Home / Articles / Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations

Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations

Aleksandr Viktorovich Vasilyev 1, 2
Aleksandr Viktorovich Vasilyev
1 St. Petersburg State Forest Technical University
2 Institute of Chemistry, St. Petersburg State University
10.1070/RC2013v082n03ABEH004345
Published 30 November 2012
Communication , Volume 82, Issue 3, 187-204
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Vasilyev A. V. Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 187-204.
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Vasilyev A. V. Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations // Russian Chemical Reviews. 2013. Vol. 82. No. 3. pp. 187-204.
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TY - JOUR
DO - 10.1070/RC2013v082n03ABEH004345
UR - https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004345
TI - Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations
T2 - Russian Chemical Reviews
AU - Vasilyev, Aleksandr Viktorovich
PY - 2013
DA - 2012/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 187-204
IS - 3
VL - 82
ER -
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@article{2013_Vasilyev,
author = {Aleksandr Viktorovich Vasilyev},
title = {Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations},
journal = {Russian Chemical Reviews},
year = {2013},
volume = {82},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004345},
number = {3},
pages = {187--204},
doi = {10.1070/RC2013v082n03ABEH004345}
}
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Vasilyev, Aleksandr Viktorovich. “Electrophilic activation of acetylene compounds in Brønsted superacids. Reactions of vinylic cations.” Russian Chemical Reviews, vol. 82, no. 3, Nov. 2013, pp. 187-204. https://rcr.colab.ws/publications/10.1070/RC2013v082n03ABEH004345.
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Abstract

The review generalizes the published data on the reactions of vinylic cations generated upon alkyne protonation at the triple bond in proton-donor Br${\oslash}$nsted superacids and Børonsted–Lewis conjugated systems: HSO3F5, CF3SO3H–SbF5, HF–SbF5, HBr–AlBr3 and so on. Characteristics of vinylic cations obtained by physicochemical methods (NMR spectroscopy, X-ray diffraction, IR spectroscopy) are presented. Bibliography — 88 references.

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