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Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions

Evgeny Nikolaevich Ushakov 1, 2
Evgeny Nikolaevich Ushakov
, 
Sergei Panteleimonovich Gromov 2
Sergei Panteleimonovich Gromov
1 Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow region
2 Photochemistry Centre, Russian Academy of Sciences, Moscow
10.1070/RCR4514
Published 30 November 2014
Communication , Volume 84, Issue 8, 787-802
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Ushakov E. N., Gromov S. P. Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions // Russian Chemical Reviews. 2015. Vol. 84. No. 8. pp. 787-802.
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Ushakov E. N., Gromov S. P. Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions // Russian Chemical Reviews. 2015. Vol. 84. No. 8. pp. 787-802.
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TY - JOUR
DO - 10.1070/RCR4514
UR - https://rcr.colab.ws/publications/10.1070/RCR4514
TI - Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions
T2 - Russian Chemical Reviews
AU - Ushakov, Evgeny Nikolaevich
AU - Gromov, Sergei Panteleimonovich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 787-802
IS - 8
VL - 84
ER -
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@article{2015_Ushakov,
author = {Evgeny Nikolaevich Ushakov and Sergei Panteleimonovich Gromov},
title = {Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4514},
number = {8},
pages = {787--802},
doi = {10.1070/RCR4514}
}
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Ushakov, Evgeny Nikolaevich, and Sergei Panteleimonovich Gromov. “Supramolecular methods for controlling intermolecular [2+2] photocycloaddition reactions of unsaturated compounds in solutions.” Russian Chemical Reviews, vol. 84, no. 8, Nov. 2015, pp. 787-802. https://rcr.colab.ws/publications/10.1070/RCR4514.
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Abstract

This review deals with the methods of supramolecular chemistry used for controlling the efficiency and stereoselectivity of intermolecular [2+2] photocycloaddition of olefins and other unsaturated compounds in homogeneous solutions. The best-studied methods are self-assembly through cation--macrocycle interactions, complexation with molecular templates through hydrogen bonding, and confinement of the reactants in supramolecular containers. The possibilities of using anionic templates and combined supramolecular approaches are discussed.

The bibliography includes 107~references.

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