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The mechanism of thermal decomposition of secondary nitramines

Yuan'tse Shu 1
Yuan'tse Shu
, 
Boris L'vovich Korsunskii 1
Boris L'vovich Korsunskii
, 
Gennadii Mikhailovich Nazin 1
Gennadii Mikhailovich Nazin
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2004v073n03ABEH000802
Published 30 November 2003
Communication , Volume 73, Issue 3, 293-307
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Shu Y., Korsunskii B. L., Nazin G. M. The mechanism of thermal decomposition of secondary nitramines // Russian Chemical Reviews. 2004. Vol. 73. No. 3. pp. 293-307.
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Shu Y., Korsunskii B. L., Nazin G. M. The mechanism of thermal decomposition of secondary nitramines // Russian Chemical Reviews. 2004. Vol. 73. No. 3. pp. 293-307.
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TY - JOUR
DO - 10.1070/RC2004v073n03ABEH000802
UR - https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000802
TI - The mechanism of thermal decomposition of secondary nitramines
T2 - Russian Chemical Reviews
AU - Shu, Yuan'tse
AU - Korsunskii, Boris L'vovich
AU - Nazin, Gennadii Mikhailovich
PY - 2004
DA - 2003/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 293-307
IS - 3
VL - 73
ER -
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@article{2004_Shu,
author = {Yuan'tse Shu and Boris L'vovich Korsunskii and Gennadii Mikhailovich Nazin},
title = {The mechanism of thermal decomposition of secondary nitramines},
journal = {Russian Chemical Reviews},
year = {2004},
volume = {73},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000802},
number = {3},
pages = {293--307},
doi = {10.1070/RC2004v073n03ABEH000802}
}
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Shu, Yuan'tse, et al. “The mechanism of thermal decomposition of secondary nitramines.” Russian Chemical Reviews, vol. 73, no. 3, Nov. 2004, pp. 293-307. https://rcr.colab.ws/publications/10.1070/RC2004v073n03ABEH000802.
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Abstract

A critical review of the published data on the mechanism of decomposition of secondary nitramines is presented. Based on the data available, it is concluded that the first step of decomposition always includes cleavage of the N — NO2 bond, which is followed by various secondary reactions and sometimes by chain processes. The effects of structures of nitramines on their stabilities are considered.