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Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers

Alexander Alexandrovich Kurganov 1
Alexander Alexandrovich Kurganov
, 
Anastasiya Yur'evna Kanatyeva 1
Anastasiya Yur'evna Kanatyeva
, 
Vladimir Alexeevich Orekhov 1
Vladimir Alexeevich Orekhov
1 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
10.1070/RC2014v083n07ABEH004433
Published 30 November 2013
Communication , Volume 83, Issue 7, 638-656
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Kurganov A. A., Kanatyeva A. Y., Orekhov V. A. Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers // Russian Chemical Reviews. 2014. Vol. 83. No. 7. pp. 638-656.
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Kurganov A. A., Kanatyeva A. Y., Orekhov V. A. Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers // Russian Chemical Reviews. 2014. Vol. 83. No. 7. pp. 638-656.
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TY - JOUR
DO - 10.1070/RC2014v083n07ABEH004433
UR - https://rcr.colab.ws/publications/10.1070/RC2014v083n07ABEH004433
TI - Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers
T2 - Russian Chemical Reviews
AU - Kurganov, Alexander Alexandrovich
AU - Kanatyeva, Anastasiya Yur'evna
AU - Orekhov, Vladimir Alexeevich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 638-656
IS - 7
VL - 83
ER -
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@article{2014_Kurganov,
author = {Alexander Alexandrovich Kurganov and Anastasiya Yur'evna Kanatyeva and Vladimir Alexeevich Orekhov},
title = {Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v083n07ABEH004433},
number = {7},
pages = {638--656},
doi = {10.1070/RC2014v083n07ABEH004433}
}
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Kurganov, Alexander Alexandrovich, et al. “Conformational transitions of macromolecules in an eluent flow and their manifestation in the chromatography of polymers.” Russian Chemical Reviews, vol. 83, no. 7, Nov. 2014, pp. 638-656. https://rcr.colab.ws/publications/10.1070/RC2014v083n07ABEH004433.
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Abstract

The behaviour of macromolecules in a free eluent flow, in a confined space and in a flow passing through a pore system is considered. It is shown that the behaviour of molecules in a flow can be described by various theories (De Gennes, DiMarzio and Guttman theories). Specific features of chromatographic fractionation and membrane separation of ultrahigh molecular mass polymers, which are widely used as constructional materials, are discussed. These features are interpreted in terms of theoretical models that consider conformational transitions of macromolecules in the eluent flow and take into account the possible degradation of macromolecules under the action of the flow. The state of the art of theoretical and experimental studies of the behaviour of macromolecules in a fluid flow is surveyed.

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