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Metal complex catalysis in the synthesis of organomagnesium compounds

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Askhat Gabdrakhmanovich Ibragimov 1
Askhat Gabdrakhmanovich Ibragimov
1 Institute of Petrochemistry and Catalysis of RAS, Ufa
10.1070/RC2005v074n09ABEH001171
Published 30 November 2004
Communication , Volume 74, Issue 9, 807-823
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Dzhemilev U. M., Ibragimov A. G. Metal complex catalysis in the synthesis of organomagnesium compounds // Russian Chemical Reviews. 2005. Vol. 74. No. 9. pp. 807-823.
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Dzhemilev U. M., Ibragimov A. G. Metal complex catalysis in the synthesis of organomagnesium compounds // Russian Chemical Reviews. 2005. Vol. 74. No. 9. pp. 807-823.
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TY - JOUR
DO - 10.1070/RC2005v074n09ABEH001171
UR - https://rcr.colab.ws/publications/10.1070/RC2005v074n09ABEH001171
TI - Metal complex catalysis in the synthesis of organomagnesium compounds
T2 - Russian Chemical Reviews
AU - Dzhemilev, Usein Memetovich
AU - Ibragimov, Askhat Gabdrakhmanovich
PY - 2005
DA - 2004/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 807-823
IS - 9
VL - 74
ER -
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@article{2005_Dzhemilev,
author = {Usein Memetovich Dzhemilev and Askhat Gabdrakhmanovich Ibragimov},
title = {Metal complex catalysis in the synthesis of organomagnesium compounds},
journal = {Russian Chemical Reviews},
year = {2005},
volume = {74},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2005v074n09ABEH001171},
number = {9},
pages = {807--823},
doi = {10.1070/RC2005v074n09ABEH001171}
}
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Dzhemilev, Usein Memetovich, and Askhat Gabdrakhmanovich Ibragimov. “Metal complex catalysis in the synthesis of organomagnesium compounds.” Russian Chemical Reviews, vol. 74, no. 9, Nov. 2005, pp. 807-823. https://rcr.colab.ws/publications/10.1070/RC2005v074n09ABEH001171.
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Abstract

The published data on the synthesis of organomagnesium compounds assisted by metal complex catalysts are generalised and described systematically for the first time. Hydro-, carbo- and cyclomagnesiation reactions of unsaturated compounds with R1MgR2 (R1 = Alk, Ar; R2 = H, Hal; R1 = R2 = Alk) catalysed by Ti, Zr and other transition metal salts and complexes are considered. Selected examples of applications of organomagnesium reagents to organic synthesis are given.