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Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions

Evgenii Yakovlevich Misochko 1
Evgenii Yakovlevich Misochko
, 
Alexander Vladimirovich Akimov 1
Alexander Vladimirovich Akimov
, 
Ilya Udovich Goldschleger 1
Ilya Udovich Goldschleger
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2003v072n03ABEH000777
Published 30 November 2002
Communication , Volume 72, Issue 3, 233-255
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Misochko E. Y., Akimov A. V., Goldschleger I. U. Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions // Russian Chemical Reviews. 2003. Vol. 72. No. 3. pp. 233-255.
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Misochko E. Y., Akimov A. V., Goldschleger I. U. Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions // Russian Chemical Reviews. 2003. Vol. 72. No. 3. pp. 233-255.
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TY - JOUR
DO - 10.1070/RC2003v072n03ABEH000777
UR - https://rcr.colab.ws/publications/10.1070/RC2003v072n03ABEH000777
TI - Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions
T2 - Russian Chemical Reviews
AU - Misochko, Evgenii Yakovlevich
AU - Akimov, Alexander Vladimirovich
AU - Goldschleger, Ilya Udovich
PY - 2003
DA - 2002/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 233-255
IS - 3
VL - 72
ER -
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@article{2003_Misochko,
author = {Evgenii Yakovlevich Misochko and Alexander Vladimirovich Akimov and Ilya Udovich Goldschleger},
title = {Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions},
journal = {Russian Chemical Reviews},
year = {2003},
volume = {72},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2003v072n03ABEH000777},
number = {3},
pages = {233--255},
doi = {10.1070/RC2003v072n03ABEH000777}
}
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Misochko, Evgenii Yakovlevich, et al. “Modern applications of matrix isolation technique to investigation of radical species generated in atom–molecular chemical reactions.” Russian Chemical Reviews, vol. 72, no. 3, Nov. 2003, pp. 233-255. https://rcr.colab.ws/publications/10.1070/RC2003v072n03ABEH000777.
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Abstract

The potential of using the translational mobility of hydrogen, oxygen and fluorine atoms in the crystals and solid matrices of inert gases for initiating solid-phase cryochemical reactions and for investigating the stabilised intermediate particles generated in these reactions is discussed. The main spectroscopic methods used to study the stabilised particles are considered. Particular emphasis is placed on elucidation of the spectroscopic characteristics required for reliable identification and determination of the structure of new reactive intermediates. Methodological approaches to the solution of this problem are discussed. Examples of successful implementation of these approaches by various research groups are given.