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Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives

Valentin Yakovlevich Basevich 1
Valentin Yakovlevich Basevich
, 
Sergei Mikhailovich Frolov 1
Sergei Mikhailovich Frolov
1 N. N. Semenov Institute of Chemical Physics, Russian Academy of Sciences, Moscow
10.1070/RC2007v076n09ABEH003703
Published 30 November 2006
Communication , Volume 76, Issue 9, 867-884
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Basevich V. Y., Frolov S. M. Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives // Russian Chemical Reviews. 2007. Vol. 76. No. 9. pp. 867-884.
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Basevich V. Y., Frolov S. M. Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives // Russian Chemical Reviews. 2007. Vol. 76. No. 9. pp. 867-884.
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TY - JOUR
DO - 10.1070/RC2007v076n09ABEH003703
UR - https://rcr.colab.ws/publications/10.1070/RC2007v076n09ABEH003703
TI - Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives
T2 - Russian Chemical Reviews
AU - Basevich, Valentin Yakovlevich
AU - Frolov, Sergei Mikhailovich
PY - 2007
DA - 2006/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 867-884
IS - 9
VL - 76
ER -
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@article{2007_Basevich,
author = {Valentin Yakovlevich Basevich and Sergei Mikhailovich Frolov},
title = {Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives},
journal = {Russian Chemical Reviews},
year = {2007},
volume = {76},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2007v076n09ABEH003703},
number = {9},
pages = {867--884},
doi = {10.1070/RC2007v076n09ABEH003703}
}
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Basevich, Valentin Yakovlevich, and Sergei Mikhailovich Frolov. “Kinetics of ′blue' flames in the gas-phase oxidation and combustion of hydrocarbons and their derivatives.” Russian Chemical Reviews, vol. 76, no. 9, Nov. 2007, pp. 867-884. https://rcr.colab.ws/publications/10.1070/RC2007v076n09ABEH003703.
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Abstract

Experimental and calculated data on the kinetics of ′blue' flame observed in the gas-phase oxidation and combustion of hydrocarbons and their derivatives are considered. It is shown that blue flames arise due to the decomposition of hydrogen peroxide that forms in the oxidation of hydrocarbons. They manifest themselves by light emission, are identified by partial heat release (the appearance of a step in the time dependences of temperature and pressure observed in closed-vessel experiments) and propagate as conventional hot flames.