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Strain-induced softening of glassy and crystalline polymers

Aleksandr L'vovich Volynsky 1
Aleksandr L'vovich Volynsky
, 
Alena Yur'evna Yarysheva 1
Alena Yur'evna Yarysheva
, 
Ekaterina Gennad'evna Rukhlya 1
Ekaterina Gennad'evna Rukhlya
, 
Alexandr Valeryevich Efimov 1
Alexandr Valeryevich Efimov
, 
Larisa Mikhailovna Yarysheva 1
Larisa Mikhailovna Yarysheva
, 
Nikolay Filippovich Bakeev 1
Nikolay Filippovich Bakeev
1 Lomonosov Moscow State University, Faculty of Chemistry
10.1070/RC2013v082n10ABEH004333
Published 30 November 2012
Communication , Volume 82, Issue 10, 988-1006
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Volynsky A. L. et al. Strain-induced softening of glassy and crystalline polymers // Russian Chemical Reviews. 2013. Vol. 82. No. 10. pp. 988-1006.
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Volynsky A. L., Yarysheva A. Y., Rukhlya E. G., Efimov A. V., Yarysheva L. M., Bakeev N. F. Strain-induced softening of glassy and crystalline polymers // Russian Chemical Reviews. 2013. Vol. 82. No. 10. pp. 988-1006.
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TY - JOUR
DO - 10.1070/RC2013v082n10ABEH004333
UR - https://rcr.colab.ws/publications/10.1070/RC2013v082n10ABEH004333
TI - Strain-induced softening of glassy and crystalline polymers
T2 - Russian Chemical Reviews
AU - Volynsky, Aleksandr L'vovich
AU - Yarysheva, Alena Yur'evna
AU - Rukhlya, Ekaterina Gennad'evna
AU - Efimov, Alexandr Valeryevich
AU - Yarysheva, Larisa Mikhailovna
AU - Bakeev, Nikolay Filippovich
PY - 2013
DA - 2012/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 988-1006
IS - 10
VL - 82
ER -
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@article{2013_Volynsky,
author = {Aleksandr L'vovich Volynsky and Alena Yur'evna Yarysheva and Ekaterina Gennad'evna Rukhlya and Alexandr Valeryevich Efimov and Larisa Mikhailovna Yarysheva and Nikolay Filippovich Bakeev},
title = {Strain-induced softening of glassy and crystalline polymers},
journal = {Russian Chemical Reviews},
year = {2013},
volume = {82},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2013v082n10ABEH004333},
number = {10},
pages = {988--1006},
doi = {10.1070/RC2013v082n10ABEH004333}
}
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Volynsky, Aleksandr L'vovich, et al. “Strain-induced softening of glassy and crystalline polymers.” Russian Chemical Reviews, vol. 82, no. 10, Nov. 2013, pp. 988-1006. https://rcr.colab.ws/publications/10.1070/RC2013v082n10ABEH004333.
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Abstract

The data on strain-induced softening of glassy and crystalline polymers accompanying by development of capability of the deformed samples to high reversible strains are analysed. It is shown that in the first deformation cycle, the test sample demonstrates properties typical of glassy or crystalline state, whereas at the repeated stretching, it undergoes transformation into a rubber-like high-elasticity state, in which the polymer is capable of high reversible strains. It is noted that this transition represents a physical basis of strain-induced softening of glassy and crystalline polymers.

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