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Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds

Yurii Yur'evich Medvedev 1
Yurii Yur'evich Medvedev
, 
Valery Aleksandrovich Nikolaev 1
Valery Aleksandrovich Nikolaev
1 Institute of Chemistry, St. Petersburg State University
10.1070/RCR4522
Published 30 November 2014
Communication , Volume 84, Issue 7, 737-757
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Medvedev Y. Y., Nikolaev V. A. Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds // Russian Chemical Reviews. 2015. Vol. 84. No. 7. pp. 737-757.
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Medvedev Y. Y., Nikolaev V. A. Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds // Russian Chemical Reviews. 2015. Vol. 84. No. 7. pp. 737-757.
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TY - JOUR
DO - 10.1070/RCR4522
UR - https://rcr.colab.ws/publications/10.1070/RCR4522
TI - Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds
T2 - Russian Chemical Reviews
AU - Medvedev, Yurii Yur'evich
AU - Nikolaev, Valery Aleksandrovich
PY - 2015
DA - 2014/11/30
PB - ANO Editorial Board of the journal Uspekhi Khimii
SP - 737-757
IS - 7
VL - 84
ER -
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@article{2015_Medvedev,
author = {Yurii Yur'evich Medvedev and Valery Aleksandrovich Nikolaev},
title = {Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds},
journal = {Russian Chemical Reviews},
year = {2015},
volume = {84},
publisher = {ANO Editorial Board of the journal Uspekhi Khimii},
month = {Nov},
url = {https://rcr.colab.ws/publications/10.1070/RCR4522},
number = {7},
pages = {737--757},
doi = {10.1070/RCR4522}
}
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Medvedev, Yurii Yur'evich, and Valery Aleksandrovich Nikolaev. “Recent advances in the chemistry of Rh carbenoids: multicomponent reactions of diazocarbonyl compounds.” Russian Chemical Reviews, vol. 84, no. 7, Nov. 2015, pp. 737-757. https://rcr.colab.ws/publications/10.1070/RCR4522.
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Abstract

Multicomponent reactions of diazo compounds catalyzed by Rh$^\mathrm{II}$ complexes become a~powerful tool for organic synthesis. They enable three- or four-step processes to be carried out as one-pot procedures (actually as one step) with high stereoselectivity to give complex organic molecules, including biologically active compounds. This review addresses recent results in the chemistry of Rh-catalyzed multicomponent reactions of diazocarbonyl compounds with the intermediate formation of N-, O- and C=O--ylides. The diastereo- and enantioselectivity of these reactions and the possibility of using various co-catalysts to increase the efficiency of the processes under consideration are discussed.

The bibliography includes 120 references.

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