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Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes

Aleksandr L'vovich Volynsky 1
Aleksandr L'vovich Volynsky
, 
Alena Yur'evna Yarysheva 1
Alena Yur'evna Yarysheva
, 
Ekaterina Gennad'evna Rukhlya 1
Ekaterina Gennad'evna Rukhlya
, 
Larisa Mikhailovna Yarysheva 1
Larisa Mikhailovna Yarysheva
, 
Nikolay Filippovich Bakeev 1
Nikolay Filippovich Bakeev
1 M. V. Lomonosov Moscow State University, Department of Chemistry
10.1070/RCR4428
Published 30 November 2013
Communication , Volume 83, Issue 11, 1003-1026
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Volynsky A. L. et al. Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes // Russian Chemical Reviews. 2014. Vol. 83. No. 11. pp. 1003-1026.
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Volynsky A. L., Yarysheva A. Y., Rukhlya E. G., Yarysheva L. M., Bakeev N. F. Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes // Russian Chemical Reviews. 2014. Vol. 83. No. 11. pp. 1003-1026.
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TY - JOUR
DO - 10.1070/RCR4428
UR - https://rcr.colab.ws/publications/10.1070/RCR4428
TI - Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes
T2 - Russian Chemical Reviews
AU - Volynsky, Aleksandr L'vovich
AU - Yarysheva, Alena Yur'evna
AU - Rukhlya, Ekaterina Gennad'evna
AU - Yarysheva, Larisa Mikhailovna
AU - Bakeev, Nikolay Filippovich
PY - 2014
DA - 2013/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1003-1026
IS - 11
VL - 83
ER -
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@article{2014_Volynsky,
author = {Aleksandr L'vovich Volynsky and Alena Yur'evna Yarysheva and Ekaterina Gennad'evna Rukhlya and Larisa Mikhailovna Yarysheva and Nikolay Filippovich Bakeev},
title = {Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes},
journal = {Russian Chemical Reviews},
year = {2014},
volume = {83},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4428},
number = {11},
pages = {1003--1026},
doi = {10.1070/RCR4428}
}
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Volynsky, Aleksandr L'vovich, et al. “Specific features of structure and properties of solutions, melts and solid states of polymers in confined nanometric volumes.” Russian Chemical Reviews, vol. 83, no. 11, Nov. 2014, pp. 1003-1026. https://rcr.colab.ws/publications/10.1070/RCR4428.
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Abstract

The data on the influence of spatial restrictions on the structure and properties of polymers are analyzed. It is demonstrated that dispersion of polymers into aggregates of nanometre size critically changes all their characteristics in consequence of conformational restructuring of the polymeric chains. The spatial restrictions affect both characteristics of phase transitions in polymers (the crystallization and melting points, heat of melting and the degree of crystallinity decrease) and the processes of orientation of crystallites in asymmetric volumes of nanometre size. It is shown that these effects are primarily related to the changes in relative contribution of the stages of nucleation and growth of crystallite to the overall process occurring in confined volumes. Comparative analysis of the effects of spatial restrictions on the processes of crystallization of polymers and low-molecular-mass compounds is carried out. The similarity in changes in thermodynamic characteristics for both series of compounds is revealed.

The bibliography includes 211 references.

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