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Thermolysis of organic peroxides in solution

Vilen Lazarevich Antonovskii 1
Vilen Lazarevich Antonovskii
, 
Sergei Leonidovich Khursan 2
Sergei Leonidovich Khursan
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
2 Bashkir State University, Ufa
10.1070/RC2003v072n11ABEH000749
Published 30 November 2002
Communication , Volume 72, Issue 11, 939-963
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Antonovskii V. L., Khursan S. L. Thermolysis of organic peroxides in solution // Russian Chemical Reviews. 2003. Vol. 72. No. 11. pp. 939-963.
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Antonovskii V. L., Khursan S. L. Thermolysis of organic peroxides in solution // Russian Chemical Reviews. 2003. Vol. 72. No. 11. pp. 939-963.
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TY - JOUR
DO - 10.1070/RC2003v072n11ABEH000749
UR - https://rcr.colab.ws/publications/10.1070/RC2003v072n11ABEH000749
TI - Thermolysis of organic peroxides in solution
T2 - Russian Chemical Reviews
AU - Antonovskii, Vilen Lazarevich
AU - Khursan, Sergei Leonidovich
PY - 2003
DA - 2002/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 939-963
IS - 11
VL - 72
ER -
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@article{2003_Antonovskii,
author = {Vilen Lazarevich Antonovskii and Sergei Leonidovich Khursan},
title = {Thermolysis of organic peroxides in solution},
journal = {Russian Chemical Reviews},
year = {2003},
volume = {72},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2003v072n11ABEH000749},
number = {11},
pages = {939--963},
doi = {10.1070/RC2003v072n11ABEH000749}
}
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Antonovskii, Vilen Lazarevich, and Sergei Leonidovich Khursan. “Thermolysis of organic peroxides in solution.” Russian Chemical Reviews, vol. 72, no. 11, Nov. 2003, pp. 939-963. https://rcr.colab.ws/publications/10.1070/RC2003v072n11ABEH000749.
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Abstract

The results of investigations of the kinetics and mechanisms of thermolysis of the main classes of organic peroxides in solution are generalised. The relationship between the kinetics and mechanism of thermolysis and the peroxide structure is analysed. The main attention is given to the decomposition reactions of peroxides that are not confined to mere homolysis of the O–O bond and the factors responsible for the abnormalities in the thermolysis mechanism. The mechanisms of thermolysis of trioxides, dioxiranes and peroxides are considered in detail.