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Nucleation: theory and experiment

Mikhail Prokop'evich Anisimov 1
Mikhail Prokop'evich Anisimov
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
Published 30 November 2002
Communication , Volume 72, Issue 7, 591-628
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Anisimov M. P. Nucleation: theory and experiment // Russian Chemical Reviews. 2003. Vol. 72. No. 7. pp. 591-628.
GOST all authors (up to 50)
Anisimov M. P. Nucleation: theory and experiment // Russian Chemical Reviews. 2003. Vol. 72. No. 7. pp. 591-628.
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TY - JOUR
DO - 10.1070/RC2003v072n07ABEH000761
UR - https://rcr.colab.ws/publications/10.1070/RC2003v072n07ABEH000761
TI - Nucleation: theory and experiment
T2 - Russian Chemical Reviews
AU - Anisimov, Mikhail Prokop'evich
PY - 2003
DA - 2002/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 591-628
IS - 7
VL - 72
ER -
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@article{2003_Anisimov,
author = {Mikhail Prokop'evich Anisimov},
title = {Nucleation: theory and experiment},
journal = {Russian Chemical Reviews},
year = {2003},
volume = {72},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2003v072n07ABEH000761},
number = {7},
pages = {591--628},
doi = {10.1070/RC2003v072n07ABEH000761}
}
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Anisimov, Mikhail Prokop'evich. “Nucleation: theory and experiment.” Russian Chemical Reviews, vol. 72, no. 7, Nov. 2003, pp. 591-628. https://rcr.colab.ws/publications/10.1070/RC2003v072n07ABEH000761.
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Abstract

Various theoretical and experimental methods for studying nucleation are considered. Since theoretical methods have fundamental limitations, information is gained from experimental research. It is demonstrated that the nucleation theory is entering a new phase of development, which is going to be, in essence, semiempirical. A semiempirical method for constructing nucleation rate surfaces is described. The topology of these surfaces in the limit of the zero nucleation rate can be determined using phase equilibrium diagrams. This opens up possibilities for revising certain approximations employed in experiments and particular axiomatic statements of the classical nucleation theory. Examples of the practical use of nucleation essential for the development of modern technologies are given.