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Tunnelling chemical reactions of hydrogen isotopes in quantum solids

Vladimir Vasil'evich Khmelenko 1, 2
Vladimir Vasil'evich Khmelenko
, 
Ethan P Bernard 2
Ethan P Bernard
, 
S А Vasiliev 3
S А Vasiliev
, 
David M Lee 2
David M Lee
1 Institute of Energy Problems of Chemical Physics, Russian Academy of Sciences, Moscow
2 Department of Physics, Cornell University
3 Department of Physics, University of Turku
10.1070/RC2007v076n12ABEH003729
Published 30 November 2006
Communication , Volume 76, Issue 12, 1107-1121
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Khmelenko V. V. et al. Tunnelling chemical reactions of hydrogen isotopes in quantum solids // Russian Chemical Reviews. 2007. Vol. 76. No. 12. pp. 1107-1121.
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Khmelenko V. V., Bernard E. P., Vasiliev S. А., Lee D. M. Tunnelling chemical reactions of hydrogen isotopes in quantum solids // Russian Chemical Reviews. 2007. Vol. 76. No. 12. pp. 1107-1121.
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TY - JOUR
DO - 10.1070/RC2007v076n12ABEH003729
UR - https://rcr.colab.ws/publications/10.1070/RC2007v076n12ABEH003729
TI - Tunnelling chemical reactions of hydrogen isotopes in quantum solids
T2 - Russian Chemical Reviews
AU - Khmelenko, Vladimir Vasil'evich
AU - Bernard, Ethan P
AU - Vasiliev, S А
AU - Lee, David M
PY - 2007
DA - 2006/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1107-1121
IS - 12
VL - 76
ER -
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@article{2007_Khmelenko,
author = {Vladimir Vasil'evich Khmelenko and Ethan P Bernard and S А Vasiliev and David M Lee},
title = {Tunnelling chemical reactions of hydrogen isotopes in quantum solids},
journal = {Russian Chemical Reviews},
year = {2007},
volume = {76},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2007v076n12ABEH003729},
number = {12},
pages = {1107--1121},
doi = {10.1070/RC2007v076n12ABEH003729}
}
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Khmelenko, Vladimir Vasil'evich, et al. “Tunnelling chemical reactions of hydrogen isotopes in quantum solids.” Russian Chemical Reviews, vol. 76, no. 12, Nov. 2007, pp. 1107-1121. https://rcr.colab.ws/publications/10.1070/RC2007v076n12ABEH003729.
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Abstract

The kinetics of tunnelling reactions of hydrogen isotopes in solid molecular nanoclusters immersed in superfluid helium and the changes in the environment of the atoms during the course of these reactions are reviewed. Results of pulsed electron spin resonance show that a very large fraction (50%–60%) of the stabilised atoms reside on the surfaces of the nanoclusters. The results of studies of the recombination and the exotic behaviour of hydrogen atoms in a solid molecular hydrogen matrix at ultralow temperatures (0.15–0.9 K) are also discussed.

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