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Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds

Anatolii Leonidovich Buchachenko 1
Anatolii Leonidovich Buchachenko
1 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2009v078n04ABEH003904
Published 30 November 2008
Communication , Volume 78, Issue 4, 319-328
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Buchachenko A. L. Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds // Russian Chemical Reviews. 2009. Vol. 78. No. 4. pp. 319-328.
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Buchachenko A. L. Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds // Russian Chemical Reviews. 2009. Vol. 78. No. 4. pp. 319-328.
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TY - JOUR
DO - 10.1070/RC2009v078n04ABEH003904
UR - https://rcr.colab.ws/publications/10.1070/RC2009v078n04ABEH003904
TI - Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds
T2 - Russian Chemical Reviews
AU - Buchachenko, Anatolii Leonidovich
PY - 2009
DA - 2008/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 319-328
IS - 4
VL - 78
ER -
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@article{2009_Buchachenko,
author = {Anatolii Leonidovich Buchachenko},
title = {Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds},
journal = {Russian Chemical Reviews},
year = {2009},
volume = {78},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2009v078n04ABEH003904},
number = {4},
pages = {319--328},
doi = {10.1070/RC2009v078n04ABEH003904}
}
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Buchachenko, Anatolii Leonidovich. “Mercury isotope effects in the environmental chemistry and biochemistry of mercury-containing compounds.” Russian Chemical Reviews, vol. 78, no. 4, Nov. 2009, pp. 319-328. https://rcr.colab.ws/publications/10.1070/RC2009v078n04ABEH003904.
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Abstract

Mercury isotope effects in environmentally significant chemical and biochemical reactions are considered. The recently discovered anomaly for the 199Hg and 201Hg magnetic nuclei proves that both chemical and biochemical transformations of mercury compounds (outside and inside living organisms) follow radical spin-selective mechanisms. The regularities of isotope fractionation in natural photochemical processes and in living tissues are discussed.