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Some new views on the tautomerisation mechanism

Jumber Abesalomovich Kereselidze 1
Jumber Abesalomovich Kereselidze
, 
Tamar Shalvovna Zarqua 1
Tamar Shalvovna Zarqua
, 
Tinatin Jzhemalovna Kikalishvili 1
Tinatin Jzhemalovna Kikalishvili
, 
Ema Jzhemalovna Churgulia 1
Ema Jzhemalovna Churgulia
, 
M S Makaridze 1
M S Makaridze
1 Tbilisi Ivane Javakhishvili State University, Department of Chemistry
10.1070/RC2002v071n12ABEH000727
Published 30 November 2001
Communication , Volume 71, Issue 12, 993-1003
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Kereselidze J. A. et al. Some new views on the tautomerisation mechanism // Russian Chemical Reviews. 2002. Vol. 71. No. 12. pp. 993-1003.
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Kereselidze J. A., Zarqua T. S., Kikalishvili T. J., Churgulia E. J., Makaridze M. S. Some new views on the tautomerisation mechanism // Russian Chemical Reviews. 2002. Vol. 71. No. 12. pp. 993-1003.
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TY - JOUR
DO - 10.1070/RC2002v071n12ABEH000727
UR - https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000727
TI - Some new views on the tautomerisation mechanism
T2 - Russian Chemical Reviews
AU - Kereselidze, Jumber Abesalomovich
AU - Zarqua, Tamar Shalvovna
AU - Kikalishvili, Tinatin Jzhemalovna
AU - Churgulia, Ema Jzhemalovna
AU - Makaridze, M S
PY - 2002
DA - 2001/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 993-1003
IS - 12
VL - 71
ER -
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@article{2002_Kereselidze,
author = {Jumber Abesalomovich Kereselidze and Tamar Shalvovna Zarqua and Tinatin Jzhemalovna Kikalishvili and Ema Jzhemalovna Churgulia and M S Makaridze},
title = {Some new views on the tautomerisation mechanism},
journal = {Russian Chemical Reviews},
year = {2002},
volume = {71},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000727},
number = {12},
pages = {993--1003},
doi = {10.1070/RC2002v071n12ABEH000727}
}
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Kereselidze, Jumber Abesalomovich, et al. “Some new views on the tautomerisation mechanism.” Russian Chemical Reviews, vol. 71, no. 12, Nov. 2002, pp. 993-1003. https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000727.
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Abstract

Published data on the prototropic tautomerism of some carbonyl and nitrogen-containing acyclic and heterocyclic compounds are systematised. Mechanisms of intramolecular and intermolecular proton transfer in tautomerisation reactions are considered. On the basis of the results of semiempirical and ab initio quantum-chemical calculations, preference is given to an intermolecular collective (dimeric, trimeric, tetrameric or oligomeric) mechanism. A new approach to the description of the solvent effect on the prototropic tautomeric equilibrium is proposed. The bibliography includes 107 references.