Home / Articles / Spectroscopy and structure of free radicals stabilized in cryogenic matrices

Spectroscopy and structure of free radicals stabilized in cryogenic matrices

Esfir Grigor'evna Baskir 1
Esfir Grigor'evna Baskir
, 
Evgenii Yakovlevich Misochko 2
Evgenii Yakovlevich Misochko
, 
Oleg Matveevich Nefedov 1
Oleg Matveevich Nefedov
1 N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
2 Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RC2009v078n08ABEH003758
Published 30 November 2008
Communication , Volume 78, Issue 8, 683-715
17
Share
Cite this
GOST
 | 
Cite this
GOST
Copy cite
Baskir E. G., Misochko E. Y., Nefedov O. M. Spectroscopy and structure of free radicals stabilized in cryogenic matrices // Russian Chemical Reviews. 2009. Vol. 78. No. 8. pp. 683-715.
GOST all authors (up to 50)
Copy cite
Baskir E. G., Misochko E. Y., Nefedov O. M. Spectroscopy and structure of free radicals stabilized in cryogenic matrices // Russian Chemical Reviews. 2009. Vol. 78. No. 8. pp. 683-715.
RIS
 | 
Cite this
RIS
Copy cite
TY - JOUR
DO - 10.1070/RC2009v078n08ABEH003758
UR - https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH003758
TI - Spectroscopy and structure of free radicals stabilized in cryogenic matrices
T2 - Russian Chemical Reviews
AU - Baskir, Esfir Grigor'evna
AU - Misochko, Evgenii Yakovlevich
AU - Nefedov, Oleg Matveevich
PY - 2009
DA - 2008/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 683-715
IS - 8
VL - 78
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
Copy cite
@article{2009_Baskir,
author = {Esfir Grigor'evna Baskir and Evgenii Yakovlevich Misochko and Oleg Matveevich Nefedov},
title = {Spectroscopy and structure of free radicals stabilized in cryogenic matrices},
journal = {Russian Chemical Reviews},
year = {2009},
volume = {78},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH003758},
number = {8},
pages = {683--715},
doi = {10.1070/RC2009v078n08ABEH003758}
}
MLA
Cite this
MLA
Copy cite
Baskir, Esfir Grigor'evna, et al. “Spectroscopy and structure of free radicals stabilized in cryogenic matrices.” Russian Chemical Reviews, vol. 78, no. 8, Nov. 2009, pp. 683-715. https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH003758.
Views / Visits / Downloads
12 / 12 / 3

Abstract

The results of spectroscopic (mainly vibrational IR spectroscopy and EPR spectroscopy) studies of radicals stabilized in solid inert-gas matrices are considered. Attention is focused on a comparison of experimental spectroscopic characteristics of radicals with those simulated by modern quantum chemical computation methods and on the use of these data for the elucidation of molecular and electronic structures of free radicals. The potential of new methods for radical generation in cryogenic matrices and the prospects for their application in spectroscopic studies are discussed. Data from the recent and earlier studies are compared.