Home / Articles / Polymerization of silicon-carbon heterocycles

Polymerization of silicon-carbon heterocycles

Nikolay Victorovich Ushakov 1
Nikolay Victorovich Ushakov
, 
Evgenii Shmerovich Finkelshtein 1
Evgenii Shmerovich Finkelshtein
1 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Published 30 November 2012
Communication , Volume 82, Issue 3, 205-227
13
Share
Cite this
GOST
 | 
Cite this
GOST
Ushakov N. V., Finkelshtein E. S. Polymerization of silicon-carbon heterocycles // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 205-227.
GOST all authors (up to 50)
Ushakov N. V., Finkelshtein E. S. Polymerization of silicon-carbon heterocycles // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 205-227.
RIS
 | 
Cite this
RIS
TY - JOUR
DO - 10.1070/RC2013v082n03ABEH004323
UR - https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004323
TI - Polymerization of silicon-carbon heterocycles
T2 - Russian Chemical Reviews
AU - Ushakov, Nikolay Victorovich
AU - Finkelshtein, Evgenii Shmerovich
PY - 2013
DA - 2012/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 205-227
IS - 3
VL - 82
ER -
BibTex
 | 
Cite this
BibTex (up to 50 authors)
@article{2013_Ushakov,
author = {Nikolay Victorovich Ushakov and Evgenii Shmerovich Finkelshtein},
title = {Polymerization of silicon-carbon heterocycles},
journal = {Russian Chemical Reviews},
year = {2013},
volume = {82},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004323},
number = {3},
pages = {205--227},
doi = {10.1070/RC2013v082n03ABEH004323}
}
MLA
Cite this
MLA
Ushakov, Nikolay Victorovich, and Evgenii Shmerovich Finkelshtein. “Polymerization of silicon-carbon heterocycles.” Russian Chemical Reviews, vol. 82, no. 3, Nov. 2013, pp. 205-227. https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004323.
Views / Visits / Downloads
17 / 17 / 6

Abstract

Ring-opening polymerization methods for all of the known reactive silicon-carbon heterocycles are considered. The data concerning the catalytic polymerization of silicon-containing cyclic monomers published in the last 15 years are generalized. The results of investigations of polymerization mechanisms are presented, the properties of polymers are described and examples of their practical use are given. Bibliography — 206 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
4
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
5.
Polycarbosilanes Based on Silicon-Carbon Cyclic Monomers
Finkelshtein E.S., Ushakov N.V., Gringolts M.L.
Advances in Polymer Science , 2010
6.
Synthesis and polymerization ofSi-substituted silacyclobutanes
Ushakov N.V., Fedorova G.K., Finkel'shtein E.S.
Russian Chemical Bulletin , 1995
7.
7
E. Rabinowitch
"Photosynthesis" , 1956
8.
8
V. N. Kondrat'ev
"Kinetika Reaktsii v Gazovoi Faze" (Kinetics of Reactions in the Gas Phase) , 1959
9.
9
V. H. Lynch
Carnegie Inst. Year Book , 1954
10.
10
T. A. Kryukova
"Polyaro-graficheskii Analiz" (Polarographic Analysis) , 1959
11.
New polysilalkylenes: synthesis and gas-separation properties
Finkelshtein E.S., Ushakov N.V., Krasheninnikov E.G., Yampolskii Y.P.
Russian Chemical Bulletin , 2004
12.
12
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
13.
13
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1954
15.
15
A. S. Holt
"Research in Photosynthesis" , 1957
16.
16
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1949
20.
20
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1954
21.
21
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1958
22.
10.1002/(SICI)1099-0518(19971115)35:15<3207::AID-POLA13>3.0.CO;2-F
25.
Anionic Ring-Opening Polymerization of Phenylsilacyclobutanes
Matsumoto K., Shinohata M., Yamaoka H.
Polymer Journal , 2000
26.
Polymerization of 1,1,2-Trimethylsilacyclobutane
Komuro K., Kawakami Y.
Polymer Journal , 1999
27.
10.1002/(SICI)1099-0518(19980130)36:2<225::AID-POLA3>3.0.CO;2-Q
29.
Controlled synthesis of silicon-containing polymers by metal catalysts
Kawakami Y., Park S.Y., Uenishi K., Oishi M., Imae I.
Polymer International , 2003
30.
10.1002/(SICI)1099-0518(19981115)36:15<2699::AID-POLA4>3.0.CO;2-N
34.
10.1002/1099-0518(20010101)39:1<86::AID-POLA100>3.0.CO;2-K
36.
Preparation of Poly(1,1-dimethyl silabutane) by Anionic Polymerization and Its Crystallization
Kawahara S., Nagai A., Kazama T., Takano A., Isono Y.
Macromolecules , 2003
41.
41
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1950
43.
10.1002/(SICI)1521-3935(20000401)201:7<805::AID-MACP805>3.0.CO;2-3
46.
Synthesis and Lithographic Patterning of Polycarbosilanes with Pendant Cobalt Carbonyl Clusters
Greenberg S., Clendenning S.B., Liu K., Manners I., Aouba S., Ruda H.E.
Macromolecules , 2005
51.
Highly Active Visible-Light Photocatalysts for Curing a Ceramic Precursor1
Guo A., Fry B.E., Neckers D.C.
Chemistry of Materials , 1998
55.
Poly(diarylsilmethylene)s, I. Synthesis and characterization
Ogawa T., Tachikawa M., Kushibiki N., Murakami M.
Journal of Polymer Science, Part A: Polymer Chemistry , 1995
56.
56
T. Iasui
Bull. Chem. Soc. Japan. , 1935
57.
Poly(silylenemethylenes) — a novel class of organosilicon polymers
Interrante L.V., Liu Q., Rushkin I., Shen Q.
Journal of Organometallic Chemistry , 1996
58.
Poly(di-n-alkylsiloxane)s with Long Alkyl Side Groups
Out G.J., Turetskii A.A., Moeller M., Oelfin D.
Macromolecules , 1994
59.
Crystalline and disordered state of poly(dihexylsilylene) copolymers
Frey H., Möller M., Matyjaszewski K., Oelfin D.
Macromolecular Chemistry and Physics , 1995
61.
Synthesis and mesomorphic behavior of poly(dipropylsilylenemethylene)
Koopmann F., Frey H.
Macromolecular Rapid Communications , 1995
67.
Modification of a Hyperbranched Hydridopolycarbosilane as a Route to New Polycarbosilanes
Rushkin I.L., Shen Q., Lehman S.E., Interrante L.V.
Macromolecules , 1997
69.
Synthesis and Characterization of the New Fluoropolymer Poly(difluorosilylenemethylene); An Analogue of Poly(vinylidene fluoride)
Lienhard M., Rushkin I., Verdecia G., Wiegand C., Apple T., Interrante L.V.
Journal of the American Chemical Society , 1997
70.
10.1002/(SICI)1099-0739(199810/11)12:10/11<695::AID-AOC774>3.0.CO;2-7
71.
10.1002/(SICI)1521-3935(19981001)199:10<2119::AID-MACP2119>3.0.CO;2-U
72.
10.1002/(SICI)1099-0518(19980415)36:5<725::AID-POLA6>3.0.CO;2-K
73.
Structural Characterization of Poly(silylenemethylene)
Shen Q.H., Interrante L.V.
Macromolecules , 1996
74.
Synthesis and characterization of cyano-substituted disilacyclobutane rings and poly(silylenemethylene) polymers
Lienhard M., Wiegand C., Apple T., Interrante L.V.
Journal of Organometallic Chemistry , 2003
75.
75
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
76.
76
A. N. Terenin
"Fotokhimiya Krasitelei" (The Photochemistry of Dyes) , 1947
77.
77
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
79.
79
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1952
81.
81
J. C. Ghosh
J. Indian Chem. Soc. , 1934
82.
A Novel Polycarbosilane-Based Low-k Dielectric Material
Wang P., Wu Z., Lu T., Interrante L.V.
Journal of the Electrochemical Society , 2006
84.
Polymer-Derived Ceramics: 40 Years of Research and Innovation in Advanced Ceramics
Colombo P., Mera G., Riedel R., Sorarù G.D.
Journal of the American Ceramic Society , 2010
85.
10.1002/(SICI)1099-0518(199702)35:3<399::AID-POLA2>3.0.CO;2-O
86.
10.1002/(SICI)1099-0518(199706)35:8<1431::AID-POLA12>3.0.CO;2-8
91.
Fabrication of Poly(diphenylsilylenemethylene) and Poly(diphenylsiloxane) Thin Films Using Fine Metal Particles
Rossignol F., Nakata Y., Nagai H., Okutani T., Suzuki M., Kushibiki N., Murakami M.
Chemistry of Materials , 1999
92.
Properties of Poly(diphenylsilylenemethylene) Thin Films Fabricated with Fine Metal Particles
Rossignol F., Konno S., Nakata Y., Nagai H., Okutani T., Suzuki M., Kushibiki N., Murakami M.
Chemistry of Materials , 1999
93.
Effect of laser-ablated copper nanoparticles on polymerization of 1,1,3,3-tetraphenyl-1,3-disilacyclobutane
Song R.G., Yamaguchi M., Nishimura O., Shimokawa K., Kushibiki N., Suzuki M.
Applied Physics A: Materials Science and Processing , 2004
94.
Investigation of metal nanoparticles produced by laser ablation and their catalytic activity
Song R.G., Yamaguchi M., Nishimura O., Suzuki M.
Applied Surface Science , 2007
95.
95
A. A. Krasnovskii
Fiziologiya Rastenii , 1957
96.
96
L. M. Vorob'eva
Biokhimiya , 1958
99.
Anionic Ring-Opening Polymerization of Silacyclopropanes
Matsumoto K., Matsuoka H.
Macromolecules , 2003
100.
100
V. V. Zolotarev
Chem. Abs. , 1941
101.
101
M. F. Shostakovskii
Izv. Akad. Nauk SSSR, Otd. Khim. Nauk , 1960
102.
102
F. Fichter
Helv. Chim. Acta , 1922
103.
103
L. N. Bell
Dokl. Akad. Nauk SSSR , 1956
106.
106
F. Fichter
Helv. Chim. Acta , 1927
107.
107
M. F. Shostakovskii
Zhur. Obshch. Khim. , 1961
108.
SILA- AND GERMACYCLOPENTENES IN FUNDAMENTAL AND APPLIED ORGANOMETALLIC CHEMISTRY
Manuel G., Weber W.P., Boukherroub R.
Main Group Metal Chemistry , 1996
109.
Synthesis, dimerization, and oligomerization of 5-silaspiro[4.4]non-2-ene
Ushakov N.V., Finkel’shtein E.S.
Russian Chemical Bulletin , 2009
110.
110
M. F. Shostakovskii
Dokl. Akad. Nauk SSSR , 1960
111.
111
M. Calvin
1956
113.
113
H. Blum
"Photodynamic Action and Diseases caused Light" , 1940
115.
Synthesis and Properties of Poly(ferrocenyldihydrosilane) Homopolymer and Random Copolymers
Pudelski J.K., Rulkens R., Foucher D.A., Lough A.J., MacDonald P.M., Manners I.
Macromolecules , 1995
117.
Elschenbroich C., Bretschneider-Hurley A., Hurley J., Massa W., Wocadlo S., Pebler J., Reijerse E.
Inorganic Chemistry , 1993
122.
Transition metal catalyzed ring-opening polymerization of silicon-bridged [1]ferrocenophanes at ambient temperature
123.
Platinum- or palladium-catalysed ring-opening homo- and co-polymerization of silicon- and germanium-bridged [1]ferrocenophanes
Reddy N.P., Yamashita H., Tanaka M.
Journal of the Chemical Society Chemical Communications , 1995
130.
10.1002/(SICI)1521-3765(19981102)4:11<2117::AID-CHEM2117>3.0.CO;2-E
131.
(Bis{2,4,6-triisopropylphenyl}stannylene)ferrocenophane and Related Ring-Opened Products
Sharma H.K., Cervantes-Lee F., Mahmoud J.S., Pannell K.H.
Organometallics , 1999
132.
Nucleophilically Assisted Ring-Opening Polymerization of Group 14 Element-Bridged [1]Ferrocenophanes
Jäkle F., Rulkens R., Zech G., Massey J.A., Manners I.
Journal of the American Chemical Society , 2000
133.
Synthesis, Properties, and Functionalization of Poly(ferrocenylsilane)s with Chloroalkyl Side Chains
Power-Billard K.N., Peckham T.J., Butt A., Jäkle F., Manners I.
Journal of Inorganic and Organometallic Polymers , 2000
134.
Ring-Opening Polymerization Behavior of ansa- and Spirocyclic ansa-Zirconocene Complexes
Peckham T.J., Nguyen P., Bourke S.C., Wang Q., Harrison D.G., Zoricak P., Russell C., Liable-Sands L.M., Rheingold A.L., Lough A.J., Manners I.
Organometallics , 2001
135.
Thermal and Transition-Metal-Catalyzed Ring-Opening Polymerization (ROP) of [1]Silaferrocenophanes with Chlorine Substituents at Silicon:  A Route to Tunable Poly(ferrocenylsilanes)
Zechel D.L., Hultzsch K.C., Rulkens R., Balaishis D., Ni Y., Pudelski J.K., Lough A.J., Manners I., Foucher D.A.
Organometallics , 1996
137.
Silacyclobutenes – Synthesis and reactivity
Mohseni-Ala J., Auner N.
Inorganica Chimica Acta , 2006
138.
Superparamagnetic Ceramic Nanocomposites:  Synthesis and Pyrolysis of Ring-Opened Poly(ferrocenylsilanes) inside Periodic Mesoporous Silica
MacLachlan M.J., Ginzburg M., Coombs N., Raju N.P., Greedan J.E., Ozin G.A., Manners I.
Journal of the American Chemical Society , 2000
139.
Shaped Ceramics with Tunable Magnetic Properties from Metal-Containing Polymers
MacLachlan M.J., Ginzburg M., Coombs N., Coyle T.W., Raju N.P., Greedan J.E., Ozin G.A., Manners I.
Science , 2000
140.
140
1912
141.
Poly(ferrocenyldimethylsilanes) for Reactive Ion Etch Barrier Applications
Lammertink R.G., Hempenius M.A., Chan V.Z., Thomas E.L., Vancso G.J.
Chemistry of Materials , 2001
142.
Photooxidation and Photoconductivity of Polyferrocenylsilane Thin Films
Cyr P.W., Tzolov M., Manners I., Sargent E.H.
Macromolecular Chemistry and Physics , 2003
143.
Synthesis and Characterization of Poly(ferrocenylsilane)s and Their Charge Transfer Salts
Tang H., Liu Y., Chen X., Qin J., Inokuchi M., Kinoshita M., Jin X., Wang Z., Xu B.
Macromolecules , 2004
144.
10.1002/1521-3927(20020201)23:3<210::AID-MARC210>3.0.CO;2-C
150.
Controlling the Morphologies of Organometallic Block Copolymers in the 3-Dimensional Spatial Confinement of Colloidal and Inverse Colloidal Crystals
152.
Optical Properties of Poly(ferrocenylsilane) Multilayer Thin Films
Kooij E.S., Ma Y., Hempenius M.A., Vancso G.J., Poelsema B.
Langmuir , 2010
156.
10.1021/ja030559+
157.
Study on synthesis and properties of poly(ferrocenylnbutylmethylsilane) with unsymmetrical silicon substitution groups
158.
Trovacene Chemistry. 10 [1] The [1]- and [2]Silatrovacenophanes (η7-iR2) and (η7-iR2 (R = Me, Ph): Synthesis, Structure, and Ring Opening
Elschenbroich C., Paganelli F., Nowotny M., Neumüller B., Burghaus O.
Zeitschrift fur Anorganische und Allgemeine Chemie , 2004
159.
Synthesis ofansa-[n]Silacyclopentadienyl-Cycloheptatrienyl-Chromium Complexes (n = 1, 2): Novel Precursors for Polymers Bearing Chromium in the Backbone
Bartole-Scott A., Braunschweig H., Kupfer T., Lutz M., Manners I., Nguyen T., Radacki K., Seeler F.
Chemistry - A European Journal , 2006
160.
Ansa [1]Trochrocenophanes and Their Related Unstrained 1,1‘-Disubstituted Counterparts:  Synthesis and Electronic Structure
Braunschweig H., Kupfer T., Lutz M., Radacki K.
Journal of the American Chemical Society , 2007
161.
Selective Dimetalation of [Mn(η5-C5H5)(η6-C6H6)]: Crystal Structure and Conversion to Strained [n]Metalloarenophanes
164.
Photocontrolled living polymerizations
Tanabe M., Vandermeulen G.W., Chan W.Y., Cyr P.W., Vanderark L., Rider D.A., Manners I.
Nature Materials , 2006
165.
Nucleophilically Assisted and Cationic Ring-Opening Polymerization of Tin-Bridged [1]Ferrocenophanes
Baumgartner T., Jäkle F., Rulkens R., Zech G., Lough A.J., Manners I.
Journal of the American Chemical Society , 2002
166.
166
1917
167.
167
Friedl.
169.
169
Friedl.
170.
Metal-catalyzed routes to rings, chains and macromolecules based on inorganic elements
Jaska C.A., Bartole-Scott A., Manners I.
Dalton Transactions , 2003
171.
171
Friedl.
172.
Stimulus-Responsive Self-Assembly: Reversible, Redox-Controlled Micellization of Polyferrocenylsilane Diblock Copolymers
Eloi J., Rider D.A., Cambridge G., Whittell G.R., Winnik M.A., Manners I.
Journal of the American Chemical Society , 2011
173.
Relatively stable silaethylenes. Photolysis of acylpolysilanes
Brook A.G., Harris J.W., Lennon J., El Sheikh M.
Journal of the American Chemical Society , 1979
175.
Thermal Transformation of a 1,2-Disilacyclobutane to a Trisilacyclobutane
Bravo-Zhivotovskii D., Melamed S., Kapon M., Apeloig Y.
Organometallics , 2002
176.
176
G. V. Samsonov
"Metody Ispytaniya na Mikrotverdost' i Pribory" (Methods of Microhardness Testing and Apparatus) , 1965
177.
177
J. Henry
Proc. R. Irish Acad. , 1945
178.
178
1946
179.
179
Chem. Abs. , 1947
180.
Spontaneous Ring-Opening Copolymerization of 1,1,2,2-Tetramethyl-1,2-Disilacyclobutane with Styrene
Gusel'nikov L.E., Volkova V.V., Volnina E.A., Gladkova N.K., Negrebetsky V.V., Blazso M.
Journal of Inorganic and Organometallic Polymers , 1998
181.
Synthesis of 1-ethyl-l,2,2-trimethyl-l,2-disilacyclobutane and its spontaneous polymerization and copolymerization with 1,1,2,2 -tetramethyl-1,2 -disilacyclobutane
Gusel’nikov L.E., Buravtseva E.N., Ushakov N.V., Lakhtin V.G., Parshkova L.A., Kuyantseva N.A., Chernyshev E.A.
Russian Chemical Bulletin , 2010
182.
182
1947
183.
Thermal and Photochemical [2+2] Cycloreversion of a 1,2-Disilacyclobutane and a 1,2-Digermacyclobutane
Apeloig Y., Bravo-Zhivotovskii D., Zharov I., Panov V., Leigh W.J., Sluggett G.W.
Journal of the American Chemical Society , 1998
184.
Anionic ring-opening polymerization of 1,1,2,2-tetramethyl-1,2-disilacyclopentane
Suzuki M., Obayashi T., Saegusa T.
Journal of the Chemical Society Chemical Communications , 1993
185.
Anionic Ring-Opening Polymerization of 1,2,2-Trimethyl-1-phenyl-1,2-disilacyclopentane
Suzuki M., Kaneko T., Morishima Y., Obayashi T., Saegusa T.
Polymer Journal , 1996
191.
Chemistry of organosilicon compounds
Sakurai H., Kobayashi T., Nakadaira Y.
Journal of Organometallic Chemistry , 1978
192.
Palladium-Catalyzed Disilane Metathesis Reactions of 1,2-Disilacyclobutanes
Kusukawa T., Kabe Y., Nestler B., Ando W.
Organometallics , 1995
193.
Mechanistic Study on the Platinum-Catalyzed Reaction between Disilacyclobutene and Acetylene
Kang S., Yamabe T., Naka A., Ishikawa M., Yoshizawa K.
Organometallics , 2001
194.
High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene
Sen S.S., Roesky H.W., Stern D., Henn J., Stalke D.
Journal of the American Chemical Society , 2009
196.
Palladium- and platinum-catalyzed reactions of benzo[1,2:4,5]bis(1,1,2,2-tetraethyl-1,2-disilacyclobut-3-ene) with alkenes
Naka A., Koo Lee K., Yoshizawa K., Yamabe T., Ishikawa M.
Journal of Organometallic Chemistry , 1999
197.
Synthesis and Stereochemistry of cis- and trans-3,4- Benzo-1,2-di(tert-butyl)-1,2-dimethyl-1,2-disilacyclobutene
Ishikawa M., Ikadai J., Naka A., Ohshita J., Kunai A., Yoshizawa K., Kang S., Yamabe T.
Organometallics , 2001
203.
Polymeric organosilicon systems. 12. Synthesis and anionic ring-opening polymerization of 1,2,5,6-tetrasilacycloocta-3,7-diynes
Ishikawa M., Hatano T., Hasegawa Y., Horio T., Kunai A., Miyai A., Ishida T., Tsukihara T., Yamanaka T.
Organometallics , 1992
205.
Polymeric organosilicon systems. XIII, Thermal polymerization of 1,2,5,6-tetrasilacycloocta-3,7-diynes
Ishikawa M., Hatano T., Horio T., Kunai A.
Journal of Organometallic Chemistry , 1991
209.
209
C. J. Haggerty
Trans. Am. Electrochem. Soc. , 1929
210.
210
H. L. Wheeler
Chem. Zentr. , 1908
211.
211
C. Schall
Z. Elektrochem. , 1923