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Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer

T D Nekipelova 1
T D Nekipelova
, 
Vladimir Alexandrovich Kuzmin 1
Vladimir Alexandrovich Kuzmin
1 Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, Moscow
Published 30 November 2011
Communication , Volume 81, Issue 11, 983-993
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Nekipelova T. D., Kuzmin V. A. Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer // Russian Chemical Reviews. 2012. Vol. 81. No. 11. pp. 983-993.
GOST all authors (up to 50)
Nekipelova T. D., Kuzmin V. A. Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer // Russian Chemical Reviews. 2012. Vol. 81. No. 11. pp. 983-993.
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TY - JOUR
DO - 10.1070/RC2012v081n11ABEH004293
UR - https://rcr.colab.ws/publications/10.1070/RC2012v081n11ABEH004293
TI - Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer
T2 - Russian Chemical Reviews
AU - Nekipelova, T D
AU - Kuzmin, Vladimir Alexandrovich
PY - 2012
DA - 2011/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 983-993
IS - 11
VL - 81
ER -
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BibTex (up to 50 authors)
@article{2012_Nekipelova,
author = {T D Nekipelova and Vladimir Alexandrovich Kuzmin},
title = {Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer},
journal = {Russian Chemical Reviews},
year = {2012},
volume = {81},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2012v081n11ABEH004293},
number = {11},
pages = {983--993},
doi = {10.1070/RC2012v081n11ABEH004293}
}
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Nekipelova, T. D., and Vladimir Alexandrovich Kuzmin. “Light-induced transformations of 1,2-dihydroquinolines: opening of the heterocycle, radical formation and photoinduced proton transfer.” Russian Chemical Reviews, vol. 81, no. 11, Nov. 2012, pp. 983-993. https://rcr.colab.ws/publications/10.1070/RC2012v081n11ABEH004293.
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Abstract

Three types of light-induced photochemical reactions of 1,2-dihydroquinolines, opening of the heterocycle, formation of aminyl radicals upon the homolytic N–H bond cleavage and proton transfer in protic solvents, have been considered. Special attention has been focused on the photoinduced proton transfer reactions. The effect of the dihydroquinoline structure and solvent composition on the routes and kinetic parameters of photochemical reactions has been analyzed. The bibliography includes 108 references.