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Principal trends in the chemistry of amidinate complexes of main-group and transition elements

D A Kissounko 1
D A Kissounko
, 
M V Zabalov 2
M V Zabalov
, 
G P Brusova 2
G P Brusova
, 
Dmitrii Anatol'evich Lemenovskii 2
Dmitrii Anatol'evich Lemenovskii
1 Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL
2 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC2006v075n05ABEH001201
Published 30 November 2005
Communication , Volume 75, Issue 5, 351-374
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Kissounko D. A. et al. Principal trends in the chemistry of amidinate complexes of main-group and transition elements // Russian Chemical Reviews. 2006. Vol. 75. No. 5. pp. 351-374.
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Kissounko D. A., Zabalov M. V., Brusova G. P., Lemenovskii D. A. Principal trends in the chemistry of amidinate complexes of main-group and transition elements // Russian Chemical Reviews. 2006. Vol. 75. No. 5. pp. 351-374.
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TY - JOUR
DO - 10.1070/RC2006v075n05ABEH001201
UR - https://rcr.colab.ws/publications/10.1070/RC2006v075n05ABEH001201
TI - Principal trends in the chemistry of amidinate complexes of main-group and transition elements
T2 - Russian Chemical Reviews
AU - Kissounko, D A
AU - Zabalov, M V
AU - Brusova, G P
AU - Lemenovskii, Dmitrii Anatol'evich
PY - 2006
DA - 2005/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 351-374
IS - 5
VL - 75
ER -
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@article{2006_Kissounko,
author = {D A Kissounko and M V Zabalov and G P Brusova and Dmitrii Anatol'evich Lemenovskii},
title = {Principal trends in the chemistry of amidinate complexes of main-group and transition elements},
journal = {Russian Chemical Reviews},
year = {2006},
volume = {75},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2006v075n05ABEH001201},
number = {5},
pages = {351--374},
doi = {10.1070/RC2006v075n05ABEH001201}
}
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Kissounko, D. A., et al. “Principal trends in the chemistry of amidinate complexes of main-group and transition elements.” Russian Chemical Reviews, vol. 75, no. 5, Nov. 2006, pp. 351-374. https://rcr.colab.ws/publications/10.1070/RC2006v075n05ABEH001201.
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Abstract

Principal trends in modern organometallic chemistry of transition and main group elements containing amidinate ligands are analysed. The nature of element–amidinate ligand bonding inferred from the X-ray structural data and computational studies is discussed. Synthesis and reactivity of Group 1–15 metal amidinate complexes are reviewed. Particular emphasis is drawn to the use of amidinate complexes as catalysts for olefin polymerisation and organic synthesis. Prospects in the development in this area of chemistry are suggested.