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The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products

Irina Yur'evna Sapurina 1
Irina Yur'evna Sapurina
, 
Jaroslav Stejskal 2
Jaroslav Stejskal
1 Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg
2 Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Prague, Czech Republic
10.1070/RC2010v079n12ABEH004140
Published 30 November 2009
Communication , Volume 79, Issue 12, 1123-1143
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Sapurina I. Y., Stejskal J. The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products // Russian Chemical Reviews. 2010. Vol. 79. No. 12. pp. 1123-1143.
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Sapurina I. Y., Stejskal J. The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products // Russian Chemical Reviews. 2010. Vol. 79. No. 12. pp. 1123-1143.
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TY - JOUR
DO - 10.1070/RC2010v079n12ABEH004140
UR - https://rcr.colab.ws/publications/10.1070/RC2010v079n12ABEH004140
TI - The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products
T2 - Russian Chemical Reviews
AU - Sapurina, Irina Yur'evna
AU - Stejskal, Jaroslav
PY - 2010
DA - 2009/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1123-1143
IS - 12
VL - 79
ER -
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@article{2010_Sapurina,
author = {Irina Yur'evna Sapurina and Jaroslav Stejskal},
title = {The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products},
journal = {Russian Chemical Reviews},
year = {2010},
volume = {79},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2010v079n12ABEH004140},
number = {12},
pages = {1123--1143},
doi = {10.1070/RC2010v079n12ABEH004140}
}
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Sapurina, Irina Yur'evna, and Jaroslav Stejskal. “The effect of pH on the oxidative polymerization of aniline and the morphology and properties of products.” Russian Chemical Reviews, vol. 79, no. 12, Nov. 2010, pp. 1123-1143. https://rcr.colab.ws/publications/10.1070/RC2010v079n12ABEH004140.
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Abstract

The synthesis and properties of the most popular and widely used electrically conducting polymer, polyaniline, are considered. The proposed mechanisms of the molecular synthesis and self-assembly of macromolecules occurring during the polymerization agree with the large body of experimental data. The reaction medium acidity is demonstrated to affect the mechanism of aniline oxidative polymerization and the formation of different types of supramolecular structures, namely, nanoglobules, nanofibres, nanotubes and microspheres.