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Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials

Vladislav Veniaminovich Malakhov 1
Vladislav Veniaminovich Malakhov
, 
I G Vasilyeva 2
I G Vasilyeva
1 Boreskov Institute of Catalysis SB RAS, Novosibirsk
2 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RC2008v077n04ABEH003737
Published 30 November 2007
Communication , Volume 77, Issue 4, 351-372
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Malakhov V. V., Vasilyeva I. G. Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials // Russian Chemical Reviews. 2008. Vol. 77. No. 4. pp. 351-372.
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Malakhov V. V., Vasilyeva I. G. Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials // Russian Chemical Reviews. 2008. Vol. 77. No. 4. pp. 351-372.
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TY - JOUR
DO - 10.1070/RC2008v077n04ABEH003737
UR - https://rcr.colab.ws/publications/10.1070/RC2008v077n04ABEH003737
TI - Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials
T2 - Russian Chemical Reviews
AU - Malakhov, Vladislav Veniaminovich
AU - Vasilyeva, I G
PY - 2008
DA - 2007/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 351-372
IS - 4
VL - 77
ER -
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@article{2008_Malakhov,
author = {Vladislav Veniaminovich Malakhov and I G Vasilyeva},
title = {Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials},
journal = {Russian Chemical Reviews},
year = {2008},
volume = {77},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2008v077n04ABEH003737},
number = {4},
pages = {351--372},
doi = {10.1070/RC2008v077n04ABEH003737}
}
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Malakhov, Vladislav Veniaminovich, and I G Vasilyeva. “Stoichiography and chemical methods of phase analysis of multielement multiphase substances and materials.” Russian Chemical Reviews, vol. 77, no. 4, Nov. 2008, pp. 351-372. https://rcr.colab.ws/publications/10.1070/RC2008v077n04ABEH003737.
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Abstract

The problems and achievements in the determination of the phase composition of multielement multiphase inorganic solid substances are considered. The problems of theory, methodology and practical use of two chemical methods of phase analysis, viz., selective dissolution and reference-free stoichiographic dissolution are discussed. The unique potential of stoichiography and differential dissolution method, which allows one to overcome many limitations and difficulties typical of modern phase analysis techniques, are demonstrated. Examples of using differential dissolution for the phase analysis of diverse substances and functional materials are given.