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Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety

Achim Müller 1
Achim Müller
, 
Soumyajit Roy 1
Soumyajit Roy
1 Bielefeld University, Department of Chemistry
10.1070/RC2002v071n12ABEH000751
Published 30 November 2001
Communication , Volume 71, Issue 12, 981-991
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Müller A., Roy S. Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety // Russian Chemical Reviews. 2002. Vol. 71. No. 12. pp. 981-991.
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Müller A., Roy S. Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety // Russian Chemical Reviews. 2002. Vol. 71. No. 12. pp. 981-991.
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TY - JOUR
DO - 10.1070/RC2002v071n12ABEH000751
UR - https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000751
TI - Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety
T2 - Russian Chemical Reviews
AU - Müller, Achim
AU - Roy, Soumyajit
PY - 2002
DA - 2001/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 981-991
IS - 12
VL - 71
ER -
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@article{2002_Müller,
author = {Achim Müller and Soumyajit Roy},
title = {Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety},
journal = {Russian Chemical Reviews},
year = {2002},
volume = {71},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000751},
number = {12},
pages = {981--991},
doi = {10.1070/RC2002v071n12ABEH000751}
}
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Müller, Achim, and Soumyajit Roy. “Metal-oxide based nanoobjects: reactivity, building blocks for polymeric structures and structural variety.” Russian Chemical Reviews, vol. 71, no. 12, Nov. 2002, pp. 981-991. https://rcr.colab.ws/publications/10.1070/RC2002v071n12ABEH000751.
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Abstract

From the unique 'library' of molybdenum-oxide based building blocks/fragments under reducing conditions in aqueous solution a huge variety of nanoobjects, allowing specific reactions at well-defined positions, can be generated. This enables us to perform a new type of nanochemistry. Examples include the well-known molecular big-wheel of the type {Mo176} and big-ball of the type {Mo132} including their derivatives which are considered here. In addition, the by far largest structurally well-characterised cluster having 368 molybdenum atoms with the shape of a lemon is outlined and discussed. The bibliography includes 71 references.