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Crystallographic analysis of a series of inorganic compounds

Stanislav Vasil'evich Borisov 1
Stanislav Vasil'evich Borisov
, 
Svetlana Aleksandrovna Magarill 1
Svetlana Aleksandrovna Magarill
, 
Natal'ya Viktorovna Pervukhina 1
Natal'ya Viktorovna Pervukhina
1 Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk
10.1070/RCR4479
Published 30 November 2014
Communication , Volume 84, Issue 4, 393-421
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Borisov S. V., Magarill S. A., Pervukhina N. V. Crystallographic analysis of a series of inorganic compounds // Russian Chemical Reviews. 2015. Vol. 84. No. 4. pp. 393-421.
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Borisov S. V., Magarill S. A., Pervukhina N. V. Crystallographic analysis of a series of inorganic compounds // Russian Chemical Reviews. 2015. Vol. 84. No. 4. pp. 393-421.
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TY - JOUR
DO - 10.1070/RCR4479
UR - https://rcr.colab.ws/publications/10.1070/RCR4479
TI - Crystallographic analysis of a series of inorganic compounds
T2 - Russian Chemical Reviews
AU - Borisov, Stanislav Vasil'evich
AU - Magarill, Svetlana Aleksandrovna
AU - Pervukhina, Natal'ya Viktorovna
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 393-421
IS - 4
VL - 84
ER -
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@article{2015_Borisov,
author = {Stanislav Vasil'evich Borisov and Svetlana Aleksandrovna Magarill and Natal'ya Viktorovna Pervukhina},
title = {Crystallographic analysis of a series of inorganic compounds},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4479},
number = {4},
pages = {393--421},
doi = {10.1070/RCR4479}
}
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Borisov, Stanislav Vasil'evich, et al. “Crystallographic analysis of a series of inorganic compounds.” Russian Chemical Reviews, vol. 84, no. 4, Nov. 2015, pp. 393-421. https://rcr.colab.ws/publications/10.1070/RCR4479.
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Abstract

The method of crystallographic analysis relies on the mechanical-wave concept that treats the crystalline state as the result of ordering of atomic positions by families of parallel equidistant planes. Using this method, a large set of fluoride, oxide and sulfide structures was analyzed. The pseudo-translational ordering of various atomic groups (including the presence of cation and anion sublattices) in the structures of various classes of inorganic compounds was established. The crucial role of local ordering of heavy cations (coherent assembly) in the structures comprising large cluster fragments (Keggin polyanions, polyoxoniobates, {\it etc}.) is discussed. The role of symmetry and the regular distribution of heavy atoms in the formation of stable crystal structures, which is to be taken into account in the targeted design, is considered. The universality of configurations of atomic positions in the structures of various classes of inorganic compounds resulting from the ordering mechanism organized by mechanical (elastic) forces is demonstrated.

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