Home / Articles / The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes

The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes

Vitaly Ivanovich Volkov 1
Vitaly Ivanovich Volkov
, 
Aleksandr Alekseevich Marinin 1
Aleksandr Alekseevich Marinin
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences
10.1070/RC2013v082n03ABEH004278
Published 30 November 2012
Communication , Volume 82, Issue 3, 248-272
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Volkov V. I., Marinin A. A. The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 248-272.
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Volkov V. I., Marinin A. A. The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 248-272.
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TY - JOUR
DO - 10.1070/RC2013v082n03ABEH004278
UR - https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004278
TI - The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes
T2 - Russian Chemical Reviews
AU - Volkov, Vitaly Ivanovich
AU - Marinin, Aleksandr Alekseevich
PY - 2013
DA - 2012/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 248-272
IS - 3
VL - 82
ER -
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@article{2013_Volkov,
author = {Vitaly Ivanovich Volkov and Aleksandr Alekseevich Marinin},
title = {The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes},
journal = {Russian Chemical Reviews},
year = {2013},
volume = {82},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004278},
number = {3},
pages = {248--272},
doi = {10.1070/RC2013v082n03ABEH004278}
}
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Volkov, Vitaly Ivanovich, and Aleksandr Alekseevich Marinin. “The application of NMR techniques in the studies of ion and molecular transport in polymeric electrolytes.” Russian Chemical Reviews, vol. 82, no. 3, Nov. 2013, pp. 248-272. https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004278.
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Abstract

The results of studies demonstrating the potential of NMR techniques in the studies of formation of transport channels, the mechanisms of ion–polymer matrix interaction and ion and molecule mobility and diffusion in the polymeric electrolytes are analyzed and generalized. The ion exchange membranes with chemically different polymer matrices are considered. The translational mobilities of ions measured by NMR with magnetic field pulse gradient are compared with the ion conductivity data obtained by impedance spectroscopy. The primary attention is paid to the possibilities of NMR for the studies of the states of ions and molecules in electrolytes and their diffusional mobility on different spatial scales. On the basis of NMR data, ion transport mechanisms in ion exchange perfluorinated membranes are proposed. Bibliography — 182 references.

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