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Synthesis, properties and transformations of fullerene peroxides

Ramil Garifovich Bulgakov 1
Ramil Garifovich Bulgakov
, 
Dim Irshatovich Galimov 1
Dim Irshatovich Galimov
, 
1 Institute of Petrochemistry and Catalysis of RAS
10.1070/RC2014v083n08ABEH004401
Published 30 November 2013
Communication , Volume 83, Issue 8, 677-717
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Bulgakov R. G., Galimov D. I., Dzhemilev U. M. Synthesis, properties and transformations of fullerene peroxides // Russian Chemical Reviews. 2014. Vol. 83. No. 8. pp. 677-717.
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Bulgakov R. G., Galimov D. I., Dzhemilev U. M. Synthesis, properties and transformations of fullerene peroxides // Russian Chemical Reviews. 2014. Vol. 83. No. 8. pp. 677-717.
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TY - JOUR
DO - 10.1070/RC2014v083n08ABEH004401
UR - https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004401
TI - Synthesis, properties and transformations of fullerene peroxides
T2 - Russian Chemical Reviews
AU - Bulgakov, Ramil Garifovich
AU - Galimov, Dim Irshatovich
AU - Dzhemilev, Usein Memetovich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 677-717
IS - 8
VL - 83
ER -
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@article{2014_Bulgakov,
author = {Ramil Garifovich Bulgakov and Dim Irshatovich Galimov and Usein Memetovich Dzhemilev},
title = {Synthesis, properties and transformations of fullerene peroxides},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004401},
number = {8},
pages = {677--717},
doi = {10.1070/RC2014v083n08ABEH004401}
}
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Bulgakov, Ramil Garifovich, et al. “Synthesis, properties and transformations of fullerene peroxides.” Russian Chemical Reviews, vol. 83, no. 8, Nov. 2014, pp. 677-717. https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004401.
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Abstract

The formation routes, properties and transformations of fullerene peroxides are considered and described systematically for the first time. It is demonstrated that the chemistry of fullerene peroxides is a new line of research in the field of fullerene functionalization being vigorously developed since 2002. The preparation methods, mechanisms of formation and reactions of C$_{60}$ and C$_{70}$ alkyl peroxides both containing and not containing epoxide groups are discussed. The transformations of fullerene peroxides are presented, resulting in a broad range of fullerene derivatives containing halogen or sulfur atoms, epoxide, dioxolane, thiirane, crown ether, aziridine and dioxetane rings, and hydroxyl, alkoxyl and carbonyl groups. Primary attention is devoted to reactions that form the basis of a new approach, so-called 'molecular surgery', which allows the preparation of open-cage fullerenes. These compounds were shown to be promising for the design of photovoltaic cells, drug carriers and radionuclide carriers (for radiopharmaceuticals).

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