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Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation

Boris Petrovich Tumanyan 1
Boris Petrovich Tumanyan
, 
Natal'ya Nikolaevna Petrukhina 1
Natal'ya Nikolaevna Petrukhina
, 
Galina Petrovna Kayukova 2, 3
Galina Petrovna Kayukova
,  , 
L E Foss 2
L E Foss
, 
Gennadii Vasil'evich Romanov 2, 3
Gennadii Vasil'evich Romanov
1 Gubkin Russian State University of Oil and Gas
2 A. E. Arbuzov Institute of Organic and Physical Chemistry of Kazan Scientific Center of Russian Academy of Sciences
3 Kazan (Volga region) Federal University
10.1070/RCR4500
Published 30 November 2014
Communication , Volume 84, Issue 11, 1145-1175
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Tumanyan B. P. et al. Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1145-1175.
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Tumanyan B. P., Petrukhina N. N., Kayukova G. P., Nurgaliev D. K., Foss L. E., Romanov G. V. Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation // Russian Chemical Reviews. 2015. Vol. 84. No. 11. pp. 1145-1175.
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TY - JOUR
DO - 10.1070/RCR4500
UR - https://rcr.colab.ws/publications/10.1070/RCR4500
TI - Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation
T2 - Russian Chemical Reviews
AU - Tumanyan, Boris Petrovich
AU - Petrukhina, Natal'ya Nikolaevna
AU - Kayukova, Galina Petrovna
AU - Nurgaliev, Danis Karlovich
AU - Foss, L E
AU - Romanov, Gennadii Vasil'evich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 1145-1175
IS - 11
VL - 84
ER -
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@article{2015_Tumanyan,
author = {Boris Petrovich Tumanyan and Natal'ya Nikolaevna Petrukhina and Galina Petrovna Kayukova and Danis Karlovich Nurgaliev and L E Foss and Gennadii Vasil'evich Romanov},
title = {Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4500},
number = {11},
pages = {1145--1175},
doi = {10.1070/RCR4500}
}
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Tumanyan, Boris Petrovich, et al. “Aquathermolysis of crude oils and natural bitumen: chemistry, catalysts and prospects for industrial implementation.” Russian Chemical Reviews, vol. 84, no. 11, Nov. 2015, pp. 1145-1175. https://rcr.colab.ws/publications/10.1070/RCR4500.
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Abstract

The results of studies of alterations in the elemental and SARA compositions and physicochemical and rheological properties of highly viscous heavy crude oils upon catalytic and non-catalytic aquathermolysis are generalized. The chemistry of transformations of model hydrocarbons and heteroatomic compounds in aqueous media at high temperature, including subcritical and supercritical conditions, is considered. Comparative analysis of methods for activation of oil conversion {\it via} aquathermolysis using hydrogen donors, oil-soluble and water-soluble nanodispersed catalysts, ionic hydrogenation processes and various ways for reservoir heating is presented. Problems and prospects of oil-field implementation of catalytic aquathermolysis for upgrading heavy oils and natural bitumen are discussed.

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