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Methods for investigation of the free volume in polymers

Yurii Pavlovich Yampolskii 1
Yurii Pavlovich Yampolskii
1 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
10.1070/RC2007v076n01ABEH003629
Published 30 November 2006
Communication , Volume 76, Issue 1, 59-78
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Yampolskii Y. P. Methods for investigation of the free volume in polymers // Russian Chemical Reviews. 2007. Vol. 76. No. 1. pp. 59-78.
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Yampolskii Y. P. Methods for investigation of the free volume in polymers // Russian Chemical Reviews. 2007. Vol. 76. No. 1. pp. 59-78.
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TY - JOUR
DO - 10.1070/RC2007v076n01ABEH003629
UR - https://rcr.colab.ws/publications/10.1070/RC2007v076n01ABEH003629
TI - Methods for investigation of the free volume in polymers
T2 - Russian Chemical Reviews
AU - Yampolskii, Yurii Pavlovich
PY - 2007
DA - 2006/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 59-78
IS - 1
VL - 76
ER -
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@article{2007_Yampolskii,
author = {Yurii Pavlovich Yampolskii},
title = {Methods for investigation of the free volume in polymers},
journal = {Russian Chemical Reviews},
year = {2007},
volume = {76},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2007v076n01ABEH003629},
number = {1},
pages = {59--78},
doi = {10.1070/RC2007v076n01ABEH003629}
}
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Yampolskii, Yurii Pavlovich. “Methods for investigation of the free volume in polymers.” Russian Chemical Reviews, vol. 76, no. 1, Nov. 2007, pp. 59-78. https://rcr.colab.ws/publications/10.1070/RC2007v076n01ABEH003629.
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Abstract

Experimental probe methods for investigation of the free volume in polymers (positron annihilation lifetime spectroscopy, 129Xe NMR spectroscopy and inverse gas chromatography) and relevant theoretical approaches (computer simulation) are considered. Various definitions of the free volume and related terms are given. The physical principles that underlie particular probe methods as well as the scope and limitations of each method are discussed. A systematic comparison of the size of free-volume elements in polymers determined by different methods is carried out.