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Organic molecules with abnormal geometric parameters

Igor Vladimirovich Komarov 1
Igor Vladimirovich Komarov
1 State Taras Shevchenko University of Kyiv, Chemical Faculty
Published 30 November 2000
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Komarov I. V. Organic molecules with abnormal geometric parameters // Russian Chemical Reviews. 2001. Vol. 70. No. 12. pp. 991-1016.
GOST all authors (up to 50)
Komarov I. V. Organic molecules with abnormal geometric parameters // Russian Chemical Reviews. 2001. Vol. 70. No. 12. pp. 991-1016.
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TY - JOUR
DO - 10.1070/RC2001v070n12ABEH000633
UR - https://rcr.colab.ws/publications/10.1070/RC2001v070n12ABEH000633
TI - Organic molecules with abnormal geometric parameters
T2 - Russian Chemical Reviews
AU - Komarov, Igor Vladimirovich
PY - 2001
DA - 2000/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 991-1016
IS - 12
VL - 70
ER -
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@article{2001_Komarov,
author = {Igor Vladimirovich Komarov},
title = {Organic molecules with abnormal geometric parameters},
journal = {Russian Chemical Reviews},
year = {2001},
volume = {70},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2001v070n12ABEH000633},
number = {12},
pages = {991--1016},
doi = {10.1070/RC2001v070n12ABEH000633}
}
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Komarov, Igor Vladimirovich. “Organic molecules with abnormal geometric parameters.” Russian Chemical Reviews, vol. 70, no. 12, Nov. 2001, pp. 991-1016. https://rcr.colab.ws/publications/10.1070/RC2001v070n12ABEH000633.
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Abstract

Organic molecules, the structural parameters of which (carbon–carbon bond lengths, bond and torsion angles) differ appreciably from the typical most frequently encountered values, are discussed. Using many examples of 'record-breaking' molecules, the limits of structural distortions in carbon compounds and their unusual chemical properties are demonstrated. Particular attention is devoted to strained compounds not yet synthesised whose properties have been predicted using quantum-chemical calculations. Factors that ensure the stability of such compounds are outlined. The bibliography includes 358 references.