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Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes

Igor Sergeevich Kovalev 1
Igor Sergeevich Kovalev
, 
Dmitrii Sergeevich Kopchuk 1, 2
Dmitrii Sergeevich Kopchuk
, 
Grigory Vasil'evich Zyryanov 1, 2
Grigory Vasil'evich Zyryanov
, 
Vladimir Leonidovich Rusinov 1, 2
Vladimir Leonidovich Rusinov
, 
Oleg Nikolaevich Chupakhin 1, 2
Oleg Nikolaevich Chupakhin
, 
Valery Nikolaevich Charushin 1, 2
Valery Nikolaevich Charushin
1 Chemical Technological Institute, Ural Federal University named after the First President of Russia B. N. Yeltsin, Ekaterinburg
2 I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of Russian Academy of Sciences, Ekaterinburg
10.1070/RCR4462
Published 30 November 2014
Communication , Volume 84, Issue 12, 1191-1225
28
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Kovalev I. S. et al. Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes // Russian Chemical Reviews. 2015. Vol. 84. No. 12. pp. 1191-1225.
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Kovalev I. S., Kopchuk D. S., Zyryanov G. V., Rusinov V. L., Chupakhin O. N., Charushin V. N. Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes // Russian Chemical Reviews. 2015. Vol. 84. No. 12. pp. 1191-1225.
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TY - JOUR
DO - 10.1070/RCR4462
UR - https://rcr.colab.ws/publications/10.1070/RCR4462
TI - Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes
T2 - Russian Chemical Reviews
AU - Kovalev, Igor Sergeevich
AU - Kopchuk, Dmitrii Sergeevich
AU - Zyryanov, Grigory Vasil'evich
AU - Rusinov, Vladimir Leonidovich
AU - Chupakhin, Oleg Nikolaevich
AU - Charushin, Valery Nikolaevich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1191-1225
IS - 12
VL - 84
ER -
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@article{2015_Kovalev,
author = {Igor Sergeevich Kovalev and Dmitrii Sergeevich Kopchuk and Grigory Vasil'evich Zyryanov and Vladimir Leonidovich Rusinov and Oleg Nikolaevich Chupakhin and Valery Nikolaevich Charushin},
title = {Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4462},
number = {12},
pages = {1191--1225},
doi = {10.1070/RCR4462}
}
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Kovalev, Igor Sergeevich, et al. “Organolithium compounds in the nucleophilic substitution of hydrogen in arenes and hetarenes.” Russian Chemical Reviews, vol. 84, no. 12, Nov. 2015, pp. 1191-1225. https://rcr.colab.ws/publications/10.1070/RCR4462.
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Abstract

The review considers the most typical examples of the direct non-activated non-catalytic C--C bond formation in arenes and their metal complexes activated by electron-withdrawing substituents in the aromatic nucleus and in hetarenes (azines and their N-oxides, porphyrins, {\it etc}.) upon the reactions with aliphatic and (hetero)aromatic (hetero)organolithium nucleophiles. Particular attention is given to the direct introduction of nitroxide radicals and (hetero)organic moieties into mono-, di- and triazines and their N-oxides. The influence of the structures of the (hetero)aromatic substrate and the (hetero)organolithium nucleophile on the reaction pathway and rate and on the structure of the reaction product is analyzed.

The bibliography includes 237 references.

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