoval V. I., Solov'ev V. V., Malyshev V. V. Electrochemically active species and multielectron processes in ionic melts // Russian Chemical Reviews. 2001. Vol. 70. No. 2. pp. 161-176.
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Shapoval V. I., Solov'ev V. V., Malyshev V. V. Electrochemically active species and multielectron processes in ionic melts // Russian Chemical Reviews. 2001. Vol. 70. No. 2. pp. 161-176.
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TY - JOUR
DO - 10.1070/RC2001v070n02ABEH000619
UR - https://rcr.colab.ws/publications/10.1070/RC2001v070n02ABEH000619
TI - Electrochemically active species and multielectron processes in ionic melts
T2 - Russian Chemical Reviews
AU - Shapoval, Viktor Ivanovich
AU - Solov'ev, Veniamin Vasil'evich
AU - Malyshev, Viktor Vladimirovich
PY - 2001
DA - 2000/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 161-176
IS - 2
VL - 70
ER -
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@article{2001_Shapoval,
author = {Viktor Ivanovich Shapoval and Veniamin Vasil'evich Solov'ev and Viktor Vladimirovich Malyshev},
title = {Electrochemically active species and multielectron processes in ionic melts},
journal = {Russian Chemical Reviews},
year = {2001},
volume = {70},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2001v070n02ABEH000619},
number = {2},
pages = {161--176},
doi = {10.1070/RC2001v070n02ABEH000619}
}
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Shapoval, Viktor Ivanovich, et al. “Electrochemically active species and multielectron processes in ionic melts.” Russian Chemical Reviews, vol. 70, no. 2, Nov. 2001, pp. 161-176. https://rcr.colab.ws/publications/10.1070/RC2001v070n02ABEH000619.
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Abstract

The model concepts for the mechanisms of formation of electrochemically active species and multielectron processes in ionic nitrate-, carbonate-, boron- and titanium-containing fluoride melts are generalised. The fundamental importance of the acid-base properties of a melt in the mechanism of formation of electrochemically active species is shown for nitrate- and carbonate-containing melts. This fact is confirmed by electrochemical measurements and by calculations of force constants for oxyanions. The optimum form of electrochemically active species has been established; their reduction abilities depend on the cationic composition of a melt, the adsorption properties of the electrode surface and the electric field strength. The bibliography includes 218 references.

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