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Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile

Dmitry Fedorovich Grishin 1
Dmitry Fedorovich Grishin
, 
Ivan Dmitrievich Grishin 1
Ivan Dmitrievich Grishin
1 Lobachevski State University of Nizhni Novgorod
10.1070/RCR4476
Published 30 November 2014
Communication , Volume 84, Issue 7, 712-736
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Grishin D. F., Grishin I. D. Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile // Russian Chemical Reviews. 2015. Vol. 84. No. 7. pp. 712-736.
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Grishin D. F., Grishin I. D. Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile // Russian Chemical Reviews. 2015. Vol. 84. No. 7. pp. 712-736.
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TY - JOUR
DO - 10.1070/RCR4476
UR - https://rcr.colab.ws/publications/10.1070/RCR4476
TI - Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile
T2 - Russian Chemical Reviews
AU - Grishin, Dmitry Fedorovich
AU - Grishin, Ivan Dmitrievich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 712-736
IS - 7
VL - 84
ER -
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@article{2015_Grishin,
author = {Dmitry Fedorovich Grishin and Ivan Dmitrievich Grishin},
title = {Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4476},
number = {7},
pages = {712--736},
doi = {10.1070/RCR4476}
}
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Grishin, Dmitry Fedorovich, and Ivan Dmitrievich Grishin. “Radical-initiated controlled synthesis of homo- and copolymers based on acrylonitrile.” Russian Chemical Reviews, vol. 84, no. 7, Nov. 2015, pp. 712-736. https://rcr.colab.ws/publications/10.1070/RCR4476.
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Abstract

Data on the controlled synthesis of polyacrylonitrile and acrylonitrile copolymers with other (meth)acrylic and vinyl monomers upon radical initiation and metal complex catalysis are analyzed. Primary attention is given to the use of metal complexes for the synthesis of acrylonitrile-based (co)polymers with defined molecular weight and polydispersity in living mode by atom transfer radical polymerization. The prospects for using known methods of controlled synthesis of macromolecules for the preparation of acrylonitrile homo- and copolymers as carbon fibre precursors are estimated. The major array of published data analyzed in the review refers to the last decade.

The bibliography includes 175 references.

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