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Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions

Oleg Dmitrievich Linnikov 1
Oleg Dmitrievich Linnikov
1 Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences
10.1070/RC2014v083n04ABEH004399
Published 30 November 2013
Communication , Volume 83, Issue 4, 343-364
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Linnikov O. D. Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions // Russian Chemical Reviews. 2014. Vol. 83. No. 4. pp. 343-364.
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Linnikov O. D. Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions // Russian Chemical Reviews. 2014. Vol. 83. No. 4. pp. 343-364.
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TY - JOUR
DO - 10.1070/RC2014v083n04ABEH004399
UR - https://rcr.colab.ws/publications/10.1070/RC2014v083n04ABEH004399
TI - Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions
T2 - Russian Chemical Reviews
AU - Linnikov, Oleg Dmitrievich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 343-364
IS - 4
VL - 83
ER -
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@article{2014_Linnikov,
author = {Oleg Dmitrievich Linnikov},
title = {Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v083n04ABEH004399},
number = {4},
pages = {343--364},
doi = {10.1070/RC2014v083n04ABEH004399}
}
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Linnikov, Oleg Dmitrievich. “Mechanism of precipitate formation during spontaneous crystallization from supersaturated aqueous solutions.” Russian Chemical Reviews, vol. 83, no. 4, Nov. 2014, pp. 343-364. https://rcr.colab.ws/publications/10.1070/RC2014v083n04ABEH004399.
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Abstract

The models of formation of salt precipitates during crystallization from supersaturated aqueous solutions are analyzed. The results of theoretical simulations and experimental studies are compared. The attention is focused on the processes of crystal aggregation and agglomeration. The data on the mechanism of crystal intergrowth under conditions of mass crystallization of salts from supersaturated aqueous solutions are considered. The intergrowth process is shown to be described most reliably by the model based on the Polak theory according to which in supersaturated solutions, connecting nucleus-bridges are formed within aggregates between the closest faces of neighbouring crystals.

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