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Energetics of bimolecular nucleophilic reactions in solution

Vladislav Mikhailovich Vlasov 1
Vladislav Mikhailovich Vlasov
1 N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistryof the Siberian Branch of Russian Academy of Sciences
10.1070/RC2006v075n09ABEH003614
Published 30 November 2005
Communication , Volume 75, Issue 9, 765-796
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Vlasov V. M. Energetics of bimolecular nucleophilic reactions in solution // Russian Chemical Reviews. 2006. Vol. 75. No. 9. pp. 765-796.
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Vlasov V. M. Energetics of bimolecular nucleophilic reactions in solution // Russian Chemical Reviews. 2006. Vol. 75. No. 9. pp. 765-796.
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TY - JOUR
DO - 10.1070/RC2006v075n09ABEH003614
UR - https://rcr.colab.ws/publications/10.1070/RC2006v075n09ABEH003614
TI - Energetics of bimolecular nucleophilic reactions in solution
T2 - Russian Chemical Reviews
AU - Vlasov, Vladislav Mikhailovich
PY - 2006
DA - 2005/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 765-796
IS - 9
VL - 75
ER -
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@article{2006_Vlasov,
author = {Vladislav Mikhailovich Vlasov},
title = {Energetics of bimolecular nucleophilic reactions in solution},
journal = {Russian Chemical Reviews},
year = {2006},
volume = {75},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2006v075n09ABEH003614},
number = {9},
pages = {765--796},
doi = {10.1070/RC2006v075n09ABEH003614}
}
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Vlasov, Vladislav Mikhailovich. “Energetics of bimolecular nucleophilic reactions in solution.” Russian Chemical Reviews, vol. 75, no. 9, Nov. 2006, pp. 765-796. https://rcr.colab.ws/publications/10.1070/RC2006v075n09ABEH003614.
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Abstract

Published data on the activation parameters of bimolecular nucleophilic reactions in solution are generalised and described systematically. The factors that influence the relation between the activation parameters in these reactions are discussed. The relationships between the mechanisms of bimolecular nucleophilic substitution and addition reactions and their activation parameters are considered, and the role of the enthalpy–entropy compensation effect is analysed.