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Ligand-protected gold clusters: the structure, synthesis and applications

Dar'ya Aleksandrovna Pichugina 1
Dar'ya Aleksandrovna Pichugina
, 
Nikolai Egorovich Kuz'menko 1
Nikolai Egorovich Kuz'menko
, 
Alexander Fedorovich Shestakov 2
Alexander Fedorovich Shestakov
1 Lomonosov Moscow State University, Faculty of Chemistry
2 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
10.1070/RCR4493
Published 30 November 2014
Communication , Volume 84, Issue 11, 1114-1144
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Pichugina D. A., Kuz'menko N. E., Shestakov A. F. Ligand-protected gold clusters: the structure, synthesis and applications // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1114-1144.
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Pichugina D. A., Kuz'menko N. E., Shestakov A. F. Ligand-protected gold clusters: the structure, synthesis and applications // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1114-1144.
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TY - JOUR
DO - 10.1070/RCR4493
UR - https://rcr.colab.ws/publications/10.1070/RCR4493
TI - Ligand-protected gold clusters: the structure, synthesis and applications
T2 - Russian Chemical Reviews
AU - Pichugina, Dar'ya Aleksandrovna
AU - Kuz'menko, Nikolai Egorovich
AU - Shestakov, Alexander Fedorovich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1114-1144
IS - 11
VL - 84
ER -
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@article{2015_Pichugina,
author = {Dar'ya Aleksandrovna Pichugina and Nikolai Egorovich Kuz'menko and Alexander Fedorovich Shestakov},
title = {Ligand-protected gold clusters: the structure, synthesis and applications},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4493},
number = {11},
pages = {1114--1144},
doi = {10.1070/RCR4493}
}
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Pichugina, Dar'ya Aleksandrovna, et al. “Ligand-protected gold clusters: the structure, synthesis and applications.” Russian Chemical Reviews, vol. 84, no. 11, Nov. 2015, pp. 1114-1144. https://rcr.colab.ws/publications/10.1070/RCR4493.
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Abstract

Modern concepts of the structure and properties of atomic gold clusters protected by thiolate, selenolate, phosphine and phenylacetylene ligands are analyzed. Within the framework of the superatom theory, the 'divide and protect' approach and the structure rule, the stability and composition of a~cluster are determined by the structure of the cluster core, the type of ligands and the total number of valence electrons. Methods of selective synthesis of gold clusters in solution and on the surface of inorganic composites based, in particular, on the reaction of $\mathrm{Au}_n$ with $\mathrm{RS}$, $\mathrm{RSe}$, $\mathrm{PhC\equiv C}$, $\mathrm{Hal}$ ligands or functional groups of proteins, on stabilization of clusters in cavities of the $\alpha$-, $\beta$ and $\gamma$-cyclodextrin molecules ($\mathrm{Au}_{15}$ and $\mathrm{Au}_{25}$) and on anchorage to a~support surface ($\mathrm{Au_{25}/SiO}_2$, $\mathrm{Au_{20}/C}$, $\mathrm{Au_{10}/FeO}_x$) are reviewed. Problems in this field are also discussed. Among the methods for cluster structure prediction, particular attention is given to the theoretical approaches based on the density functional theory (DFT). The structures of a~number of synthesized clusters are described using the results obtained by X-ray diffraction analysis and DFT calculations. A~possible mechanism of formation of the $\mathrm{SR(AuSR})_n$ 'staple' units in the cluster shell is proposed. The structure and properties of bimetallic clusters $\mathrm M_x\mathrm{Au}_n\mathrm L_m$ ($\mathrm{M=Pd}$, $\mathrm{Pt}$, $\mathrm{Ag}$, $\mathrm{Cu}$) are discussed. The $\mathrm{Pd}$ or~$\mathrm{Pt}$ atom is located at the centre of the cluster, whereas $\mathrm{Ag}$ and $\mathrm{Cu}$ atoms form bimetallic compounds in which the heteroatom is located on the surface of the cluster core or in the 'staple' units. The optical properties, fluorescence and luminescence of ligand-protected gold clusters originate from the quantum effects of the $\mathrm{Au}$ atoms in the cluster core and in the oligomeric $\mathrm{SR(AuSR})_x$ units in the cluster shell. Homogeneous and heterogeneous reactions catalyzed by atomic gold clusters are discussed in the context of the reaction mechanism and the nature of the active sites.

The bibliography includes 345 references.

References

1.
1
A. A. Krasnovskii
Dokl. Akad. Nauk SSSR , 1948
2.
2
A. A. Krasnovskii
Zhur. Fiz. Khim. , 1956
3.
3
M. F. Shostakovskii
"Prostye Vinilovye Efiry" (Vinyl Ethers) , 1952
4.
Nikolaev Konstantin Gennadievich, Ermakov Sergey Sergeevich, Offenhäusser Andreas, Mourzina Yulia
Mendeleev Communications , 2014
5.
Ziangirova Maiya Yur'evna, Kotelev Mikhail Sergeevich, Skorikova Galina Sergeevna, Ivanov Evgenii Vladimirovich, Perel'man Lev Teodorovich, Vinokurov Vladimir Arnol'dovich
Mendeleev Communications , 2013
11.
Quantum Sized Gold Nanoclusters with Atomic Precision
Qian H., Zhu M., Wu Z., Jin R.
Accounts of Chemical Research , 2012
13.
Synthesis and X-ray crystal structure determination of the cationic gold cluster compound [Au8(PPh3)7](NO3)2
van der Velden J.W., Bour J.J., Bosman W.P., Noordik J.H.
Journal of the Chemical Society Chemical Communications , 1981
14.
Novel gold clusters. Preparation, properties, and X-ray structure determination of salts of octakis(triarylphosphine)enneagold, [Au9L8]X3
Bellon P.L., Cariati F., Manassero M., Naldini L., Sansoni M.
Journal of the Chemical Society D Chemical Communications , 1971
15.
Structural characterisation of [Au10Cl3(PCy2Ph)6](NO3)(Cy = cyclohexyl) and the development of a structural principle for high nuclearity gold clusters
Briant C.E., Hall K.P., Wheeler A.C., Mingos D.M.
Journal of the Chemical Society Chemical Communications , 1984
16.
Novel cluster complexes of gold(0)–gold(I)
McPartlin M., Mason R., Malatesta L.
Journal of the Chemical Society D Chemical Communications , 1969
18.
Molecular-orbital calculations on cluster compounds of gold
Mingos D.M.
Journal of the Chemical Society Dalton Transactions , 1976
21.
The relevance of shape and size of Au55 clusters
Schmid G.
Chemical Society Reviews , 2008
22.
Ligand-Induced Stability of Gold Nanoclusters: Thiolate versus Selenolate.
Kurashige W., Yamaguchi M., Nobusada K., Negishi Y.
Journal of Physical Chemistry Letters , 2012
23.
Alkyl selenide- and alkyl thiolate-functionalized gold nanoparticles: Chain packing and bond nature
Yee C.K., Ulman A., Ruiz J.D., Parikh A., White H., Rafailovich M.
Langmuir , 2003
25.
Selenolate-Protected Au38 Nanoclusters: Isolation and Structural Characterization
Kurashige W., Yamazoe S., Kanehira K., Tsukuda T., Negishi Y.
Journal of Physical Chemistry Letters , 2013
26.
Organogold Clusters Protected by Phenylacetylene
Maity P., Tsunoyama H., Yamauchi M., Xie S., Tsukuda T.
Journal of the American Chemical Society , 2011
27.
Selective synthesis of organogold magic clusters Au54(CCPh)26
Maity P., Wakabayashi T., Ichikuni N., Tsunoyama H., Xie S., Yamauchi M., Tsukuda T.
Chemical Communications , 2012
28.
The gold–sulfur interface at the nanoscale
Häkkinen H.
Nature Chemistry , 2012
29.
Theoretical Prediction of S–H Bond Rupture in Methanethiol upon Interaction with Gold
Askerka M., Pichugina D., Kuz’menko N., Shestakov A.
Journal of Physical Chemistry A , 2012
30.
The structures of small gold cluster anions as determined by a combination of ion mobility measurements and density functional calculations
Furche F., Ahlrichs R., Weis P., Jacob C., Gilb S., Bierweiler T., Kappes M.M.
Journal of Chemical Physics , 2002
32.
Gas-Phase Ion Chemistry of Small Gold Cluster Anions
Höckendorf R.F., Cao Y., Beyer M.K.
Organometallics , 2010
33.
Identification of Active Gold Nanoclusters on Iron Oxide Supports for CO Oxidation
Herzing A.A., Kiely C.J., Carley A.F., Landon P., Hutchings G.J.
Science , 2008
35.
Au25@SiO2: Quantum Clusters of Gold Embedded in Silica
Habeeb Muhammed M.A., Pradeep T.
Small , 2010
36.
Quick XAFS Studies on the Y-Type Zeolite Supported Au Catalysts for CO−O2 Reaction
Okumura K., Yoshino K., Kato K., Niwa M.
Journal of Physical Chemistry B , 2005
37.
Au55[P(C6H5)3]12CI6 — ein Goldcluster ungewöhnlicher Größe
Schmid G., Pfeil R., Boese R., Bandermann F., Meyer S., Calis G.H., van der Velden J.W.
European Journal of Inorganic Chemistry , 1981
38.
Synthesis of thiol-derivatised gold nanoparticles in a two-phase Liquid–Liquid system
Brust M., Walker M., Bethell D., Schiffrin D.J., Whyman R.
Journal of the Chemical Society Chemical Communications , 1994
39.
Gold–Thiolate Ring as a Protecting Motif in the Au20(SR)16 Nanocluster and Implications
Zeng C., Liu C., Chen Y., Rosi N.L., Jin R.
Journal of the American Chemical Society , 2014
40.
Nonsuperatomic [Au23(SC6H11)16]− Nanocluster Featuring Bipyramidal Au15 Kernel and Trimeric Au3(SR)4 Motif
Das A., Li T., Nobusada K., Zeng C., Rosi N.L., Jin R.
Journal of the American Chemical Society , 2013
42.
Crystal structure and electronic properties of a thiolate-protected Au24 nanocluster
Das A., Li T., Li G., Nobusada K., Zeng C., Rosi N.L., Jin R.
Nanoscale , 2014
43.
Crystal Structure of the Gold Nanoparticle [N(C8H17)4][Au25(SCH2CH2Ph)18]
Heaven M.W., Dass A., White P.S., Holt K.M., Murray R.W.
Journal of the American Chemical Society , 2008
44.
Correlating the crystal structure of a thiol-protected Au25 cluster and optical properties.
Zhu M., Aikens C.M., Hollander F.J., Schatz G.C., Jin R.
Journal of the American Chemical Society , 2008
45.
Au25(SEt)18, a Nearly Naked Thiolate-Protected Au25 Cluster: Structural Analysis by Single Crystal X-ray Crystallography and Electron Nuclear Double Resonance
Dainese T., Antonello S., Gascón J.A., Pan F., Perera N.V., Ruzzi M., Venzo A., Zoleo A., Rissanen K., Maran F.
ACS Nano , 2014
46.
Chiral Structure of Thiolate-Protected 28-Gold-Atom Nanocluster Determined by X-ray Crystallography
Zeng C., Li T., Das A., Rosi N.L., Jin R.
Journal of the American Chemical Society , 2013
47.
High-yield synthesis and crystal structure of a green Au30cluster co-capped by thiolate and sulfide
Yang H., Wang Y., Edwards A.J., Yan J., Zheng N.
Chemical Communications , 2014
48.
Single Crystal XRD Structure and Theoretical Analysis of the Chiral Au30S(S-t-Bu)18Cluster
Crasto D., Malola S., Brosofsky G., Dass A., Häkkinen H.
Journal of the American Chemical Society , 2014
49.
Total Structure and Electronic Properties of the Gold Nanocrystal Au36(SR)24
Zeng C., Qian H., Li T., Li G., Rosi N.L., Yoon B., Barnett R.N., Whetten R.L., Landman U., Jin R.
Angewandte Chemie - International Edition , 2012
50.
Total Structure Determination of Thiolate-Protected Au38 Nanoparticles
Qian H., Eckenhoff W.T., Zhu Y., Pintauer T., Jin R.
Journal of the American Chemical Society , 2010
51.
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 Å Resolution
Jadzinsky P.D., Calero G., Ackerson C.J., Bushnell D.A., Kornberg R.D.
Science , 2007
53.
[Au7]3+: A Missing Link in the Four-Electron Gold Cluster Family
Shichibu Y., Zhang M., Kamei Y., Konishi K.
Journal of the American Chemical Society , 2014
55.
Synthesis, single crystal X-ray analysis, and TEM for a single-sized Au11 cluster stabilized by SR ligands: The interface between molecules and particles
Nunokawa K., Onaka S., Ito M., Horibe M., Yonezawa T., Nishihara H., Ozeki T., Chiba H., Watase S., Nakamoto M.
Journal of Organometallic Chemistry , 2006
56.
Synthesis and X-ray structural characterization of the centred icosahedral gold cluster compound [Aul3(PMe2Ph)10Cl2](PF6)3; the realization of a theoretical prediction
Briant C.E., Theobald B.R., White J.W., Bell L.K., Mingos D.M., Welch A.J.
Journal of the Chemical Society Chemical Communications , 1981
57.
[Au14(PPh3)8(NO3)4]: An Example of a New Class of Au(NO3)-Ligated Superatom Complexes
Gutrath B.S., Oppel I.M., Presly O., Beljakov I., Meded V., Wenzel W., Simon U.
Angewandte Chemie - International Edition , 2013
58.
Au20 Nanocluster Protected by Hemilabile Phosphines
Wan X., Lin Z., Wang Q.
Journal of the American Chemical Society , 2012
60.
A Chiral Gold Nanocluster Au20Protected by Tetradentate Phosphine Ligands
Wan X., Yuan S., Lin Z., Wang Q.
Angewandte Chemie - International Edition , 2014
61.
Controlling Gold Nanoclusters by Diphospine Ligands
Chen J., Zhang Q., Bonaccorso T.A., Williard P.G., Wang L.
Journal of the American Chemical Society , 2013
62.
Total Structure and Optical Properties of a Phosphine/Thiolate-Protected Au24 Nanocluster
Das A., Li T., Nobusada K., Zeng Q., Rosi N.L., Jin R.
Journal of the American Chemical Society , 2012
63.
Biicosahedral Gold Clusters [Au25(PPh3)10(SCnH2n+1)5Cl2]2+ (n = 2−18):  A Stepping Stone to Cluster-Assembled Materials
Shichibu Y., Negishi Y., Watanabe T., Chaki N.K., Kawaguchi H., Tsukuda T.
Journal of Physical Chemistry C , 2007
64.
Stabilized gold clusters: from isolation toward controlled synthesis
Maity P., Xie S., Yamauchi M., Tsukuda T.
Nanoscale , 2012
65.
Divide and Protect:  Capping Gold Nanoclusters with Molecular Gold−Thiolate Rings
Häkkinen H., Walter M., Grönbeck H.
Journal of Physical Chemistry B , 2006
66.
66
V. B. Evstigneev
Dokl. Akad. Nauk SSSR , 1950
67.
Ubiquitous 8 and 29 kDa Gold:Alkanethiolate Cluster Compounds: Mass-Spectrometric Determination of Molecular Formulas and Structural Implications
Chaki N.K., Negishi Y., Tsunoyama H., Shichibu Y., Tsukuda T.
Journal of the American Chemical Society , 2008
68.
Structural Prediction of Thiolate-Protected Au38: A Face-Fused Bi-icosahedral Au Core
Pei Y., Gao Y., Zeng X.C.
Journal of the American Chemical Society , 2008
70.
70
N. Bubnov
Biofizika , 1960
71.
Destabilization of Gold Clusters for Controlled Nanosynthesis: From Clusters to Polyhedra
Guan G., Liu S., Cai Y., Low M., Bharathi M.S., Zhang S., Bai S., Zhang Y., Han M.
Advanced Materials , 2014
72.
Catalysis by Gold
Bond G.C., Louis C., Thompson D.T.
Catalytic Science Series , 2006
73.
73
T. Skwarski
Chem. Abs. , 1957
75.
Gold, an alternative to platinum group metals in automobile catalytic converters
Zhang Y., Cattrall R.W., McKelvie I.D., Kolev S.D.
Gold Bulletin , 2011
76.
Metallic nanosystems in catalysis
Bukhtiyarov V.I., Slin'ko M.G.
Russian Chemical Reviews , 2001
78.
Evolution of Nonlinear Optical Properties: From Gold Atomic Clusters to Plasmonic Nanocrystals
Philip R., Chantharasupawong P., Qian H., Jin R., Thomas J.
Nano Letters , 2012
80.
Structural and Magnetic Properties of Gold and Silica Doubly Coated γ-Fe2O3 Nanoparticles
Park K., Liang G., Ji X., Luo Z., Li C., Croft M.C., Markert J.T.
Journal of Physical Chemistry C , 2007
81.
s-Electron Ferromagnetism in Gold and Silver Nanoclusters
Luo W., Pennycook S.J., Pantelides S.T.
Nano Letters , 2007
83.
Biological applications of gold nanoparticles.
Sperling R.A., Rivera Gil P., Zhang F., Zanella M., Parak W.J.
Chemical Society Reviews , 2008
84.
Theoretical Chemistry of Gold
Pyykkö P.
Angewandte Chemie - International Edition , 2004
86.
Catalytic activity of unsupported gold nanoparticles
Mikami Y., Dhakshinamoorthy A., Alvaro M., García H.
Catalysis Science and Technology , 2013
87.
Catalysis opportunities of atomically precise gold nanoclusters
Zhu Y., Qian H., Jin R.
Journal of Materials Chemistry A , 2011
88.
Air-Stable Gold Nanoparticles Ligated by Secondary Phosphine Oxides as Catalyst for the Chemoselective Hydrogenation of Substituted Aldehydes: a Remarkable Ligand Effect
Cano I., Huertos M.A., Chapman A.M., Buntkowsky G., Gutmann T., Groszewicz P.B., van Leeuwen P.W.
Journal of the American Chemical Society , 2015
89.
Atomically Precise Gold Nanoclusters as New Model Catalysts
Li G., Jin R.
Accounts of Chemical Research , 2013
91.
Size-Dependent Excited State Behavior of Glutathione-Capped Gold Clusters and Their Light-Harvesting Capacity
Stamplecoskie K.G., Kamat P.V.
Journal of the American Chemical Society , 2014
92.
Toward the creation of stable, functionalized metal clusters
Negishi Y., Kurashige W., Niihori Y., Nobusada K.
Physical Chemistry Chemical Physics , 2013
94.
A density functional investigation of thiolate-protected bimetal PdAu24(SR)18z clusters: doping the superatom complex
Kacprzak K.A., Lehtovaara L., Akola J., Lopez-Acevedo O., Häkkinen H.
Physical Chemistry Chemical Physics , 2009
95.
Isolation, structure, and stability of a dodecanethiolate-protected Pd(1)Au(24) cluster.
Negishi Y., Kurashige W., Niihori Y., Iwasa T., Nobusada K.
Physical Chemistry Chemical Physics , 2010
96.
Synthesis and Characterization of Sphere-Like Cu2ZnSnS4 Nanocrystals by Solvothermal Method
Qian C., Xiao-Juan L., Jia-Song Z., Ming-Guo S., Yun W., Xiao-Wei Z., Wei-Dong X.
Wuli Huaxue Xuebao/ Acta Physico - Chimica Sinica , 2011
97.
Palladium doping of magic gold cluster Au38(SC2H4Ph)24: formation of Pd2Au36(SC2H4Ph)24with higher stability than Au38(SC2H4Ph)24
Negishi Y., Igarashi K., Munakata K., Ohgake W., Nobusada K.
Chemical Communications , 2012
99.
(AuAg)144(SR)60 alloy nanomolecules
Kumara C., Dass A.
Nanoscale , 2011
100.
AuAg alloy nanomolecules with 38 metal atoms
Kumara C., Dass A.
Nanoscale , 2012
101.
Adding Two Active Silver Atoms on Au25 Nanoparticle
Yao C., Chen J., Li M., Liu L., Yang J., Wu Z.
Nano Letters , 2015
102.
Effect of Copper Doping on Electronic Structure, Geometric Structure, and Stability of Thiolate-Protected Au25 Nanoclusters
Negishi Y., Munakata K., Ohgake W., Nobusada K.
Journal of Physical Chemistry Letters , 2012
103.
X-ray Crystal Structure and Theoretical Analysis of Au25-xAgx(SCH2CH2Ph)18(-) Alloy.
Kumara C., Aikens C.M., Dass A.
Journal of Physical Chemistry Letters , 2014
104.
All-thiol-stabilized Ag44 and Au12Ag32 nanoparticles with single-crystal structures.
Yang H., Wang Y., Huang H., Gell L., Lehtovaara L., Malola S., Häkkinen H., Zheng N.
Nature Communications , 2013
105.
Ligand-Stabilized Au13Cux (x = 2, 4, 8) Bimetallic Nanoclusters: Ligand Engineering to Control the Exposure of Metal Sites
Yang H., Wang Y., Lei J., Shi L., Wu X., Mäkinen V., Lin S., Tang Z., He J., Häkkinen H., Zheng L., Zheng N.
Journal of the American Chemical Society , 2013
106.
Structural Evolution of Atomically Precise Thiolated Bimetallic [Au12+nCu32(SR)30+n]4– (n = 0, 2, 4, 6) Nanoclusters
Yang H., Wang Y., Yan J., Chen X., Zhang X., Häkkinen H., Zheng N.
Journal of the American Chemical Society , 2014
109.
Colloidal gold. Part II
Turkevich J.
Gold Bulletin , 1985
111.
Size Focusing: A Methodology for Synthesizing Atomically Precise Gold Nanoclusters
Jin R., Qian H., Wu Z., Zhu Y., Zhu M., Mohanty A., Garg N.
Journal of Physical Chemistry Letters , 2010
116.
Thiol-functionalized, 1.5-nm gold nanoparticles through ligand exchange reactions: scope and mechanism of ligand exchange.
Woehrle G.H., Brown L.O., Hutchison J.E.
Journal of the American Chemical Society , 2005
117.
Ligand control in thiol stabilized Au38 clusters
Stellwagen D., Weber A., Bovenkamp G.L., Jin R., Bitter J.H., Kumar C.S.
RSC Advances , 2012
119.
Two-Phase Synthesis of Small Thiolate-Protected Au15and Au18Nanoclusters
Yao Q., Yu Y., Yuan X., Yu Y., Xie J., Lee J.Y.
Small , 2013
120.
Fast Synthesis of Thiolated Au25 Nanoclusters via Protection–Deprotection Method
Yuan X., Yu Y., Yao Q., Zhang Q., Xie J.
Journal of Physical Chemistry Letters , 2012
121.
Kinetic Control and Thermodynamic Selection in the Synthesis of Atomically Precise Gold Nanoclusters
Wu Z., MacDonald M.A., Chen J., Zhang P., Jin R.
Journal of the American Chemical Society , 2011
122.
Gold clusters containing bidentate phosphine ligands. Preparation and X-Ray structure investigation of [Au5 (dppmH)3 (dppm)](NO3 )2 and [Au13 (dppmH)6 ](NO3 )n
van der Velden J.W., Vollenbroek F.A., Bour J.J., Beurskens P.T., Smits J.M., Bosnian W.P.
Recueil des Travaux Chimiques des Pays-Bas , 1981
124.
Clusters on Clusters:closo-Dodecaborate as a Ligand for Au55 Clusters
Schmid G., Pugin R., Meyer-Zaika W., Simon U.
European Journal of Inorganic Chemistry , 1999
125.
Silsesquioxanes as Ligands for Gold Clusters
Schmid G., Pugin R., Malm J., Bovin J.
European Journal of Inorganic Chemistry , 1998
126.
Reaction Mechanism Governing Formation of 1,3-Bis(diphenylphosphino)propane-Protected Gold Nanoclusters
Hudgens J.W., Pettibone J.M., Senftle T.P., Bratton R.N.
Inorganic Chemistry , 2011
127.
Nanocrystal gold molecules
Whetten R.L., Khoury J.T., Alvarez M.M., Murthy S., Vezmar I., Wang Z.L., Stephens P.W., Cleveland C.L., Luedtke W.D., Landman U.
Advanced Materials , 1996
128.
Chiroptical Activity of BINAP-Stabilized Undecagold Clusters
Yanagimoto Y., Negishi Y., Fujihara H., Tsukuda T.
Journal of Physical Chemistry B , 2006
129.
Tri-icosahedral Gold Nanocluster [Au37(PPh3)10(SC2H4Ph)10X2]+: Linear Assembly of Icosahedral Building Blocks
Jin R., Liu C., Zhao S., Das A., Xing H., Gayathri C., Xing Y., Rosi N.L., Gil R.R., Jin R.
ACS Nano , 2015
130.
Quantum Clusters in Cavities: Trapped Au15 in Cyclodextrins
Shibu E.S., Pradeep T.
Chemistry of Materials , 2011
131.
Supramolecular Functionalization and Concomitant Enhancement in Properties of Au25 Clusters
Mathew A., Natarajan G., Lehtovaara L., Häkkinen H., Kumar R.M., Subramanian V., Jaleel A., Pradeep T.
ACS Nano , 2013
132.
Gold Nanoparticles Stabilized by Thioether Dendrimers
Hermes J.P., Sander F., Peterle T., Urbani R., Pfohl T., Thompson D., Mayor M.
Chemistry - A European Journal , 2011
133.
Mixed-Monolayer-Protected Au25 Clusters with Bulky Calix[4]arene Functionalities
Hassinen J., Pulkkinen P., Kalenius E., Pradeep T., Tenhu H., Häkkinen H., Ras R.H.
Journal of Physical Chemistry Letters , 2014
135.
Determination of Rigidity of Protein Bound Au144 Clusters by Electron Cryomicroscopy
Sexton J.Z., Ackerson C.J.
Journal of Physical Chemistry C , 2010
136.
Protein-Directed Synthesis of Highly Fluorescent Gold Nanoclusters
Xie J., Zheng Y., Ying J.Y.
Journal of the American Chemical Society , 2009
137.
Protein-encapsulated gold cluster aggregates: the case of lysozyme
Baksi A., Xavier P.L., Chaudhari K., Goswami N., Pal S.K., Pradeep T.
Nanoscale , 2013
138.
Bare Clusters Derived from Protein Templates: Au25+, Au38+and Au102+
Baksi A., Pradeep T., Yoon B., Yannouleas C., Landman U.
ChemPhysChem , 2013
139.
Experimental and DFT studies of gold nanoparticles supported on MgO(111) nano-sheets and their catalytic activity
Li Z., Ciobanu C.V., Hu J., Palomares-Báez J., Rodríguez-López J., Richards R.
Physical Chemistry Chemical Physics , 2011
140.
Theory of gold on ceria
Zhang C., Michaelides A., Jenkins S.J.
Physical Chemistry Chemical Physics , 2011
141.
Au20: A Tetrahedral Cluster
Li J., Li X., Zhai H., Wang L.
Science , 2003
142.
Hydrocarbon adsorption on gold clusters: Experiment and quantum chemical modeling
Lanin S.N., Pichugina D.A., Shestakov A.F., Smirnov V.V., Nikolaev S.A., Lanina K.S., Vasil’kov A.Y., Zung F.T., Beletskaya A.V.
Russian Journal of Physical Chemistry A , 2010
143.
143
Friedl.
144.
A Structural and Stability Evaluation of Au12 from an Isolated Cluster to the Deposited Material
Mukhamedzyanova D.F., Ratmanova N.K., Pichugina D.A., Kuz’menko N.E.
Journal of Physical Chemistry C , 2012
145.
Quantum-chemical modeling of ethylene and acetylene adsorption on gold clusters
Pichugina D.A., Nikolaev S.A., Mukhamedzyanova D.F., Kuz’menko N.E.
Russian Journal of Physical Chemistry A , 2014
146.
Квантово-химическое моделирование адсорбции этилена и ацетилена на кластерах золота
Пичугина Д.А., Николаев С.А., Мухамедзянова Д.Ф., Кузьменко Н.Е.
Журнал физической химии , 2014
147.
Sites for the selective hydrogenation of ethyne to ethene on supported NiO/Au catalysts
Nikolaev S.А., Pichugina D.А., Mukhamedzyanova D.F.
Gold Bulletin , 2012
148.
Effect of the structure and charge of Au10 clusters on adsorption of hydrocarbons
Pichugina D.A., Lanin S.N., Kovaleva N.V., Lanina K.S., Shestakov A.F., Kuz’menko N.E.
Russian Chemical Bulletin , 2010
149.
149
V. V. Korshak
Dokl. Akad. Nauk SSSR , 1954
150.
Role of deposition technique and support nature on the catalytic activity of supported gold clusters: experimental and theoretical study
Golubina E.V., Pichugina D.A., Majouga A.G., Aytekenov S.A.
Studies in Surface Science and Catalysis , 2010
151.
Catalysis by very small Au clusters
CHRETIEN S., BURATTO S., METIU H.
Current Opinion in Solid State and Materials Science , 2007
152.
New Protocols for the Synthesis of Stable Ag and Au Nanocluster Molecules
Udayabhaskararao T., Pradeep T.
Journal of Physical Chemistry Letters , 2013
153.
X-ray Spectroscopy of Gold–Thiolate Nanoclusters
Zhang P.
Journal of Physical Chemistry C , 2014
154.
Isolation and Selected Properties of a 10.4 kDa Gold:Glutathione Cluster Compound
Schaaff T.G., Knight G., Shafigullin M.N., Borkman R.F., Whetten R.L.
Journal of Physical Chemistry B , 1998
155.
Infra-red spectroscopy of size selected Au25, Au38 and Au144 ligand protected gold clusters
Farrag M., Tschurl M., Dass A., Heiz U.
Physical Chemistry Chemical Physics , 2013
156.
Nonlinear Optical Properties of Thiolate-Protected Gold Clusters
Knoppe S., Vanbel M., van Cleuvenbergen S., Vanpraet L., Bürgi T., Verbiest T.
Journal of Physical Chemistry C , 2015
157.
Probing the Structure and Charge State of Glutathione-Capped Au25(SG)18 Clusters by NMR and Mass Spectrometry
Wu Z., Gayathri C., Gil R.R., Jin R.
Journal of the American Chemical Society , 2009
158.
Electron Transfer between [Au25(SC2H4Ph)18]−TOA+ and Oxoammonium Cations
Liu Z., Zhu M., Meng X., Xu G., Jin R.
Journal of Physical Chemistry Letters , 2011
159.
Structural evolution of smaller gold nanocrystals: The truncated decahedral motif
Cleveland C.L., Landman U., Schaaff T.G., Shafigullin M.N., Stephens P.W., Whetten R.L.
Physical Review Letters , 1997
160.
Self-Assembled Monolayers of Thiolates on Metals as a Form of Nanotechnology
Love J.C., Estroff L.A., Kriebel J.K., Nuzzo R.G., Whitesides G.M.
Chemical Reviews , 2005
161.
Self-assembled monolayers of alkanethiols on Au(111): surface structures, defects and dynamics
Vericat C., Vela M.E., Salvarezza R.C.
Physical Chemistry Chemical Physics , 2005
162.
Onset of Double Helical Structure in Small-Sized Homoleptic Gold Thiolate Clusters
Shao N., Pei Y., Gao Y., Zeng X.C.
Journal of Physical Chemistry A , 2009
163.
The Smallest Thiolated Gold Superatom Complexes
Jiang D., Whetten R.L., Luo W., Dai S.
Journal of Physical Chemistry C , 2009
164.
Structure of Au15(SR)13 and Its Implication for the Origin of the Nucleus in Thiolated Gold Nanoclusters
Jiang D., Overbury S.H., Dai S.
Journal of the American Chemical Society , 2013
165.
On the structure of the thiolated Au15 cluster
Tlahuice-Flores A., Jose-Yacamán M., Whetten R.L.
Physical Chemistry Chemical Physics , 2013
166.
On the structure of the Au18(SR)14 cluster
Tlahuice A., Garzón I.L.
Physical Chemistry Chemical Physics , 2012
167.
Isolation of Ubiquitous Au40(SR)24Clusters from the 8 kDa Gold Clusters
Qian H., Zhu Y., Jin R.
Journal of the American Chemical Society , 2010
168.
On the Structure of a Thiolated Gold Cluster: Au44(SR)282−
Jiang D., Walter M., Akola J.
Journal of Physical Chemistry C , 2010
170.
Structure of the Thiolated Au130 Cluster
Tlahuice-Flores A., Santiago U., Bahena D., Vinogradova E., Conroy C.V., Ahuja T., Bach S.B., Ponce A., Wang G., José-Yacamán M., Whetten R.L.
Journal of Physical Chemistry A , 2013
171.
Aspects of bonding in small gold clusters
Xiong X., Xu W., Li J., Pyykkö P.
International Journal of Mass Spectrometry , 2013
172.
Communication: Determining the lowest-energy isomer of Au8: 2D, or not 2D
Hansen J.A., Piecuch P., Levine B.G.
Journal of Chemical Physics , 2013
173.
Is Au6 a circular ring?
Balasubramanian K., Liao D.
Journal of Chemical Physics , 1991
178.
A Missing Link in Undecagold Cluster Chemistry: Single‐Crystal X‐ray Analysis of [Au 11 (PPh 3 ) 7 Cl 3 ]
Gutrath B.S., Englert U., Wang Y., Simon U.
European Journal of Inorganic Chemistry , 2013
179.
Accurate Computation of Cohesive Energies for Small to Medium-Sized Gold Clusters.
Chan B., Yim W.
Journal of Chemical Theory and Computation , 2013
182.
A Benchmark Study of H2 Activation by Au3 and Ag3 Clusters
Moncho S., Brothers E.N., Janesko B.G.
Journal of Physical Chemistry C , 2013
184.
Quantum Monte Carlo for noncovalent interactions: an efficient protocol attaining benchmark accuracy
Dubecký M., Derian R., Jurečka P., Mitas L., Hobza P., Otyepka M.
Physical Chemistry Chemical Physics , 2014
185.
Development of Interatomic ReaxFF Potentials for Au–S–C–H Systems
Järvi T.T., van Duin A.C., Nordlund K., Goddard W.A.
Journal of Physical Chemistry A , 2011
186.
Improved ReaxFF Force Field Parameters for Au–S–C–H Systems
Bae G., Aikens C.M.
Journal of Physical Chemistry A , 2013
187.
A QM/MM approach for the study of monolayer-protected gold clusters
Banerjee S., Montgomery J.A., Gascón J.A.
Journal of Materials Science , 2012
188.
Surfactant-free Synthesis of Ultrasmall Gold Nanoclusters
Reilly S.M., Krick T., Dass A.
Journal of Physical Chemistry C , 2009
189.
Glutathione capped gold AuN(SG)M clusters studied by isotope-resolved mass spectrometry
Hamouda R., Bertorelle F., Rayane D., Antoine R., Broyer M., Dugourd P.
International Journal of Mass Spectrometry , 2013
192.
Thiolate-Protected Au24(SC2H4Ph)20 Nanoclusters: Superatoms or Not?
Zhu M., Qian H., Jin R.
Journal of Physical Chemistry Letters , 2010
194.
Homoleptic Gold Thiolate Catenanes
Wiseman M.R., Marsh P.A., Bishop P.T., Brisdon B.J., Mahon M.F.
Journal of the American Chemical Society , 2000
195.
On the Structure of Thiolate-Protected Au25
Akola J., Walter M., Whetten R.L., Häkkinen H., Grönbeck H.
Journal of the American Chemical Society , 2008
196.
Ligand Effects on the Structure and the Electronic Optical Properties of Anionic Au25(SR)18 Clusters
Tlahuice-Flores A., Whetten R.L., Jose-Yacaman M.
Journal of Physical Chemistry C , 2013
197.
10.1021/ja073580+
198.
Superatom Electron Configuration Predicts Thermal Stability of Au25(SR)18 Nanoclusters
Tofanelli M.A., Ackerson C.J.
Journal of the American Chemical Society , 2012
199.
Interplay of charge state, lability, and magnetism in the molecule-like Au25(SR)18 cluster.
Antonello S., Perera N.V., Ruzzi M., Gascón J.A., Maran F.
Journal of the American Chemical Society , 2013
201.
Synthesis and Isolation of the Molecule-like Cluster Au38(PhCH2CH2S)24
Donkers R.L., Lee D., Murray R.W.
Langmuir , 2004
203.
Do Thiols Merely Passivate Gold Nanoclusters?
Garzón I.L., Rovira C., Michaelian K., Beltrán M.R., Ordejón P., Junquera J., Sánchez-Portal D., Artacho E., Soler J.M.
Physical Review Letters , 2000
204.
The “Staple” Motif:  A Key to Stability of Thiolate-Protected Gold Nanoclusters
Jiang D., Tiago M.L., Luo W., Dai S.
Journal of the American Chemical Society , 2008
205.
Racemization of a Chiral Nanoparticle Evidences the Flexibility of the Gold–Thiolate Interface
Knoppe S., Dolamic I., Bürgi T.
Journal of the American Chemical Society , 2012
207.
Au40(SR)24 Cluster as a Chiral Dimer of 8-Electron Superatoms: Structure and Optical Properties
Malola S., Lehtovaara L., Knoppe S., Hu K., Palmer R.E., Bürgi T., Häkkinen H.
Journal of the American Chemical Society , 2012
208.
10.1021/ja053968+
209.
Structure Prediction of Au44(SR)28: A Chiral Superatom Cluster
Pei Y., Lin S., Su J., Liu C.
Journal of the American Chemical Society , 2013
210.
Ab Initio Study of Thiolate-Protected Au102 Nanocluster
Gao Y., Shao N., Zeng X.C.
ACS Nano , 2008
212.
Understanding the Magic Nature of Ligand-Protected Gold Nanoparticle Au102(MBA)44
Han Y., Kim H., Jung J., Choi Y.C.
Journal of Physical Chemistry C , 2010
213.
Determining the size-dependent structure of ligand-free gold-cluster ions
Schooss D., Weis P., Hampe O., Kappes M.M.
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences , 2010
214.
Structural and Theoretical Basis for Ligand Exchange on Thiolate Monolayer Protected Gold Nanoclusters
Heinecke C.L., Ni T.W., Malola S., Mäkinen V., Wong O.A., Häkkinen H., Ackerson C.J.
Journal of the American Chemical Society , 2012
215.
Mixed Dithiolate Durene-DT and Monothiolate Phenylethanethiolate Protected Au130 Nanoparticles with Discrete Core and Core-Ligand Energy States
Tang Z., Robinson D.A., Bokossa N., Xu B., Wang S., Wang G.
Journal of the American Chemical Society , 2011
218.
Ambient Synthesis of Au144(SR)60 Nanoclusters in Methanol
Qian H., Jin R.
Chemistry of Materials , 2011
219.
Structure and Bonding in the Ubiquitous Icosahedral Metallic Gold Cluster Au144(SR)60
Lopez-Acevedo O., Akola J., Whetten R.L., Grönbeck H., Häkkinen H.
Journal of Physical Chemistry C , 2009
220.
Vibrational Perturbations and Ligand–Layer Coupling in a Single Crystal of Au144(SC2H4Ph)60 Nanocluster
Koivisto J., Salorinne K., Mustalahti S., Lahtinen T., Malola S., Häkkinen H., Pettersson M.
Journal of Physical Chemistry Letters , 2014
221.
Ultrafast Electronic Relaxation and Vibrational Cooling Dynamics of Au144(SC2H4Ph)60 Nanocluster Probed by Transient Mid-IR Spectroscopy
Mustalahti S., Myllyperkiö P., Lahtinen T., Salorinne K., Malola S., Koivisto J., Häkkinen H., Pettersson M.
Journal of Physical Chemistry C , 2014
222.
Atomistic Simulations of Functional Au144(SR)60 Gold Nanoparticles in Aqueous Environment
Heikkilä E., Gurtovenko A.A., Martinez-Seara H., Häkkinen H., Vattulainen I., Akola J.
Journal of Physical Chemistry C , 2012
223.
Ab initiorelativistic pseudopotential study of small silver and gold sulfide clusters (M2S)n, n=1 and 2
Bagatur’yants A.A., Safonov A.A., Stoll H., Werner H.
Journal of Chemical Physics , 1998
224.
A theoretical study of the activation of methane by Gold(III) homoleptic complexes
Pichugina D.A., Shestakov A.F., Kuz’menko N.E.
Russian Journal of Physical Chemistry A , 2007
225.
225
1960
226.
Surface characterization of sulfur and alkanethiol self-assembled monolayers on Au(111)
Vericat C., Vela M.E., Benitez G.A., Gago J.A., Torrelles X., Salvarezza R.C.
Journal of Physics Condensed Matter , 2006
231.
Regularities of the retention of aminopyridines by silica gel modified with gold nanoparticles
Elfimova Y.A., Pichugina D.A., Anan’eva I.A., Mazhuga A.G., Shpigun O.A.
Russian Journal of Physical Chemistry A , 2012
232.
232
Chem. Abs. , 1960
233.
New separation materials based on gold nanoparticles
Majouga A., Pichugina D., Ananieva I., Kurilova S., Shpigun O., Kuz'menko N., Zyk N.
Journal of Manufacturing Technology Management , 2010
234.
Methanethiolate Adsorption Site on Au(111):  A Combined STM/DFT Study at the Single-Molecule Level
Maksymovych P., Sorescu D.C., Yates J.T.
Journal of Physical Chemistry B , 2006
238.
Gold−Thiolate Complexes Form a Unique c(4 × 2) Structure on Au(111)
Grönbeck H., Häkkinen H., Whetten R.L.
Journal of Physical Chemistry C , 2008
239.
Structure of aCH3SMonolayer on Au(111) Solved by the Interplay between Molecular Dynamics Calculations and Diffraction Measurements
Mazzarello R., Cossaro A., Verdini A., Rousseau R., Casalis L., Danisman M.F., Floreano L., Scandolo S., Morgante A., Scoles G.
Physical Review Letters , 2007
240.
The chemistry of the sulfur-gold interface: in search of a unified model.
Pensa E., Cortés E., Corthey G., Carro P., Vericat C., Fonticelli M.H., Benítez G., Rubert A.A., Salvarezza R.C.
Accounts of Chemical Research , 2012
241.
X-ray Diffraction and Computation Yield the Structure of Alkanethiols on Gold(111)
Cossaro A., Mazzarello R., Rousseau R., Casalis L., Verdini A., Kohlmeyer A., Floreano L., Scandolo S., Morgante A., Klein M.L., Scoles G.
Science , 2008
243.
Oxidation of Gold Clusters by Thiols
Barngrover B.M., Aikens C.M.
Journal of Physical Chemistry A , 2013
244.
Ag44(SeR)30: A Hollow Cage Silver Cluster with Selenolate Protection
Chakraborty I., Kurashige W., Kanehira K., Gell L., Häkkinen H., Negishi Y., Pradeep T.
Journal of Physical Chemistry Letters , 2013
245.
Au25 Clusters Containing Unoxidized Tellurolates in the Ligand Shell
Kurashige W., Yamazoe S., Yamaguchi M., Nishido K., Nobusada K., Tsukuda T., Negishi Y.
Journal of Physical Chemistry Letters , 2014
246.
Au@Phenyacetylene organogold clusters: Direct spectroscopic evidence of gold–carbon covalent band
Zhang H., Yin P., You T., Sun T., Lang X., Tan E., Liang X., Guo L.
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy , 2015
248.
DFT Study of Ligand Binding to Small Gold Clusters
Goel S., Velizhanin K.A., Piryatinski A., Tretiak S., Ivanov S.A.
Journal of Physical Chemistry Letters , 2010
250.
Gold clusters: synthesis and characterization of [Au8(PPh3)7(CNR)]2+, [Au9(PPh36(CNR2]3+ and [Au11(PPH37(CNR)2O]2+ and their reactivity towards amines. The crystal structure of [Au11(PPh3)7(CN-i-Pr)2I](PF6)2
Bos W., Kanters R.P., Van Halen C.J., Bosman W.P., Behm H., Smits J.M., Beurskens P.T., Bour J.J., Pignolet L.H.
Journal of Organometallic Chemistry , 1986
253.
Electronic Stability of Phosphine-Protected Au20 Nanocluster: Superatomic Bonding
Yuan Y., Cheng L., Yang J.
Journal of Physical Chemistry C , 2013
255.
Toward the Solution Synthesis of the Tetrahedral Au20 Cluster
Zhang H., Stender M., Zhang R., Wang C., Li J., Wang L.
Journal of Physical Chemistry B , 2004
256.
Role of the Central Gold Atom in Ligand-Protected Biicosahedral Au24 and Au25 Clusters
Goh J., Malola S., Häkkinen H., Akola J.
Journal of Physical Chemistry C , 2013
257.
Electronic and Optical Properties of Vertex-Sharing Homo- and Hetero-Biicosahedral Gold Clusters
Iwasa T., Nobusada K., Nakajima A.
Journal of Physical Chemistry C , 2013
258.
Ligand-Stabilized Metal Clusters:  Reinvestigation of the Structure of “Au55[P(C6H5)3]12Cl6”
Rapoport D.H., Vogel W., Cölfen H., Schlögl R.
Journal of Physical Chemistry B , 1997
259.
Improved Synthesis of Small (dCORE ≈ 1.5 nm) Phosphine-Stabilized Gold Nanoparticles
Weare W.W., Reed S.M., Warner M.G., Hutchison J.E.
Journal of the American Chemical Society , 2000
260.
NMR Characterization of Ligand Binding and Exchange Dynamics in Triphenylphosphine-Capped Gold Nanoparticles
Sharma R., Holland G.P., Solomon V.C., Zimmermann H., Schiffenhaus S., Amin S.A., Buttry D.A., Yarger J.L.
Journal of Physical Chemistry C , 2009
262.
Oxygen Electroreduction Catalyzed by Gold Nanoclusters: Strong Core Size Effects
Chen W., Chen S.
Angewandte Chemie - International Edition , 2009
264.
Electronic and Geometric Structure of the Cluster Compound Au55[P(C6H5)3]12Cl6. A Computational Study
Genest A., Krüger S., Rösch N.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences , 2009
268.
Mass Spectrometry of Small Bimetal Monolayer-Protected Clusters
Fields-Zinna C.A., Crowe M.C., Dass A., Weaver J.E., Murray R.W.
Langmuir , 2009
269.
Separation of Precise Compositions of Noble Metal Clusters Protected with Mixed Ligands
Niihori Y., Matsuzaki M., Pradeep T., Negishi Y.
Journal of the American Chemical Society , 2013
270.
Formation of a Pd@Au12Superatomic Core in Au24Pd1(SC12H25)18Probed by197Au Mössbauer and Pd K-Edge EXAFS Spectroscopy
Negishi Y., Kurashige W., Kobayashi Y., Yamazoe S., Kojima N., Seto M., Tsukuda T.
Journal of Physical Chemistry Letters , 2013
271.
Ligand-Protected Gold Alloy Clusters: Doping the Superatom
Walter M., Moseler M.
Journal of Physical Chemistry C , 2009
273.
Phosphine-stabilized, platinum-gold and palladium-gold cluster compounds and applications in catalysis
Pignolet L.H., Aubart M.A., Craighead K.L., Gould R.A., Krogstad D.A., Wiley J.S.
Coordination Chemistry Reviews , 1995
274.
Monoplatinum doping of gold nanoclusters and catalytic application.
Qian H., Jiang D., Li G., Gayathri C., Das A., Gil R.R., Jin R.
Journal of the American Chemical Society , 2012
275.
Dopant Location, Local Structure, and Electronic Properties of Au24Pt(SR)18 Nanoclusters
Christensen S.L., MacDonald M.A., Chatt A., Zhang P., Qian H., Jin R.
Journal of Physical Chemistry C , 2012
278.
Atomic-level alloying and de-alloying in doped gold nanoparticles.
Gottlieb E., Qian H., Jin R.
Chemistry - A European Journal , 2013
279.
A 200-fold quantum yield boost in the photoluminescence of silver-doped Ag(x)Au(25-x) nanoclusters: the 13th silver atom matters.
Wang S., Meng X., Das A., Li T., Song Y., Cao T., Zhu X., Zhu M., Jin R.
Angewandte Chemie - International Edition , 2014
283.
Ag7Au6: a 13-atom alloy quantum cluster.
Udayabhaskararao T., Sun Y., Goswami N., Pal S.K., Balasubramanian K., Pradeep T.
Angewandte Chemie - International Edition , 2012
284.
On the structure of the thiolated Au6Ag7cluster
Tlahuice-Flores A.
Physical Chemistry Chemical Physics , 2014
285.
Isolation of Smaller Nanocrystal Au Molecules: Robust Quantum Effects in Optical Spectra
Schaaff T.G., Shafigullin M.N., Khoury J.T., Vezmar I., Whetten R.L., Cullen W.G., First P.N., Gutiérrez-Wing C., Ascensio J., Jose-Yacamán M.J.
Journal of Physical Chemistry B , 1997
286.
Information on quantum states pervades the visible spectrum of the ubiquitous Au144(SR)60 gold nanocluster
Weissker H.-., Escobar H.B., Thanthirige V.D., Kwak K., Lee D., Ramakrishna G., Whetten R.L., López-Lozano X.
Nature Communications , 2014
287.
Faradaurate Nanomolecules: A Superstable Plasmonic 76.3 kDa Cluster
Dass A.
Journal of the American Chemical Society , 2011
288.
Intracellular Thermometry by Using Fluorescent Gold Nanoclusters
Shang L., Stockmar F., Azadfar N., Nienhaus G.U.
Angewandte Chemie - International Edition , 2013
289.
Thermoresponsive Assembly of Charged Gold Nanoparticles and Their Reversible Tuning of Plasmon Coupling
Liu Y., Han X., He L., Yin Y.
Angewandte Chemie - International Edition , 2012
291.
Electronic Structure of Ligand-Passivated Gold and Silver Nanoclusters
Aikens C.M.
Journal of Physical Chemistry Letters , 2010
292.
Non-linear optical properties of gold quantum clusters. The smaller the better
Russier-Antoine I., Bertorelle F., Vojkovic M., Rayane D., Salmon E., Jonin C., Dugourd P., Antoine R., Brevet P.
Nanoscale , 2014
293.
Thiolate-Protected Au25 Superatoms as Building Blocks: Dimers and Crystals
Akola J., Kacprzak K.A., Lopez-Acevedo O., Walter M., Grönbeck H., Häkkinen H.
Journal of Physical Chemistry C , 2010
294.
Organized Plasmonic Clusters with High Coordination Number and Extraordinary Enhancement in Surface-Enhanced Raman Scattering (SERS)
Pazos-Perez N., Wagner C.S., Romo-Herrera J.M., Liz-Marzán L.M., García de Abajo F.J., Wittemann A., Fery A., Alvarez-Puebla R.A.
Angewandte Chemie - International Edition , 2012
295.
Chirality in Thiolate-Protected Gold Clusters
Knoppe S., Bürgi T.
Accounts of Chemical Research , 2014
296.
Superatomic Orbitals under Spin–Orbit Coupling
Jiang D., Kühn M., Tang Q., Weigend F.
Journal of Physical Chemistry Letters , 2014
298.
Au25(SG)18 as a fluorescent iodide sensor
Wang M., Wu Z., Yang J., Wang G., Wang H., Cai W.
Nanoscale , 2012
299.
Well-defined nanoclusters as fluorescent nanosensors: a case study on Au(25) (SG)(18).
Wu Z., Wang M., Yang J., Zheng X., Cai W., Meng G., Qian H., Wang H., Jin R.
Small , 2012
300.
From Aggregation-Induced Emission of Au(I)–Thiolate Complexes to Ultrabright Au(0)@Au(I)–Thiolate Core–Shell Nanoclusters
Luo Z., Yuan X., Yu Y., Zhang Q., Leong D.T., Lee J.Y., Xie J.
Journal of the American Chemical Society , 2012
301.
Intensely Luminescent Alkynyl−Phosphine Gold(I)−Copper(I) Complexes: Synthesis, Characterization, Photophysical, and Computational Studies
Koshevoy I.O., Lin Y., Karttunen A.J., Chou P., Vainiotalo P., Tunik S.P., Haukka M., Pakkanen T.A.
Inorganic Chemistry , 2009
302.
Photoluminescence from Excited Energy Bands in Au$_{25}$ Nanoclusters
Sakanaga I., Inada M., Saitoh T., Kawasaki H., Iwasaki Y., Yamada T., Umezu I., Sugimura A.
Applied Physics Express , 2011
303.
Visible Luminescence of Water-Soluble Monolayer-Protected Gold Clusters
Huang T., Murray R.W.
Journal of Physical Chemistry B , 2001
304.
Identification of a Highly Luminescent Au22(SG)18 Nanocluster
Yu Y., Luo Z., Chevrier D.M., Leong D.T., Zhang P., Jiang D., Xie J.
Journal of the American Chemical Society , 2014
306.
Luminescent gold(I) complexes for chemosensing
He X., Yam V.W.
Coordination Chemistry Reviews , 2011
307.
Luminescent metal complexes of d6, d8 and d10 transition metal centres
Yam V.W., Wong K.M.
Chemical Communications , 2011
309.
Chalcogenide centred gold complexes
Gimeno M.C., Laguna A.
Chemical Society Reviews , 2008
311.
Understanding thiol-induced etching of luminescent gold nanoclusters
Ke C., Chen T., Lu L., Tseng W.
RSC Advances , 2014
312.
Functionalized Au22 Clusters: Synthesis, Characterization, and Patterning
Shibu E.S., Radha B., Verma P.K., Bhyrappa P., Kulkarni G.U., Pal S.K., Pradeep T.
ACS applied materials & interfaces , 2009
313.
Synthesis, characterization, and bioconjugation of fluorescent gold nanoclusters toward biological labeling applications.
Lin C.J., Yang T., Lee C., Huang S.H., Sperling R.A., Zanella M., Li J.K., Shen J., Wang H., Yeh H., Parak W.J., Chang W.H.
ACS Nano , 2009
314.
Bright, NIR-Emitting Au23from Au25: Characterization and Applications Including Biolabeling
Muhammed M., Verma P., Pal S., Kumar R. ., Paul S., Omkumar R., Pradeep T.
Chemistry - A European Journal , 2009
315.
Luminescent Quantum Clusters of Gold in Bulk by Albumin-Induced Core Etching of Nanoparticles: Metal Ion Sensing, Metal-Enhanced Luminescence, and Biolabeling
Habeeb Muhammed M., Verma P., Pal S., Retnakumari A., Koyakutty M., Nair S., Pradeep T.
Chemistry - A European Journal , 2010
316.
X-ray Magnetic Circular Dichroism of Size-Selected, Thiolated Gold Clusters
Negishi Y., Tsunoyama H., Suzuki M., Kawamura N., Matsushita M.M., Maruyama K., Sugawara T., Yokoyama T., Tsukuda T.
Journal of the American Chemical Society , 2006
317.
Reversible Switching of Magnetism in Thiolate-Protected Au25 Superatoms
Zhu M., Aikens C.M., Hendrich M.P., Gupta R., Qian H., Schatz G.C., Jin R.
Journal of the American Chemical Society , 2009
318.
Chemically Induced Magnetism in Atomically Precise Gold Clusters
Krishna K.S., Tarakeshwar P., Mujica V., Kumar C.S.
Small , 2013
320.
Large optical activity of gold nanocluster enantiomers induced by a pair of optically active penicillamines.
Yao H., Miki K., Nishida N., Sasaki A., Kimura K.
Journal of the American Chemical Society , 2005
322.
On the Origin of the Optical Activity Displayed by Chiral-Ligand-Protected Metallic Nanoclusters
Sánchez-Castillo A., Noguez C., Garzón I.L.
Journal of the American Chemical Society , 2010
323.
A new approach to active supported Au catalysts
Kozlov A.I., Kozlova A.P., Liu H., Iwasawa Y.
Applied Catalysis A: General , 1999
324.
Following the Creation of Active Gold Nanocatalysts from Phosphine-Stabilized Molecular Clusters
Kilmartin J., Sarip R., Grau-Crespo R., Di Tommaso D., Hogarth G., Prestipino C., Sankar G.
ACS Catalysis , 2012
329.
Enhancement in Aerobic Alcohol Oxidation Catalysis of Au25 Clusters by Single Pd Atom Doping
Xie S., Tsunoyama H., Kurashige W., Negishi Y., Tsukuda T.
ACS Catalysis , 2012
331.
Ligand-Stabilized and Atomically Precise Gold Nanocluster Catalysis: A Case Study for Correlating Fundamental Electronic Properties with Catalysis
Liu J., Krishna K.S., Losovyj Y.B., Chattopadhyay S., Lozova N., Miller J.T., Spivey J.J., Kumar C.S.
Chemistry - A European Journal , 2013
333.
Efficient and selective epoxidation of styrene with TBHP catalyzed by Au25clusters on hydroxyapatite
Liu Y., Tsunoyama H., Akita T., Tsukuda T.
Chemical Communications , 2010
334.
Selective oxidation with dioxygen by gold nanoparticle catalysts derived from 55-atom clusters
Turner M., Golovko V.B., Vaughan O.P., Abdulkin P., Berenguer-Murcia A., Tikhov M.S., Johnson B.F., Lambert R.M.
Nature , 2008
340.
N,N-Dimethylformamide-stabilized gold nanoclusters as a catalyst for the reduction of 4-nitrophenol
Yamamoto H., Yano H., Kouchi H., Obora Y., Arakawa R., Kawasaki H.
Nanoscale , 2012
341.
Stable and recyclable Au25clusters for the reduction of 4-nitrophenol
Shivhare A., Ambrose S.J., Zhang H., Purves R.W., Scott R.W.
Chemical Communications , 2013
342.
Au25 nanocluster-catalyzed Ullmann-type homocoupling reaction of aryl iodides
Li G., Liu C., Lei Y., Jin R.
Chemical Communications , 2012
344.
Conversion of Anionic [Au25(SCH2CH2Ph)18]− Cluster to Charge Neutral Cluster via Air Oxidation
Zhu M., Eckenhoff W.T., Pintauer T., Jin R.
Journal of Physical Chemistry C , 2008
345.
Chemically-synthesised, atomically-precise gold clusters deposited and activated on titania
Anderson D.P., Alvino J.F., Gentleman A., Qahtani H.A., Thomsen L., Polson M.I., Metha G.F., Golovko V.B., Andersson G.G.
Physical Chemistry Chemical Physics , 2013
346.
Photomediated Oxidation of Atomically Precise Au25(SC2H4Ph)18– Nanoclusters
Kauffman D.R., Alfonso D., Matranga C., Li G., Jin R.
Journal of Physical Chemistry Letters , 2012
347.
First-principles study of O2 activation on ligand-protected Au32 clusters
Yu S., Zeng Q., Lou Z., Yang M., Wu D.
Physical Chemistry Chemical Physics , 2013
350.
350
J. H. Balthis
1969
351.
Selective hydrogenation of phenylacetylene into styrene on gold nanoparticles
Nikolaev S.A., Permyakov N.A., Smirnov V.V., Vasil’kov A.Y., Lanin S.N.
Kinetics and Catalysis , 2010
352.
352
M. Ya. Popil'skii
Byull. Izobr. , 1970