Home / Articles / On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states

On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states

Yurii Mikhailovich Kiselev 1
Yurii Mikhailovich Kiselev
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC2009v078n01ABEH003873
Published 30 November 2008
Communication , Volume 78, Issue 1, 1-20
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Kiselev Y. M. On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states // Russian Chemical Reviews. 2009. Vol. 78. No. 1. pp. 1-20.
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Kiselev Y. M. On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states // Russian Chemical Reviews. 2009. Vol. 78. No. 1. pp. 1-20.
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TY - JOUR
DO - 10.1070/RC2009v078n01ABEH003873
UR - https://rcr.colab.ws/publications/10.1070/RC2009v078n01ABEH003873
TI - On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states
T2 - Russian Chemical Reviews
AU - Kiselev, Yurii Mikhailovich
PY - 2009
DA - 2008/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1-20
IS - 1
VL - 78
ER -
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@article{2009_Kiselev,
author = {Yurii Mikhailovich Kiselev},
title = {On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states},
journal = {Russian Chemical Reviews},
year = {2009},
volume = {78},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2009v078n01ABEH003873},
number = {1},
pages = {1--20},
doi = {10.1070/RC2009v078n01ABEH003873}
}
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Kiselev, Yurii Mikhailovich. “On matrix stabilisation of d- and f-transition metal ions in unstable oxidation states.” Russian Chemical Reviews, vol. 78, no. 1, Nov. 2009, pp. 1-20. https://rcr.colab.ws/publications/10.1070/RC2009v078n01ABEH003873.
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Abstract

The state-of-the-art in matrix stabilisation of d- and f-transition metal ions in unstable oxidation states is analysed. Main aspects of this problem concerning the genealogy of appropriate matrix systems are classified. Relevant examples are given and the data that contradict the scheme proposed are discussed. The thermodynamics of the matrix stabilisation effect is considered using the concept of isomorphic miscibility. The influence of defects and non-equilibrium on the matrix stabilisation effect is discussed. The problem of identification of the oxidation states in matrix systems is examined and various types of matrix systems are considered.

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