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Organocatalysis of asymmetric aldol reaction. Catalysts and reagents

Sergei Grigorievich Zlotin 1
Sergei Grigorievich Zlotin
, 
Alexander Sergeevich Kucherenko 1
Alexander Sergeevich Kucherenko
, 
1 N.D. Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences
2 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC2009v078n08ABEH004040
Published 30 November 2008
Communication , Volume 78, Issue 8, 737-784
112
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Zlotin S. G., Kucherenko A. S., Beletskaya I. P. Organocatalysis of asymmetric aldol reaction. Catalysts and reagents // Russian Chemical Reviews. 2009. Vol. 78. No. 8. pp. 737-784.
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Zlotin S. G., Kucherenko A. S., Beletskaya I. P. Organocatalysis of asymmetric aldol reaction. Catalysts and reagents // Russian Chemical Reviews. 2009. Vol. 78. No. 8. pp. 737-784.
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TY - JOUR
DO - 10.1070/RC2009v078n08ABEH004040
UR - https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH004040
TI - Organocatalysis of asymmetric aldol reaction. Catalysts and reagents
T2 - Russian Chemical Reviews
AU - Zlotin, Sergei Grigorievich
AU - Kucherenko, Alexander Sergeevich
AU - Beletskaya, Irina Petrovna
PY - 2009
DA - 2008/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 737-784
IS - 8
VL - 78
ER -
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@article{2009_Zlotin,
author = {Sergei Grigorievich Zlotin and Alexander Sergeevich Kucherenko and Irina Petrovna Beletskaya},
title = {Organocatalysis of asymmetric aldol reaction. Catalysts and reagents},
journal = {Russian Chemical Reviews},
year = {2009},
volume = {78},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH004040},
number = {8},
pages = {737--784},
doi = {10.1070/RC2009v078n08ABEH004040}
}
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Zlotin, Sergei Grigorievich, et al. “Organocatalysis of asymmetric aldol reaction. Catalysts and reagents.” Russian Chemical Reviews, vol. 78, no. 8, Nov. 2009, pp. 737-784. https://rcr.colab.ws/publications/10.1070/RC2009v078n08ABEH004040.
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Abstract

The review is devoted to the application of organocatalysis for the asymmetric aldol reaction, which is one of the most important methods for carbon–carbon bond formation in organic compounds. The mechanism of enamine catalysis and the main types of organocatalysts for the aldol reaction are considered, data on this type of reactions involving carbonyl compounds with various electronic and spatial structures are classified. The effects of organocatalyst structure on the regio-, stereo- and enantioselectivity of intramolecular and intermolecular aldol reactions are reviewed.