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Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes

Aleksei Aleksandrovich Nikolin 1
Aleksei Aleksandrovich Nikolin
, 
Vadim Vital'evich Negrebetsky 1
Vadim Vital'evich Negrebetsky
1 Russian National Research Medical University named after N. I. Pirogov
Published 30 November 2013
Communication , Volume 83, Issue 9, 848-883
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Nikolin A. A., Negrebetsky V. V. Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes // Russian Chemical Reviews. 2014. Vol. 83. No. 9. pp. 848-883.
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Nikolin A. A., Negrebetsky V. V. Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes // Russian Chemical Reviews. 2014. Vol. 83. No. 9. pp. 848-883.
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TY - JOUR
DO - 10.1070/RC2014v083n09ABEH004385
UR - https://rcr.colab.ws/publications/10.1070/RC2014v083n09ABEH004385
TI - Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes
T2 - Russian Chemical Reviews
AU - Nikolin, Aleksei Aleksandrovich
AU - Negrebetsky, Vadim Vital'evich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 848-883
IS - 9
VL - 83
ER -
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@article{2014_Nikolin,
author = {Aleksei Aleksandrovich Nikolin and Vadim Vital'evich Negrebetsky},
title = {Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v083n09ABEH004385},
number = {9},
pages = {848--883},
doi = {10.1070/RC2014v083n09ABEH004385}
}
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Nikolin, Aleksei Aleksandrovich, and Vadim Vital'evich Negrebetsky. “Synthesis, properties and reactivity of intramolecular hypercoordinate silicon complexes.” Russian Chemical Reviews, vol. 83, no. 9, Nov. 2014, pp. 848-883. https://rcr.colab.ws/publications/10.1070/RC2014v083n09ABEH004385.
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Abstract

The state of the art of the chemistry of hypercoordinate silicon compounds is analyzed. Published data on the current top-priority approaches to the preparative synthesis of these compounds and on their properties, structures and reactivity are summarized and generalized. Relying on the results obtained by modern physicochemical methods, the possible mechanisms of stereodynamic processes occurring in the coordination units of hypercoordinate silicon complexes are discussed.

The bibliography includes 157 references.

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