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Spin chemistry of enzymatic processes

Maria Sergeevna Afanasyeva 1
Maria Sergeevna Afanasyeva
, 
Petr Aleksandrovich Purtov 1
Petr Aleksandrovich Purtov
, 
Mark Borisovich Taraban 1
Mark Borisovich Taraban
, 
Tatyana Viktorovna Leshina 1
Tatyana Viktorovna Leshina
1 Institute of Chemical Kinetics and Combustion, Siberian Branch of the Russian Academy of Science, Novosibirsk
10.1070/RC2007v076n07ABEH003714
Published 30 November 2006
Communication , Volume 76, Issue 7, 599-615
8
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Afanasyeva M. S. et al. Spin chemistry of enzymatic processes // Russian Chemical Reviews. 2007. Vol. 76. No. 7. pp. 599-615.
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Afanasyeva M. S., Purtov P. A., Taraban M. B., Leshina T. V. Spin chemistry of enzymatic processes // Russian Chemical Reviews. 2007. Vol. 76. No. 7. pp. 599-615.
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TY - JOUR
DO - 10.1070/RC2007v076n07ABEH003714
UR - https://rcr.colab.ws/publications/10.1070/RC2007v076n07ABEH003714
TI - Spin chemistry of enzymatic processes
T2 - Russian Chemical Reviews
AU - Afanasyeva, Maria Sergeevna
AU - Purtov, Petr Aleksandrovich
AU - Taraban, Mark Borisovich
AU - Leshina, Tatyana Viktorovna
PY - 2007
DA - 2006/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 599-615
IS - 7
VL - 76
ER -
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@article{2007_Afanasyeva,
author = {Maria Sergeevna Afanasyeva and Petr Aleksandrovich Purtov and Mark Borisovich Taraban and Tatyana Viktorovna Leshina},
title = {Spin chemistry of enzymatic processes},
journal = {Russian Chemical Reviews},
year = {2007},
volume = {76},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2007v076n07ABEH003714},
number = {7},
pages = {599--615},
doi = {10.1070/RC2007v076n07ABEH003714}
}
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Afanasyeva, Maria Sergeevna, et al. “Spin chemistry of enzymatic processes.” Russian Chemical Reviews, vol. 76, no. 7, Nov. 2007, pp. 599-615. https://rcr.colab.ws/publications/10.1070/RC2007v076n07ABEH003714.
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Abstract

The results of spin chemistry studies of the single electron transfer step and the role of spin states of paramagnetic intermediates in the enzymatic oxidation of organic substrates induced by horseradish peroxidase are generalised. Detailed theoretical description of the approach used to analyse the magnetic field effects in enzymatic multispin systems is presented. Prospects for the use of spin chemistry techniques for elucidation of the mechanisms of radical steps of enzymatic processes are considered.