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Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision

Valentin Pavlovich Ananikov 1, 2
Valentin Pavlovich Ananikov
, 
Levon L'vovich Khemchyan 1
Levon L'vovich Khemchyan
, 
Yuliya Vladimirovna Ivanova 1
Yuliya Vladimirovna Ivanova
, 
Valerii Ivanovich Bukhtiyarov 3, 4
Valerii Ivanovich Bukhtiyarov
, 
Aleksei Mikhailovich Sorokin 3
Aleksei Mikhailovich Sorokin
,  ,  , 
Aleksei Viktorovich Medved'ko 5
Aleksei Viktorovich Medved'ko
, 
Vyacheslav Nazimovich Nuriev 5
Vyacheslav Nazimovich Nuriev
,  , 
Vitalij Vladimirovich Levin 1
Vitalij Vladimirovich Levin
, 
Igor Valentinovich Koptyug 4, 6
Igor Valentinovich Koptyug
, 
Kirill Victorovich Kovtunov 4, 6
Kirill Victorovich Kovtunov
, 
Vladimir Valer'evich Zhivonitko 4, 6
Vladimir Valer'evich Zhivonitko
, 
Vladimir Alexandrovich Likholobov 7
Vladimir Alexandrovich Likholobov
, 
Anatoly Vladimirovich Romanenko 3
Anatoly Vladimirovich Romanenko
, 
Pavel Anatol'evich Simonov 3, 4
Pavel Anatol'evich Simonov
, 
Valentin Georgievich Nenajdenko 5, 8
Valentin Georgievich Nenajdenko
, 
Ol'ga Igorevna Shmatova 5
Ol'ga Igorevna Shmatova
, 
Vasilii Mikhailovich Muzalevskiy 5
Vasilii Mikhailovich Muzalevskiy
,  ,  , 
Oleg Sergeyevich Morozov 9
Oleg Sergeyevich Morozov
, 
Pavel Borisovich Dzhevakov 9
Pavel Borisovich Dzhevakov
, 
Sergey Nikolaevich Osipov 8
Sergey Nikolaevich Osipov
,  , 
Maksim Anatol'evich Topchiy 8
Maksim Anatol'evich Topchiy
, 
M A Zotova 8
M A Zotova
, 
Sergey Anatol'evich Ponomarenko 5, 10
Sergey Anatol'evich Ponomarenko
, 
Oleg Valentinovich Borshchev 10
Oleg Valentinovich Borshchev
, 
Yurii Nikolaevich Luponosov 10
Yurii Nikolaevich Luponosov
, 
Andrey Andreevich Rempel 11, 12
Andrey Andreevich Rempel
, 
Al'bina Ahmetovna Valeeva 11, 12
Al'bina Ahmetovna Valeeva
,  , 
Olga Vasil'evna Turova 1
Olga Vasil'evna Turova
,  , 
Sergey Viktorovich Sysolyatin 13
Sergey Viktorovich Sysolyatin
, 
Valerii Viktorovich Malykhin 13
Valerii Viktorovich Malykhin
, 
Galina Aleksandrovna Bukhtiyarova 3
Galina Aleksandrovna Bukhtiyarova
,  , 
Igor' Borisovich Krylov 1
Igor' Borisovich Krylov
1 N.D. Zelinskii Institute of Organic Chemistry
2 Saint Petersburg State University
3 Boreskov Institute of Catalysis SB RAS, Novosibirsk
4 Novosibirsk State University
5 M. V. Lomonosov Moscow State University, Department of Chemistry
6 International Tomography Center of the Siberian Branch of the Russian Academy of Sciences, Novosibirsk
7 Institute of Hydrocarbons Processing of SB RAS
8 A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow
9 A. V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow
10 N. S. Enikolopov Institute of Synthetic Polymer Materials RAS, Moscow
11 Institute of Solid State Chemistry, Urals Branch of the Russian Academy of Sciences, Ekaterinburg
12 Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
13 Institute for Problems of Chemical and Energetic Technology, Siberian Branch of the Russian Academy of Sciences, Biisk, Altai krai
10.1070/RC2014v83n10ABEH004471
Published 30 November 2013
Communication , Volume 83, Issue 10, 885-985
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Ananikov V. P. et al. Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision // Russian Chemical Reviews. 2014. Vol. 83. No. 10. pp. 885-985.
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Ananikov V. P., Khemchyan L. L., Ivanova Y. V., Bukhtiyarov V. I., Sorokin A. M., Prosvirin I. P., Vatsadze S. Z., Medved'ko A. V., Nuriev V. N., Dilman A. D., Levin V. V., Koptyug I. V., Kovtunov K. V., Zhivonitko V. V., Likholobov V. A., Romanenko A. V., Simonov P. A., Nenajdenko V. G., Shmatova O. I., Muzalevskiy V. M., Nechaev M. S., Asachenko A. F., Morozov O. S., Dzhevakov P. B., Osipov S. N., Vorobyeva D. V., Topchiy M. A., Zotova M. A., Ponomarenko S. A., Borshchev O. V., Luponosov Y. N., Rempel A. A., Valeeva A. A., Stakheev A. Y., Turova O. V., Mashkovsky I. S., Sysolyatin S. V., Malykhin V. V., Bukhtiyarova G. A., Terent'ev A. O., Krylov I. B. Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision // Russian Chemical Reviews. 2014. Vol. 83. No. 10. pp. 885-985.
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TY - JOUR
DO - 10.1070/RC2014v83n10ABEH004471
UR - https://rcr.colab.ws/publications/10.1070/RC2014v83n10ABEH004471
TI - Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision
T2 - Russian Chemical Reviews
AU - Ananikov, Valentin Pavlovich
AU - Khemchyan, Levon L'vovich
AU - Ivanova, Yuliya Vladimirovna
AU - Bukhtiyarov, Valerii Ivanovich
AU - Sorokin, Aleksei Mikhailovich
AU - Prosvirin, Igor' Petrovich
AU - Vatsadze, Sergey Zurabovich
AU - Medved'ko, Aleksei Viktorovich
AU - Nuriev, Vyacheslav Nazimovich
AU - Dilman, Alexander Davidovich
AU - Levin, Vitalij Vladimirovich
AU - Koptyug, Igor Valentinovich
AU - Kovtunov, Kirill Victorovich
AU - Zhivonitko, Vladimir Valer'evich
AU - Likholobov, Vladimir Alexandrovich
AU - Romanenko, Anatoly Vladimirovich
AU - Simonov, Pavel Anatol'evich
AU - Nenajdenko, Valentin Georgievich
AU - Shmatova, Ol'ga Igorevna
AU - Muzalevskiy, Vasilii Mikhailovich
AU - Nechaev, M S
AU - Asachenko, Andrey Fedorovich
AU - Morozov, Oleg Sergeyevich
AU - Dzhevakov, Pavel Borisovich
AU - Osipov, Sergey Nikolaevich
AU - Vorobyeva, Dar'ya Vladimirovna
AU - Topchiy, Maksim Anatol'evich
AU - Zotova, M A
AU - Ponomarenko, Sergey Anatol'evich
AU - Borshchev, Oleg Valentinovich
AU - Luponosov, Yurii Nikolaevich
AU - Rempel, Andrey Andreevich
AU - Valeeva, Al'bina Ahmetovna
AU - Stakheev, Aleksandr Yurevich
AU - Turova, Olga Vasil'evna
AU - Mashkovsky, Igor' Sergeevich
AU - Sysolyatin, Sergey Viktorovich
AU - Malykhin, Valerii Viktorovich
AU - Bukhtiyarova, Galina Aleksandrovna
AU - Terent'ev, Alexander Olegovich
AU - Krylov, Igor' Borisovich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 885-985
IS - 10
VL - 83
ER -
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@article{2014_Ananikov,
author = {Valentin Pavlovich Ananikov and Levon L'vovich Khemchyan and Yuliya Vladimirovna Ivanova and Valerii Ivanovich Bukhtiyarov and Aleksei Mikhailovich Sorokin and Igor' Petrovich Prosvirin and Sergey Zurabovich Vatsadze and Aleksei Viktorovich Medved'ko and Vyacheslav Nazimovich Nuriev and Alexander Davidovich Dilman and Vitalij Vladimirovich Levin and Igor Valentinovich Koptyug and Kirill Victorovich Kovtunov and Vladimir Valer'evich Zhivonitko and Vladimir Alexandrovich Likholobov and Anatoly Vladimirovich Romanenko and Pavel Anatol'evich Simonov and Valentin Georgievich Nenajdenko and Ol'ga Igorevna Shmatova and Vasilii Mikhailovich Muzalevskiy and M S Nechaev and Andrey Fedorovich Asachenko and Oleg Sergeyevich Morozov and Pavel Borisovich Dzhevakov and Sergey Nikolaevich Osipov and Dar'ya Vladimirovna Vorobyeva and Maksim Anatol'evich Topchiy and M A Zotova and Sergey Anatol'evich Ponomarenko and Oleg Valentinovich Borshchev and Yurii Nikolaevich Luponosov and Andrey Andreevich Rempel and Al'bina Ahmetovna Valeeva and Aleksandr Yurevich Stakheev and Olga Vasil'evna Turova and Igor' Sergeevich Mashkovsky and Sergey Viktorovich Sysolyatin and Valerii Viktorovich Malykhin and Galina Aleksandrovna Bukhtiyarova and Alexander Olegovich Terent'ev and Igor' Borisovich Krylov},
title = {Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RC2014v83n10ABEH004471},
number = {10},
pages = {885--985},
doi = {10.1070/RC2014v83n10ABEH004471}
}
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Ananikov, Valentin Pavlovich, et al. “Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision.” Russian Chemical Reviews, vol. 83, no. 10, Nov. 2014, pp. 885-985. https://rcr.colab.ws/publications/10.1070/RC2014v83n10ABEH004471.
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Abstract

The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend --- the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as ``atomic precision'' in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.

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