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Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components

Ol'ga Georgievna Ellert 1
Ol'ga Georgievna Ellert
, 
Mark Veniaminivich Tsodikov 2
Mark Veniaminivich Tsodikov
,  , 
Vladimir Mikhailovich Novotortsev 1
Vladimir Mikhailovich Novotortsev
1 Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow
2 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
3 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RC2014v083n08ABEH004432
Published 30 November 2013
Communication , Volume 83, Issue 8, 718-732
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Ellert O. G. et al. Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components // Russian Chemical Reviews. 2014. Vol. 83. No. 8. pp. 718-732.
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Ellert O. G., Tsodikov M. V., Nikolaev S. A., Novotortsev V. M. Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components // Russian Chemical Reviews. 2014. Vol. 83. No. 8. pp. 718-732.
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TY - JOUR
DO - 10.1070/RC2014v083n08ABEH004432
UR - https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004432
TI - Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components
T2 - Russian Chemical Reviews
AU - Ellert, Ol'ga Georgievna
AU - Tsodikov, Mark Veniaminivich
AU - Nikolaev, Sergey Alexandrovich
AU - Novotortsev, Vladimir Mikhailovich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 718-732
IS - 8
VL - 83
ER -
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@article{2014_Ellert,
author = {Ol'ga Georgievna Ellert and Mark Veniaminivich Tsodikov and Sergey Alexandrovich Nikolaev and Vladimir Mikhailovich Novotortsev},
title = {Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004432},
number = {8},
pages = {718--732},
doi = {10.1070/RC2014v083n08ABEH004432}
}
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Ellert, Ol'ga Georgievna, et al. “Bimetallic nanoalloys in heterogeneous catalysis of industrially important reactions: synergetic effects and structural organization of the active components.” Russian Chemical Reviews, vol. 83, no. 8, Nov. 2014, pp. 718-732. https://rcr.colab.ws/publications/10.1070/RC2014v083n08ABEH004432.
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Abstract

The review is concerned with correlations between synergetic effects and structural organization of the surface of bimetallic alloys that are used as active components of catalysts for selective hydrogenation of organic compounds and the oxidation of CO in hydrogen-rich mixtures. Studies on the preparation of novel highly efficient catalysts using modern theoretical approaches, computer-assisted molecular design and original synthetic procedures are considered. It is shown that introduction of a second metal into the monometallic catalyst and subsequent formation of an alloy with the modified structure of the surface and near-surface layers leads to nonadditive enhancement of catalytic activity and/or selectivity.

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